Effect of Morphological Changes due to Increasing Carbon Nanoparticles Content on the Quasi-Static Mechanical Response of Epoxy Resin

Mechanical failure in epoxy polymer and composites leads them to commonly be referred to as inherently brittle due to the presence of polymerization-induced microcrack and microvoids, which are barriers to high-performance applications, e.g., in aerospace structures. Numerous studies have been carried out on epoxy's strengthening and toughening via nanomaterial reinforcement, e.g., using rubber nanoparticles in the epoxy matrix of new composite aircraft. However, extremely cautious process and functionalization steps must be taken in order to achieve high-quality dispersion and bonding, the development of which is not keeping pace with large structures applications. In this article, we report our studies on the mechanical performance of an epoxy polymer reinforced with graphite carbon nanoparticles (CNPs), and the possible effects arising from a straightforward, rapid stir-mixing technique. The CNPs were embedded in a low viscosity epoxy resin, with the CNP weight percentage (wt %) being varied between 1% and 5%. Simplified stirring embedment was selected in the interests of industrial process facilitation, and functionalization was avoided to reduce the number of parameters involved in the study. Embedment conditions and timing were held constant for all wt %. The CNP filled epoxy resin was then injected into an aluminum mold and cured under vacuum conditions at 80 °C for 12 h. A series of test specimens were then extracted from the mold, and tested under uniaxial quasi-static tension, compression, and nanoindentation. Elementary mechanical properties including failure strain, hardness, strength, and modulus were measured. The mechanical performance was improved by the incorporation of 1 and 2 wt % of CNP but was degraded by 5 wt % CNP, mainly attributed to the morphological change, including re-agglomeration, with the increasing CNP wt %. This change strongly correlated with the mechanical response in the presence of CNP, and was the major governing mechanism leading to both mechanical improvement and degradation

Electrospun Piezoelectric Polymer Nanofiber Layers for Enabling in Situ Measurement in High-Performance Composite Laminates

This article highlights the effects from composite manufacturing parameters on fiber-reinforced composite laminates modified with layers of piezoelectric thermoplastic nanofibers and a conductive electrode layer. Such modifications have been used for enabling in situ deformation measurement in high-performance aerospace and renewable energy composites. Procedures for manufacturing high-performance composites are well-known and standardized. However, this does not imply that modifications via addition of functional layers (e.g., piezoelectric nanofibers) while following the same manufacturing procedures can lead to a successful multifunctional composite structure (e.g., for enabling in situ measurement). This article challenges success of internal embedment of piezoelectric nanofibers in standard manufacturing of high-performance composites via relying on composite process specifications and parameters only. It highlights that the process parameters must be revised for manufacturing of multifunctional composites. Several methods have been used to lay up and manufacture composites such as electrospinning the thermoplastic nanofibers, processing an inter digital electrode (IDE) made by conductive epoxy-graphene resin, and prepreg autoclave manufacturing aerospace grade laminates. The purpose of fabrication of IDE was to use a resin type (HexFlow RTM6) for the conductive layer similar to that used for the composite. Thereby, material mismatch is avoided and the structural integrity is sustained via mitigation of downgrading effects on the interlaminar properties. X-ray diffraction, Fourier transform infrared spectroscopy, energy dispersive X-ray spectroscopy, and scanning electron microscopy analyses have been carried out in the material characterization phase. Pulsed thermography and ultrasonic C-scanning were used for the localization of conductive resin embedded within the composite laminates. This study also provides recommendations for enabling internally embedded piezoelectricity (and thus health-monitoring capabilities) in high-performance composite laminates

From Wires to Cables: Attempted Synthesis of 1,3,5-Trifluorenylcyclohexane as a Platform for Molecular Cables

Multiple molecular wires braided together in a single assembly, termed as molecular cable, are promising next-generation materials for effective long-range charge transport. As an example of the platform for constructing molecular cables, 1,3,5-trifluorenylcyclohexane (TFC) and its difluorenyl analogues (DFCs) were systematically investigated both experimentally (X-ray crystallography) and theoretically (DFT calculations). Although the syntheses of DFCs were successfully achieved, the synthesis of TFC, which involved a similar intramolecular Friedel–Crafts cyclization as the last step, was unsuccessful. An exhaustive study of the conformational landscape of cyclohexane ring of TFC and DFCs revealed that TFC is a moderately strained molecule (∼17 kcal/mol), and computational studies of the reaction profile show that this steric strain, present in the transition state, is responsible for the unusually high (∼5 years) reaction half-life. A successful synthesis of TFC will require that the steric strain is introduced in multiple steps, and such alternative strategies are being currently explored

Self-consistent triaxial de Zeeuw-Carollo Models

We use the usual method of Schwarzschild to construct self-consistent solutions for the triaxial de Zeeuw & Carollo (1996) models with central density cusps. ZC96 models are triaxial generalisations of spherical $\gamma$-models of Dehnen whose densities vary as $r^{-\gamma}$ near the center and $r^{-4}$ at large radii and hence, possess a central density core for $\gamma=0$ and cusps for $\gamma > 0$. We consider four triaxial models from ZC96, two prolate triaxials: $(p, q) = (0.65, 0.60)$ with $\gamma = 1.0$ and 1.5, and two oblate triaxials: $(p, q) = (0.95, 0.60)$ with $\gamma = 1.0$ and 1.5. We compute 4500 orbits in each model for time periods of $10^{5} T_{D}$. We find that a large fraction of the orbits in each model are stochastic by means of their nonzero Liapunov exponents. The stochastic orbits in each model can sustain regular shapes for $\sim 10^{3} T_{D}$ or longer, which suggests that they diffuse slowly through their allowed phase-space. Except for the oblate triaxial models with $\gamma =1.0$, our attempts to construct self-consistent solutions employing only the regular orbits fail for the remaining three models. However, the self-consistent solutions are found to exist for all models when the stochastic and regular orbits are treated in the same way because the mixing-time, $\sim10^{4} T_{D}$, is shorter than the integration time, $10^{5} T_{D}$. Moreover, the ``fully-mixed'' solutions can also be constructed for all models when the stochastic orbits are fully mixed at 15 lowest energy shells. Thus, we conclude that the self-consistent solutions exist for our selected prolate and oblate triaxial models with $\gamma = 1.0$ and 1.5.Comment: 6 Pages, 3 Figures, 2 Tables. Accepted for Publication in A&

Ground Level Enhancement in the 2014 January 6 Solar Energetic Particle Event

We present a study of the 2014 January 6 solar energetic particle (SEP) event, which produced a small ground level enhancement (GLE), making it the second GLE of this unusual solar cycle 24. This event was primarily observed by the South Pole neutron monitors (increase of ~2.5%) whereas a few other neutron monitors recorded smaller increases. The associated coronal mass ejection (CME) originated behind the western limb and had the speed of 1960 km/s. The height of the CME at the start of the associated metric type II radio burst, which indicates the formation of a strong shock, was measured to be 1.61 Rs using a direct image from STEREO-A/EUVI. The CME height at the time of GLE particle release (determined using the South Pole neutron monitor data) was directly measured as 2.96 Rs, from the STEREO-A/COR1 white-light observations. These CME heights are consistent with those obtained for the GLE71, the only other GLE of the current cycle as well as cycle-23 GLEs derived using back-extrapolation. GLE72 is of special interest because it is one of the only two GLEs of cycle 24, one of the two behind-the-limb GLEs and one of the two smallest GLEs of cycles 23 and 24