445 research outputs found
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Polyamide Nanocomposites for Selective Laser Sintering
Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high
heat resistance characteristics for a plethora of finished parts that are desired and required
for performance driven applications. It is anticipated that nanomodification of polyamide
11 and 12 will result in enhanced polymer performance, i.e., fire retardancy, high strength
and high heat resistance for polyamide 11 and 12. It is expected that these findings will
expand the market opportunities for polyamide 11 and 12 resin manufacturers.
The objective of this research is to develop improved polyamide 11 and 12 polymers
with enhanced flame retardancy, thermal, and mechanical properties for selective laser
sintering (SLS) rapid manufacturing (RM). A nanophase was introduced into the
polyamide 11 and 12 via twin screw extrusion to provide improved material properties of
the polymer blends. Arkema RILSAN® polyamide 11 molding polymer pellets and
Degussa VESTAMID® L1670 polyamide 12 were examined with three types of
nanoparticles: chemically modified montmorillonite (MMT) organoclays, surface
modified nanosilica, and carbon nanofibers (CNFs) to create polyamide 11 and 12
nanocomposites.
Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM)
were used to determine the degree of dispersion. Injection molded test specimens were
fabricated for physical, thermal, mechanical properties, and flammability tests. Thermal
stability of these polyamide 11 and 12 nanocomposites was examined by TGA.
Mechanical properties such as tensile, flexural, and elongation at break were measured.
Flammability properties were also obtained using the Cone Calorimeter at an external
heat flux of 50 kW/m2. TEM micrographs, physical, mechanical, and flammability
properties are included in the paper. Polyamide 11 and 12 nanocomposites properties are
compared with polyamide 11 and 12 baseline polymers. Based on flammability and
mechanical material performance, selective polymers including polyamide 11
nanocomposites and control polyamide 11 were cryogenically ground into fine powders
and fabricated into SLS parts.Mechanical Engineerin
A simple theoretical model of heat and moisture transport in multi-layer garments in cool ambient air
Overall resistances for heat and vapor transport in a multilayer garment depend on the properties of individual layers and the thickness of any air space between layers. Under uncomplicated, steady-state conditions, thermal and mass fluxes are uniform within the garment, and the rate of transport is simply computed as the overall temperature or water concentration difference divided by the appropriate resistance. However, that simple computation is not valid under cool ambient conditions when the vapor permeability of the garment is low, and condensation occurs within the garment. Several recent studies have measured heat and vapor transport when condensation occurs within the garment (Richards et al. in Report on Project ThermProject, Contract No. G6RD-CT-2002-00846, 2002; Havenith et al. in J Appl Physiol 104:142-149, 2008). In addition to measuring cooling rates for ensembles when the skin was either wet or dry, both studies employed a flat-plate apparatus to measure resistances of individual layers. Those data provide information required to define the properties of an ensemble in terms of its individual layers. We have extended the work of previous investigators by developing a rather simple technique for analyzing heat and water vapor transport when condensation occurs within a garment. Computed results agree well with experimental results reported by Richards et al. (Report on Project ThermProject, Contract No. G6RD-CT-2002-00846, 2002) and Havenith et al. (J Appl Physiol 104:142-149, 2008). We discuss application of the method to human subjects for whom the rate of sweat secretion, instead of the partial pressure of water on the skin, is specified. Analysis of a more complicated five-layer system studied by Yoo and Kim (Text Res J 78:189-197, 2008) required an iterative computation based on principles defined in this paper
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Intumescent Flame Retardant Polyamide 11 Nanocomposites
Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high heat
resistance characteristics for a plethora of fabricated parts that are desired and required
for performance driven applications. The introduction of selected nanoparticles such as
surface modified montmorillonite (MMT) clay or carbon nanofibers (CNFs), combined
with a conventional intumescent flame retardant (FR) additive into the polyamide
11/polyamide 12 (PA11/PA12) by melt processing conditions has resulted in the
preparation of a family of intumescent polyamide nanocomposites. These intumescent
polyamide 11 and 12 nanocomposites exhibit enhanced polymer performance
characteristics, i.e., fire retardancy, high strength and high heat resistance and are
expected to expand the market opportunities for polyamide 11 and polyamide 12 polymer
manufacturers.
