Microwave-assisted protocol for squalene isolation and conversion from oil-deodoriser distillates

Aiming to design a green and efficient protocol for squalane production from low-cost biomasses, a practical and scalable procedure for squalene extraction and hydrogenation to squalane is presented herein. The oil-deodoriser distillates that are produced by the vegetal-oil production chain are a renewable and cheap source of squalene. We were able to isolate an enriched fraction containing 89.0% of pure squalene (yield 55.4%) from a matrix containing about 2% squalene. Efficient microwave- assisted esterification under heterogeneous catalysis enabled the separation of fatty-acid methyl esters (FAME) via vacuum distillation. The residue was purified by flash-chromatography on a C-18 silica column using MeOH/H2O/2-propanol as the mobile phase. Finally, squalene was hydrogenated to the more stable squalane in a pressure-resistant microwave reactor. The reaction was performed over a Pd/C catalyst in EtOH, and even in solvent-free conditions, and was optimised using commercial squalene (5 bar of H2 at 100°C for 1 h)

Wärme- und strömungstechnische Untersuchungen an fluchtendenRohrbündel-Wärmeaustauschern aus pyramidenförmig aufgerauhten Rohren

Integral values of heat transfer and pressure drop are reported. They have been gained from 5 tube banks in cross flow of different tube pitches and roughnesses. The experiments were conducted at Reynolds numbers 5 $\cdot$ 10$^{3}$ < Re < 10$^{6}$ with air and helium as experimental fluid on the outside of the tubes. Increasing artificially the roughness of the tubes a gain in heat transfer was achieved up to 50% compared to a tube arrangement of technically smooth tubes without increasing the flow resistance. Besides this the fraction of each tube row of the integral heat transfer coefficient of the bundle was measured. In comparison to an arrangement of smooth tubes the heat transfer of the first tube row was increased in relation to the following ones. Furthermore the artificial roughness of the tubes effected an equalisation of the velocity profiles behind the heat exchanger

Velocity weakening and possibility of aftershocks in nanofriction experiments

We study the frictional behavior of small contacts as those realized in the atomic force microscope and other experimental setups, in the framework of generalized Prandtl-Tomlinson models. Particular attention is paid to mechanisms that generate velocity weakening, namely a decreasing average friction force with the relative sliding velocity.The mechanisms studied model the possibility of viscous relaxation, or aging effects in the contact. It is found that, in addition to producing velocity weakening, these mechanisms can also produce aftershocks at sufficiently low sliding velocities. This provides a remarkable analogy at the microscale, of friction properties at the macroscale, where aftershocks and velocity weakening are two fundamental features of seismic phenomena.Comment: 8 pages, 7 figure

Power Laws, Precursors and Predictability During Failure

We investigate the dynamics of a modified Burridge-Knopoff model by introducing a dissipative term to mimic the bursts of acoustic emission (AE) from rock samples. The model explains many features of the statistics of AE signals observed in experiments such as the crossover in the exponent value from relatively small amplitude AE signals to larger regime, and their dependence on the pulling speed. Significantly, we find that the cumulative energy dissipated identified with acoustic emission can be used to predict a major slip event. We also find a data collapse of the acoustic activity for several major slip events describable by a universal stretched exponential with corrections in terms of time-to-failure.Comment: 7 pages, 6 figures, Final version with minor change

Observations of Mira stars with the IOTA/FLUOR interferometer and comparison with Mira star models

We present K'-band observations of five Mira stars with the IOTA interferometer. The interferograms were obtained with the FLUOR fiber optics beam combiner, which provides high-accuracy visibility measurements in spite of time-variable atmospheric conditions. For the M-type Miras X Oph, R Aql, RU Her, R Ser, and the C-type Mira V CrB we derived the uniform-disk diameters 11.7mas, 10.9mas, 8.4mas, 8.1mas, and 7.9mas (+/- 0.3mas), respectively. Simultaneous photometric observations yielded the bolometric fluxes. The derived angular Rosseland radii and the bolometric fluxes allowed the determination of effective temperatures. For instance, the effective temperature of R Aql was determined to be 2970 +/- 110 K. A linear Rosseland radius for R Aql of (250 +100/-60) Rsun was derived from the angular Rosseland radius of 5.5mas +/- 0.2mas and the HIPPARCOS parallax of 4.73mas +/- 1.19mas. The observations were compared with theoretical Mira star models of Bessel et al. (1996) and Hofmann et al. (1998). The effective temperatures of the M-type Miras and the linear radius of R Aql indicate fundamental mode pulsation.Comment: 12 pages, 4 postscript figure

