301 research outputs found
Possible role of 3He impurities in solid 4He
We use a quantum lattice gas model to describe essential aspects of the
motion of 4He atoms and of 3He impurities in solid 4He. This study suggests
that 3He impurities bind to defects and promote 4He atoms to interstitial sites
which can turn the bosonic quantum disordered crystal into a metastable
supersolid. It is suggested that defects and interstitial atoms are produced
during the solid 4He nucleation process where the role of 3He impurities (in
addition to the cooling rate) is known to be important even at very small (1
ppm) impurity concentration. It is also proposed that such defects can form a
glass phase during the 4He solid growth by rapid cooling.Comment: 4 two-column Revtex pages, 4 figures. Europhysics Letters (in Press
BCC vs. HCP - The Effect of Crystal Symmetry on the High Temperature Mobility of Solid He
We report results of torsional oscillator (TO) experiments on solid He at
temperatures above 1K. We have previously found that single crystals, once
disordered, show some mobility (decoupled mass) even at these rather high
temperatures. The decoupled mass fraction with single crystals is typically 20-
30%. In the present work we performed similar measurements on polycrystalline
solid samples. The decoupled mass with polycrystals is much smaller, 1%,
similar to what is observed by other groups. In particular, we compared the
properties of samples grown with the TO's rotation axis at different
orientations with respect to gravity. We found that the decoupled mass fraction
of bcc samples is independent of the angle between the rotation axis and
gravity. In contrast, hcp samples showed a significant difference in the
fraction of decoupled mass as the angle between the rotation axis and gravity
was varied between zero and 85 degrees. Dislocation dynamics in the solid
offers one possible explanation of this anisotropy.Comment: 10 pages, 5 figures, to appear in Journal of Low Temperature Physics
- special issue on Supersolidit
On The Mobile Behavior of Solid He at High Temperatures
We report studies of solid helium contained inside a torsional oscillator, at
temperatures between 1.07K and 1.87K. We grew single crystals inside the
oscillator using commercially pure He and He-He mixtures containing
100 ppm He. Crystals were grown at constant temperature and pressure on the
melting curve. At the end of the growth, the crystals were disordered,
following which they partially decoupled from the oscillator. The fraction of
the decoupled He mass was temperature and velocity dependent. Around 1K, the
decoupled mass fraction for crystals grown from the mixture reached a limiting
value of around 35%. In the case of crystals grown using commercially pure
He at temperatures below 1.3K, this fraction was much smaller. This
difference could possibly be associated with the roughening transition at the
solid-liquid interface.Comment: 15 pages, 6 figure
Building block libraries and structural considerations in the self-assembly of polyoxometalate and polyoxothiometalate systems
Inorganic metal-oxide clusters form a class of compounds that are unique in their topological and electronic versatility and are becoming increasingly more important in a variety of applications. Namely, Polyoxometalates (POMs) have shown an unmatched range of physical properties and the ability to form structures that can bridge several length scales. The formation of these molecular clusters is often ambiguous and is governed by self-assembly processes that limit our ability to rationally design such molecules. However, recent years have shown that by considering new building block principles the design and discovery of novel complex clusters is aiding our understanding of this process. Now with current progress in thiometalate chemistry, specifically polyoxothiometalates (POTM), the field of inorganic molecular clusters has further diversified allowing for the targeted development of molecules with specific functionality. This chapter discusses the main differences between POM and POTM systems and how this affects synthetic methodologies and reactivities. We will illustrate how careful structural considerations can lead to the generation of novel building blocks and further deepen our understanding of complex systems
Ultra-cold Polarized Fermi Gases
Recent experiments with ultra-cold atoms have demonstrated the possibility of
realizing experimentally fermionic superfluids with imbalanced spin
populations. We discuss how these developments have shed a new light on a half-
century old open problem in condensed matter physics, and raised new
interrogations of their own.Comment: 27 pages; 8 figures; Published in Report in Rep. Prog. Phys. 73
112401 (2010
Frustrated 3-Dimensional Quantum Spin Liquid in CuHpCl
Inelastic neutron scattering measurements are reported for the quantum
antiferromagnetic material Cu_2(C_5H_12N_2)_2Cl_4 (CuHpCl). The magnetic
excitation spectrum forms a band extending from 0.9 meV to 1.4 meV. The
spectrum contains two modes that disperse throughout the a-c plane of the
monoclinic unit cell with less dispersion along the unique b-axis. Simple
arguments based on the measured dispersion relations and the crystal structure
show that a spin ladder model is inappropriate for describing CuHpCl. Instead,
it is proposed that hydrogen bond mediated exchange interactions between the
bi-nuclear molecular units yield a three-dimensional interacting spin system
with a recurrent triangular motif similar to the Shastry-Sutherland Model
(SSM). Model independent analysis based on the first moment sum rule shows that
at least four distinct spin pairs are strongly correlated and that two of
these, including the dimer bond of the corresponding SSM, are magnetically
frustrated. These results show that CuHpCl should be classified as a
frustration induced three dimensional quantum spin liquid.Comment: 13 pages, 17 figures (Color) ReSubmitted to Phys. Rev. B 9/21/2001
resubmission has new content email comments to [email protected] or
[email protected]
The Effect of Lattice Vibrations on Substitutional Alloy Thermodynamics
A longstanding limitation of first-principles calculations of substitutional
alloy phase diagrams is the difficulty to account for lattice vibrations. A
survey of the theoretical and experimental literature seeking to quantify the
impact of lattice vibrations on phase stability indicates that this effect can
be substantial. Typical vibrational entropy differences between phases are of
the order of 0.1 to 0.2 k_B/atom, which is comparable to the typical values of
configurational entropy differences in binary alloys (at most 0.693 k_B/atom).
