Stabilization of clayey soil using fibre reinforcement

The paper presents experimental and numerical investigations on crack evolution during desiccation, on unsaturated, compacted and reinforced clay using natural Alfa fibres. The effect of fibre content is investigated and a comparison between experimental and numerical simulations is made. A modified model for tensile strength is updated in the finite element program CODE_BRIGHT and used to predict tensile cracks induced by desiccation on reinforced soil. The results show that the soil desiccation cracking behaviour is significantly influenced by fibre inclusion and that experimental and numerical results are in good agreement.Postprint (published version

Analysis of band-gap formation in squashed arm-chair CNT

The electronic properties of squashed arm-chair carbon nanotubes are modeled using constraint free density functional tight binding molecular dynamics simulations. Independent from CNT diameter, squashing path can be divided into {\it three} regimes. In the first regime, the nanotube deforms with negligible force. In the second one, there is significantly more resistance to squashing with the force being $\sim 40-100$ nN/per CNT unit cell. In the last regime, the CNT looses its hexagonal structure resulting in force drop-off followed by substantial force enhancement upon squashing. We compute the change in band-gap as a function of squashing and our main results are: (i) A band-gap initially opens due to interaction between atoms at the top and bottom sides of CNT. The $\pi-$orbital approximation is successful in modeling the band-gap opening at this stage. (ii) In the second regime of squashing, large $\pi-\sigma$ interaction at the edges becomes important, which can lead to band-gap oscillation. (iii) Contrary to a common perception, nanotubes with broken mirror symmetry can have {\it zero} band-gap. (iv) All armchair nanotubes become metallic in the third regime of squashing. Finally, we discuss both differences and similarities obtained from the tight binding and density functional approaches.Comment: 16 pages and 6 figures, To appear in PR

I-V characteristics and differential conductance fluctuations of Au nanowires

Electronic transport properties of Au nano-structure are investigated using both experimental and theoretical analysis. Experimentally, stable Au nanowires were created using mechanically controllable break junction in air, and simultaneous current-voltage (I-V) and differential conductance $\delta I/\delta V$ data were measured. The atomic device scale structures are mechanically very stable up to bias voltage $V_b\sim0.6V$ and have a life time of a few $minutes$. Facilitated by a shape function data analysis technique which finger-prints electronic properties of the atomic device, our data show clearly differential conductance fluctuations with an amplitude $>1$ at room temperature, and a nonlinear I-V characteristics. To understand the transport features of these atomic scale conductors, we carried out {\it ab initio} calculations on various Au atomic wires. The theoretical results demonstrate that transport properties of these systems crucially depend on the electronic properties of the scattering region, the leads, and most importantly the interaction of the scattering region with the leads. For ideal, clean Au contacts, the theoretical results indicate a linear I-V behavior for bias voltage $V_b<0.5V$. When sulfur impurities exist at the contact junction, nonlinear I-V curves emerge due to a tunnelling barrier established in the presence of the S atom. The most striking observation is that even a single S atom can cause a qualitative change of the I-V curve from linear to nonlinear. A quantitatively favorable comparison between experimental data and theoretical results is obtained. We also report other results concerning quantum transport through Au atomic contacts.Comment: 11 pages and 9 figures, submitted to PR

Carbon nanotubes in the Coulomb blockade regime

Quantum transport through finite-length single wall carbon nanotubes was investigated theoretically in the Coulomb blockade regime. The spin-degenerate state of the nanotube is found to play a crucial role, and is responsible for the experimentally observed alternation in the heights of the conductance spectrum as electrons are added to the nanotubes. We also show that the relaxation of the energy eigenstates, which takes place as the electrons tunnel to and from the nanotubes, is responsible for the current saturation as a function of bias voltage polarity.published_or_final_versio

Size-dependent alternation of magnetoresistive properties in atomic chains

Cataloged from PDF version of article.Spin-polarized electronic and transport properties of carbon atomic chains are investigated when they are capped with magnetic transition-metal (TM) atoms like Cr or Co. The magnetic ground state of the TM-C-n-TM chains alternates between the ferromagnetic (F) and antiferromagnetic (AF) spin configurations as a function of n. In view of the nanoscale spintronic device applications the desirable AF state is obtained for only even-n chains with Cr; conversely only odd-n chains with Co have AF ground states. When connected to appropriate metallic electrodes these atomic chains display a strong spin-valve effect. Analysis of structural, electronic, and magnetic properties of these atomic chains, as well as the indirect exchange coupling of the TM atoms through non-magnetic carbon atoms are presented. (c) 2006 American Institute of Physics