Scaling differences between large interplate and intraplate earthquakes

A study of large intraplate earthquakes with well-determined source parameters shows that these earthquakes obey a scaling law similar to large interplate earthquakes, in which M_0 ∝ L^2 or u = αL, where L is rupture length and u is slip. In contrast to interplate earthquakes, for which α ≈ 1 × 10^(−5), for for the intraplate events α ≈ 6 × 10^(−5), which implies that these earthquakes have stress drops about 6 times higher than interplate events. This result is independent of focal mechanism type. This implies that intraplate faults have a higher frictional strength than do plate boundaries, and hence that faults are velocity or slip weakening in their behavior. This factor may be important in producing the concentrated deformation that creates and maintains plate boundaries

Earthquake swarm in the Santa Barbara Channel, California, 1968

Sixty-three minor earthquakes (maximum magnitude = 5.2) occurred in the Santa Barbara Channel during the period June 26 to August 3 1968. The epicenters form a shot-scatter pattern upon a broad, high-standing fault block in the channel midway between Santa Cruz Island and the City of Santa Barbara. Focal mechanism studies indicate that oblique-slip movement occurred along a northwest-striking fault even though the major folds and faults strike nearly east-west. Preliminary studies of the areal hydrocarbon production data show no compelling evidence for a causal relationship with the swarm

UV Photoelectron Spectroscopy of Aqueous Solutions

Knowledge of the electronic structure of an aqueous solution is a prerequisite to understanding its chemical and biological reactivity and its response to light. One of the most direct ways of determining electronic structure is to use photoelectron spectroscopy to measure electron binding energies. Initially, photoelectron spectroscopy was restricted to the gas or solid phases due to the requirement for high vacuum to minimize inelastic scattering of the emitted electrons. The introduction of liquid-jets and their combination with intense X-ray sources at synchrotrons in the late 1990s expanded the scope of photoelectron spectroscopy to include liquids. Liquid-jet photoelectron spectroscopy is now an active research field involving a growing number of research groups. A limitation of X-ray photoelectron spectroscopy of aqueous solutions is the requirement to use solutes with reasonably high concentrations in order to obtain photoelectron spectra with adequate signal-to-noise after subtracting the spectrum of water. This has excluded most studies of organic molecules, which tend to be only weakly soluble. A solution to this problem is to use resonance-enhanced photoelectron spectroscopy with ultraviolet (UV) light pulses (hν ≲ 6 eV). However, the development of UV liquid-jet photoelectron spectroscopy has been hampered by a lack of quantitative understanding of inelastic scattering of low kinetic energy electrons (≲5 eV) and the impact on spectral lineshapes and positions.In this Account, we describe the key steps involved in the measurement of UV photoelectron spectra of aqueous solutions: photoionization/detachment, electron transport of low kinetic energy electrons through the conduction band, transmission through the water-vacuum interface, and transport through the spectrometer. We also explain the steps we take to record accurate UV photoelectron spectra of liquids with excellent signal-to-noise. We then describe how we have combined Monte Carlo simulations of electron scattering and spectral inversion with molecular dynamics simulations of depth profiles of organic solutes in aqueous solution to develop an efficient and widely applicable method for retrieving true UV photoelectron spectra of aqueous solutions. The huge potential of our experimental and spectral retrieval methods is illustrated using three examples. The first is a measurement of the vertical detachment energy of the green fluorescent protein chromophore, a sparingly soluble organic anion whose electronic structure underpins its fluorescence and photooxidation properties. The second is a measurement of the vertical ionization energy of liquid water, which has been the subject of discussion since the first X-ray photoelectron spectroscopy measurement in 1997. The third is a UV photoelectron spectroscopy study of the vertical ionization energy of aqueous phenol which demonstrates the possibility of retrieving true photoelectron spectra from measurements with contributions from components with different concentration profiles