339 research outputs found
Micro- vs. macro-phase separation in binary blends of poly(styrene)-poly(isoprene) and poly(isoprene)-poly(ethylene oxide) diblock copolymers
In this paper we present an experimentally determined phase diagram of binary blends of the diblock copolymers poly(styrene)-poly(isoprene) and poly(isoprene)-poly(ethylene oxide). At high temperatures, the blends form an isotropic mixture. Upon lowering the temperature, the blend macro-phase separates before micro-phase separation occurs. The observed phase diagram is compared to theoretical predictions based on experimental parameters. In the low-temperature phase the crystallisation of the poly(ethylene oxide) block influences the spacing of the ordered phase
Concept for a Time-of-Flight Small Angle Neutron Scattering Instrument at the European Spallation Source
A new Small Angle Neutron Scattering instrument is proposed for the European
Spallation Source. The pulsed source requires a time-of-flight analysis of the
gathered neutrons at the detector. The optimal instrument length is found to be
rather large, which allows for a polarizer and a versatile collimation. The
polarizer allows for studying magnetic samples and incoherent background
subtraction. The wide collimation will host VSANS and SESANS options that
increase the resolution of the instrument towards um and tens of um,
respectively. Two 1m2 area detectors will cover a large solid angle
simultaneously. The expected gains for this new instrument will lie in the
range between 20 and 36, depending on the assessment criteria, when compared to
up-to-date reactor based instruments. This will open new perspectives for fast
kinetics, weakly scattering samples, and multi-dimensional contrast variation
studies.Comment: 18 pages, 10 figure
Polymerized mixed aggregates containing gadolinium complex and CCK8 peptide.
Two novel amphiphilic unimers contg. an aliph. hydrophobic chain (PDA) with two C C triple bonds and hydrophilic heads presenting the chelating agent DTPAGlu and the CCK8 bioactive peptide, resp., have been prepd. by solid phase synthesis. Aggregates obtained by mixing together PDA-DTPAGlu, or its Gd(III) complex, and PDA-L2-CCK8 in 70/30 molar ratio before and after a polymn. process carried out by UV irradn. have been structurally characterized by means of small angle neutron scattering. The relaxivity properties of aggregates contg. Gadolinium complexes have also been investigated. Elongated mixed micelles have been obsd., in which the relaxivity value r1p for each Gadolinium complex, measured at 20 MHz and 298 K, is around 12 mM-1s-1
Self-assembly of phosphate fluorosurfactants in carbon dioxide
Anionic phosphodiester surfactants, possessing either two fluorinated chains (F/F) or one hydrocarbon chain and one fluorinated chain (H/F), were synthesized and evaluated for solubility and self-assembly in liquid and supercritical carbon dioxide. Several surfactants, of both F/F and EUF types and having varied counterions, were found to be capable of solubilizing water-in-CO2 (W/C), via the formation of microemulsions, expanding upon the family of phosphate fluorosurfactants already found to stabilize W/C microemulsions. Small-angle neutron scattering was used to directly characterize the microemulsion particles at varied temperatures, pressures, and water loadings, revealing behavior consistent with previous results on W/C microemulsions
Probing structural relaxation in complex fluids by critical fluctuations
Complex fluids, such as polymer solutions and blends, colloids and gels, are
of growing interest in fundamental and applied soft-condensed-matter science. A
common feature of all such systems is the presence of a mesoscopic structural
length scale intermediate between atomic and macroscopic scales. This
mesoscopic structure of complex fluids is often fragile and sensitive to
external perturbations. Complex fluids are frequently viscoelastic (showing a
combination of viscous and elastic behaviour) with their dynamic response
depending on the time and length scales. Recently, non-invasive methods to
infer the rheological response of complex fluids have gained popularity through
the technique of microrheology, where the diffusion of probe spheres in a
viscoelastic fluid is monitored with the aid of light scattering or microscopy.