Resonant transmission through finite-sized carbon nanotubes

We have investigated theoretically the conductance through finite-sized carbon nanotubes coupled to featureless leads in the context of standard tight-binding models. Conduction takes place via resonant tunneling, and the resultant spectrum of peaks may be understood in terms of the band structure of the nanotubes. Specific nanotubes display both on- and off-resonance behavior as a function of nanotube length depending upon whether or not the bands cross at a nonzero k value. We have also investigated the approach to the infinite limit in detail, and, in general, find that the finite-size effects can persist out to hundreds of nanometers. Since the manipulation of nanotubes into devices is likely to induce defects, we have investigated their effects on the conduction. The effects of bending and two broad classes of defects, i.e., defect in the absence and/or presence of addimers, were considered. In general, the presence of defects leads both to a reduction and shifting of the resonant peaks at the Fermi level. However, in the infinite limit, low concentrations of defects have only a relatively modest effect on the transport properties. Finally, we have investigated the effects of an externally imposed magnetic field oriented perpendicular to the nanotube axis. The magnetic field shifts the levels, thereby turning on- and off-resonant devices into each other. All of the effects discussed here are testable experimentally.published_or_final_versio

Yielding and fracture mechanisms of nanowires

This paper presents a detailed analysis of atomic structure and force variations in metal nanowires under tensile strain. Our work is based on state of the art molecular dynamics simulations and ab initio self-consistent field calculations within the local density approximation, and predicts structural transformations. It is found that yielding and fracture mechanisms depend on the size, atomic arrangement, and temperature. The elongation under uniaxial stress is realized by consecutive quasielastic and yielding stages; the neck develops by the migration of atoms, but mainly by the sequential implementation of a new layer with a smaller cross section at certain ranges of uniaxial strain. This causes an abrupt decrease of the tensile force. Owing to the excessive strain at the neck, the original structure and atomic registry are modified; atoms show a tendency to rearrange in closed-packed structures. In certain circumstances, a bundle of atomic chains or a single atomic chain forms as a result of transition from the hollow site to the top site registry shortly before the break. The wire is represented by a linear combination of atomic pseudopotentials and the current is calculated to investigate the correlation between conductance variations and atomic rearrangements of the wire during the stretch. The origin of the observed "giant" yield strength is explained by using results of the present simulations and ab initio calculations of the total energy and Young's modulus for an infinite atomic chain

Quantum heat transfer through an atomic wire

We studied the phononic heat transfer through an atomic dielectric wire with both infinite and finite lengths by using a model Hamiltonian approach. At low temperature under ballistic transport, the thermal conductance contributed by each phonon branch of a uniform and harmonic chain cannot exceed the well-known value which depends linearly on temperature but is material independent. We predict that this ballistic thermal conductance will exhibit stepwise behavior as a function of temperature. By performing numerical calculations on a more realistic system, where a small atomic chain is placed between two reservoirs, we also found resonance modes, which should also lead to the stepwise behavior in the thermal conductance.Comment: 14 pages, 2 separate figure

Analysis of TerraSAR-X data and their sensitivity to soil surface parameters over bare agricultural fields

International audienceCette recherche a pour objectif de mettre en évidence la contribution des capteurs haute résolution pour une meilleure caractérisation de la surface du sol et pour analyser les effets de la polarisation et de l'angle d'incidence radar. L'objectif de cet article est d'analyser la sensibilité des données haute résolution Terrassar-X sur des sols sans couverture végétale et d'étudier la variabilité spatiale. Les relations entre le coefficient de rétrodiffusion et les paramètres du sol seront étudiés grâce aux images (TerraSAR, Ikonos, SPOT) ainsi que grâce aux mesures de terrain recueillies pendant plusieurs campagnes de terrain en hiver et printemps 2008-2009. Ce travail a été mené sur le bassin de l'Orgeval (France). / Our research aims to show the contribution of high resolution spatial sensors for a better characterization of soil surface, and to analyze polarization effects and radar incidence angle. The objective of this paper is to analyze the sensitivity of very high resolution TerraSAR-X radar data taken over bare soils, and to study the spatial variability. The relationship between backscattering coefficient and soil's parameters (moisture, surface roughness, and texture) will be examined by means of satellite images (TerraSAR, Ikonos, SPOT), as well as ground truth measurements, recorded during several field campaigns in the winter and spring of 2008 and 2009. This study is carried out on Orgeval catchment (France)