This paper describes the basic formalism underlying ab initio phase diagram
calculations, along with the generalization required to account for lattice
vibrations. We overview the various techniques allowing the theoretical
calculation and the experimental determination of phonon dispersion curves and
related thermodynamic quantities, such as vibrational entropy or free energy. A
clear picture of the origin of vibrational entropy differences between phases
in an alloy system is presented that goes beyond the traditional bond counting
and volume change arguments. Vibrational entropy change can be attributed to
the changes in chemical bond stiffness associated with the changes in bond
length that take place during a phase transformation. This so-called ``bond
stiffness vs. bond length'' interpretation both summarizes the key phenomenon
driving vibrational entropy changes and provides a practical tool to model
them.Comment: Submitted to Reviews of Modern Physics 44 pages, 6 figure
Solid 4He and the Supersolid Phase: from Theoretical Speculation to the Discovery of a New State of Matter? A Review of the Past and Present Status of Research
The possibility of a supersolid state of matter, i.e., a crystalline solid
exhibiting superfluid properties, first appeared in theoretical studies about
forty years ago. After a long period of little interest due to the lack of
experimental evidence, it has attracted strong experimental and theoretical
attention in the last few years since Kim and Chan (Penn State, USA) reported
evidence for nonclassical rotational inertia effects, a typical signature of
superfluidity, in samples of solid 4He. Since this "first observation", other
experimental groups have observed such effects in the response to the rotation
of samples of crystalline helium, and it has become clear that the response of
the solid is extremely sensitive to growth conditions, annealing processes, and
3He impurities. A peak in the specific heat in the same range of temperatures
has been reported as well as anomalies in the elastic behaviour of solid 4He
with a strong resemblance to the phenomena revealed by torsional oscillator
experiments. Very recently, the observation of unusual mass transport in hcp
solid 4He has also been reported, suggesting superflow. From the theoretical
point of view, powerful simulation methods have been used to study solid 4He,
but the interpretation of the data is still rather difficult; dealing with the
question of supersolidity means that one has to face not only the problem of
the coexistence of quantum coherence phenomena and crystalline order, exploring
the realm of spontaneous symmetry breaking and quantum field theory, but also
the problem of the role of disorder, i.e., how defects, such as vacancies,
impurities, dislocations, and grain boundaries, participate in the phase
transition mechanism.Comment: Published on J. Phys. Soc. Jpn., Vol.77, No.11, p.11101
Peripheral non-viral MIDGE vector-driven delivery of β-endorphin in inflammatory pain
<p>Abstract</p> <p>Background</p> <p>Leukocytes infiltrating inflamed tissue produce and release opioid peptides such as β-endorphin, which activate opioid receptors on peripheral terminals of sensory nerves resulting in analgesia. Gene therapy is an attractive strategy to enhance continuous production of endogenous opioids. However, classical viral and plasmid vectors for gene delivery are hampered by immunogenicity, recombination, oncogene activation, anti-bacterial antibody production or changes in physiological gene expression. Non-viral, non-plasmid minimalistic, immunologically defined gene expression (MIDGE) vectors may overcome these problems as they carry only elements needed for gene transfer. Here, we investigated the effects of a nuclear localization sequence (NLS)-coupled MIDGE encoding the β-endorphin precursor proopiomelanocortin (POMC) on complete Freund's adjuvant-induced inflammatory pain in rats.</p> <p>Results</p> <p>POMC-MIDGE-NLS injected into inflamed paws appeared to be taken up by leukocytes resulting in higher concentrations of β-endorphin in these cells. POMC-MIDGE-NLS treatment reversed enhanced mechanical sensitivity compared with control MIDGE-NLS. However, both effects were moderate, not always statistically significant or directly correlated with each other. Also, the anti-hyperalgesic actions could not be increased by enhancing β-endorphin secretion or by modifying POMC-MIDGE-NLS to code for multiple copies of β-endorphin.</p> <p>Conclusion</p> <p>Although MIDGE vectors circumvent side-effects associated with classical viral and plasmid vectors, the current POMC-MIDGE-NLS did not result in reliable analgesic effectiveness in our pain model. This was possibly associated with insufficient and variable efficacy in transfection and/or β-endorphin production. Our data point at the importance of the reproducibility of gene therapy strategies for the control of chronic pain.</p
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