Here we propose an alternative to traditional microrheology that does not
require doping of probe particles in the fluid (which can sometimes drastically
alter the molecular environment). Instead, our proposed method makes use of the
phenomenon of "avoided crossing" between modes associated with the structural
relaxation and critical fluctuations that are spontaneously generated in the
system.Comment: 4 pages, 4 figure
Особенности химизма блеклых руд участка ЭМИ Светлинского эпитермального рудного поля (Хабаровский край)
We experimentally studied the Josephson supercurrent in Nb/InN-nanowire/Nb junctions. Large
critical currents up to 5.7 μA have been achieved, which proves the good coupling of the nanowire
to the superconductor. The effect of a magnetic field perpendicular to the plane of the Josephson
junction on the critical current has been studied. The observed monotonous decrease in the critical
current with magnetic field is explained by the magnetic pair-breaking effect in planar Josephson
junctions of ultra-narrow width [J. C. Cuevas and F. S. Bergeret, Phys. Rev. Lett. 99, 217002 (2007)]
Retrospective analysis of antimicrobial resistance and bacterial spectrum of infection in Gabon, Central Africa
Background: Physicians depend on reliable information on the local epidemiology of infection and antibiotic resistance rates to guide empiric treatment in critically ill patients. As these data are scarce for Central Africa, we performed a retrospective analysis of microbiological findings from a secondary care hospital in Gabon. Methods: Microbiological reports from 2009 to 2012 were used to assess the non-susceptibility rates of the three most common isolates from six major types of infections (bloodstream, ear-eye-nose-throat, surgical site, skin and soft tissue, urinary tract and wound infection). Results: A high diversity of pathogens was found, but Staphylococcus aureus was predominant in the majority of infections. Overall, the three most prevalent pathogens in children were S. aureus (33.7%), Streptococcus pyogenes (8.1%) and Escherichia coli (4.5%) and in adults S. aureus (23.5%), E. coli (15.1%) and Klebsiella pneumoniae (7.4%). In total, 5.8% (n = 19) of all S. aureus isolates were methicillin resistant. The proportion of extended-spectrum beta-lactamase (ESBL) producing Enterobacteriaceae was 15.4% (n = 78), 49.4% of all K. pneumoniae were ESBL-producer (n = 42). Conclusion: The high diversity of potential pathogens and high resistance rates in Gram-negative bacteria challenge a rational empiric use of antibiotics. Countrywide continuous sentinel surveillance is therefore urgently needed.<br
InAs nanowire hot-electron Josephson transistor
At a superconductor (S)-normal metal (N) junction pairing correlations can
"leak-out" into the N region. This proximity effect [1, 2] modifies the system
transport properties and can lead to supercurrent flow in SNS junctions [3].
Recent experimental works showed the potential of semiconductor nanowires (NWs)
as building blocks for nanometre-scale devices [4-7], also in combination with
superconducting elements [8-12]. Here, we demonstrate an InAs NW Josephson
transistor where supercurrent is controlled by hot-quasiparticle injection from
normal-metal electrodes. Operational principle is based on the modification of
NW electron-energy distribution [13-20] that can yield reduced dissipation and
high-switching speed. We shall argue that exploitation of this principle with
heterostructured semiconductor NWs opens the way to a host of
out-of-equilibrium hybrid-nanodevice concepts [7, 21].Comment: 6 pages, 6 color figure
Dielectric relaxations of nanocomposites composed of HEUR polymers and magnetite nanoparticles
We investigate the dynamics of nanocomposites composed of hydrophobically modified ethoxylated urethanes (HEUR) and magnetite nanoparticles (MNPs) as dry films. Weemployed dielectric relaxation spectroscopy (DRS) in combination with differential scanning calorimetry (DSC) and thermally stimulated depolarization currents (TSDC).The three techniques reveal a strong heterogeneity of the matrix of the nanocomposites, consisting of (i) a crystalline poly(ethyleneoxide) PEO bulk phase, (ii) an amorphous PEO portion, and (iii) small PEO crystallites which experience different constraints than the PEO bulk phase. TSDC and DRS reveal a very high direct current (DC)-conductivity of the pure matrix, which increases with MNPs concentration. The increase of the DCconductivity is not related to an increase of the segmental mobility, but most likely to the change of the morphology of the hydrophobic domains of the polymer matrix, due to the formation of large MNPs clusters. Indeed, the MNPs neither influence the segmental dynamics of the polymer nor the phase behavior of the polymer matrix. The addition of MNPs slightly increases the activation energy related to the γ-relaxation of the polymer. This effect might be related to the changes in nano-morphology as demonstrated by the slight increase of the degree of crystallinity. The analysis of the DRS data with the electrical modulus M’’(ω) and the derivative ε’’der formalism allow us to identify a low-frequency process in addition to the conductivity relaxation. This low-frequency dispersion is also revealed by TSDC. It is most likely related to the Maxwell-Wagner- Sillars relaxation, which typically occurs in systems which feature phase separation. The detailed investigation of the dielectric properties of these novel nanocomposites with increasing MNPs concentration will be useful for their practical application, for example as absorbers of electromagnetic waves
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