DISCHARGE OXIDE STORAGE CAPACITY AND VOLTAGE LOSS IN LI-AIR BATTERY

Air cathodes, where oxygen reacts with Li ions and electrons with discharge oxide stored in their pore structure, are often considered as the most challenging component in nonaqueous Lithium-air batteries. In non-aqueous electrolytes, discharge oxides are usually insoluble and hence precipitate at local reaction site, raising the oxygen transport resistance in the pore network. Due to their low electric conductivity, their presence causes electrode passivation. This study aims to investigate the air cathode's performance through analytically obtaining oxygen profiles, modeling electrode passivation, evaluating the transport polarization raised by discharge oxide precipitate, and developing analytical formulas for insoluble Li oxides storage capacity. The variations of cathode quantities, including oxygen content and temperature, are evaluated and related to a single dimensionless parameter - the Damköhler Number (Da). An approximate model is developed to predict discharge voltage loss, along with validation against two sets of experimental data. Air cathode properties, including tortuosity, surface coverage factor and the Da number, and their effects on the cathode's capacity of storing Li oxides are formulated and discussed

Effects of Volcanic Emissions on Clouds During Kilauea Degassing Events

Aerosols influence Earths radiative balance directly by scattering and absorbing solar radiation, and indirectly by modifying cloud properties. Current scientific consensus indicates that these effects may offset as much as 50% of the warming due to greenhouse gas emissions. Over the last two decades dramatic volcanic events in Hawaii have produced localized aerosol emissions in otherwise clean environments. These are natural experiments" where the aerosol effects on clouds and climate can be partitioned from other effects like meteorology and industrial emissions. Therefore, these events provide a unique opportunity to learn about possible effects of aerosol pollution on climate through cloud modification. In this work we use the version 5 of the NASA Goddard Earth Observing System (GEOS-5) and satellite retrievals to analyze and evaluate the strength of the aerosol indirect effect on liquid and ice clouds during the 2008 and 2018 Kilauea degassing events using different emissions scenarios (0, 1, and 5 actual emissions). Our results suggested that the 2018 event was stronger and more regionally significant with respect to cloud formation process for both liquid and ice clouds, while the 2008 affected local liquid clouds only. GEOS-5 predictions reproduced spatial patterns for all parameters, however better precision could be gained by using more accurate plume parameters for height and ash concentration

Fabrication and high temperature characteristics of ion-implanted GaAs bipolar transistors and ring-oscillators

Ion implantation techniques that permit the reproducible fabrication of bipolar GaAs integrated circuits are studied. A 15 stage ring oscillator and discrete transistor were characterized between 25 and 400 C. The current gain of the transistor was found to increase slightly with temperature. The diode leakage currents increase with an activation energy of approximately 1 eV and dominate the transistor leakage current 1 sub CEO above 200 C. Present devices fail catastrophically at about 400 C because of Au-metallization

Optical spectroscopy study on single crystalline LaFeAsO

Millimeter-sized single crystals of LaFeAsO were grown from NaAs flux and the in-plane optical properties were studied over a wide frequency range. A sizable electronic correlation effect was indicated from the analysis of the free-carrier spectral weight. With decreasing temperature from 300 K, we observed a continuous suppression of the spectral weight near 0.6 eV. But a spin-density-wave gap formation at lower energy scale was seen only in the broken-symmetry state. We elaborate that both the itinerancy and local spin interactions of Fe\emph{3d} electrons are present for the FeAs-based systems; however, the establishment of the long-range magnetic order at low temperature has a dominantly itinerant origin.Comment: 4 figures, 5 page

ADN: An Information-Centric Networking Architecture for the Internet of Things

Forwarding data by name has been assumed to be a necessary aspect of an information-centric redesign of the current Internet architecture that makes content access, dissemination, and storage more efficient. The Named Data Networking (NDN) and Content-Centric Networking (CCNx) architectures are the leading examples of such an approach. However, forwarding data by name incurs storage and communication complexities that are orders of magnitude larger than solutions based on forwarding data using addresses. Furthermore, the specific algorithms used in NDN and CCNx have been shown to have a number of limitations. The Addressable Data Networking (ADN) architecture is introduced as an alternative to NDN and CCNx. ADN is particularly attractive for large-scale deployments of the Internet of Things (IoT), because it requires far less storage and processing in relaying nodes than NDN. ADN allows things and data to be denoted by names, just like NDN and CCNx do. However, instead of replacing the waist of the Internet with named-data forwarding, ADN uses an address-based forwarding plane and introduces an information plane that seamlessly maps names to addresses without the involvement of end-user applications. Simulation results illustrate the order of magnitude savings in complexity that can be attained with ADN compared to NDN.Comment: 10 page

Theory of spin blockade, charge ratchet effect, and thermoelectrical behavior in serially coupled quantum-dot system

The charge transport of a serially coupled quantum dots (SCQD) connected to the metallic electrodes is theoretically investigated in the Coulomb blockade regime. A closed-form expression for the tunneling current of SCQD in the {\color{red} weak interdot hopping} limit is obtained by solving an extended two-site Hubbard model via the Green's function method. We use this expression to investigate spin current rectification, negative differential conductance, and coherent tunneling in the nonlinear response regime. The current rectification arising from the space symmetry breaking of SCQD is suppressed by increasing temperature. The calculation of SCQD is extended to the case of multiple parallel SCQDs for studying the charge ratchet effect and SCQD with multiple levels. In the linear response regime, the functionalities of spin filter and low-temperature current filter are demonstrated to coexist in this system. It is further demonstrated that two-electron spin singlet and triplet states can be readily resolved from the measurement of Seebeck coefficient rather than that of electrical conductance.Comment: 11 pages, 9 figures. Revised argument, results unchanged, added reference