The objective of this research is to develop improved polyamide 11 and 12 polymers with
enhanced flame retardancy, thermal, and mechanical properties for selective laser
sintering (SLS) rapid manufacturing (RM). In the present study, a nanophase was
introduced into the polyamide 11 and combining it with a conventional intumescent FR
additive via twin screw extrusion. Arkema RILSAN® polyamide 11 molding polymer
pellets were examined with two types of nanoparticles: chemically modified
montmorillonite (MMT) organoclays, and carbon nanofibers (CNFs); and Clairant’s
Exolit® OP 1230 intumescent FR additive were used to create a family of FR
intumescent polyamide 11 nanocomposites.
Transmission electron microscopy (TEM) was used to determine the degree of
nanoparticles dispersion. Injection molded specimens were fabricated for physical,
thermal, and flammability measurements. Thermal stability of these intumescent
polyamide 11 nanocomposites was examined by TGA. Flammability properties were
obtained using the Cone Calorimeter at an external heat flux of 35 kW/m
2
and UL 94
Test Method. Heat deflection temperatures (HDT) were also measured. TEM
micrographs, physical, thermal, and flammability properties are presented. FR
intumescent polyamide 11 nanocomposites properties are compared with polyamide 11
baseline polymer. Based on flammability and mechanical material performance, selective
polymers including polyamide 11 nanocomposites and control polyamide 11 will be
cryogenically ground into fine powders for SLS RM processing. SLS specimens will be
fabricated for thermal, flammability, and mechanical properties characterization.Mechanical Engineerin
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Innovative Selective Laser Sintering Rapid Manufacturing using Nanotechnology
The objective of this research is to develop an improved nylon 11 (polyamide 11) polymer
with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing (RM). A nanophase was introduced into nylon 11 via twin screw
extrusion to provide improved material properties of the polymer blends. Atofina (now known
as Arkema) RILSAN® nylon 11 injection molding polymer pellets was used with three types of
nanoparticles: chemically modified montmorillonite (MMT) organoclays, nanosilica, and carbon
nanofibers (CNF) to create nylon 11 nanocomposites. Wide angle X-ray diffraction (WAXD)
and transmission electron microscopy (TEM) were used to determine the degree of dispersion.
Fifteen nylon 11 nanocomposites and control nylon 11 were fabricated by injection molding.
Flammability properties (using a cone calorimeter with a radiant flux of 50 kW/m2
) and
mechanical properties such as tensile strength and modulus, flexural modulus, elongation at
break were determined for the nylon 11 nanocomposites and compared with the baseline nylon
11. Based on flammability and mechanical material performance, five polymers including four
nylon 11 nanocomposites and a control nylon 11 were cryogenically ground into fine powders
for SLS RM. SLS specimens were fabricated for flammability, mechanical, and thermal
properties characterization. Nylon 11-CNF nanocomposites exhibited the best overall properties
for this study.Mechanical Engineerin
Physical Properties of a Set of Sandstones, III: the Effects Of Fine Grained Pore Filling Material on Compressional Wave Velocity
We have used aspect ratio modeling to explain the measured compressional
wave velocities of twenty different dry sandstone samples with varying clay
contents at a single confining pressure of 0.5 kbar. Velocities of the sandstones
range between 3.1 km/sec and 5.7 km/sec. Measured porosities are between 6%
and 33%, clay contents between 2% and 30%. Pores were described using three
simple type classifications. The pore type distributions of the samples were
quantified by point counting polished impregnated thin sections using a scanning
electron microscope. A representative aspect-ratio was assigned to each of the
three categories of pore type. Velocities were modeled using these aspect ratios
weighted by the observed distribution of the porosity types. Agreement between
theoretical and measured velocities is generally within 10%. The modeling suggests
that the effects of clays in sandstone pores is to reduce the sample porosity without
reducing the non-framework (void + clay) volume. Thus, for a given porosity, clay rich
samples contain greater non-framework volume, which in turn lowers velocity. The
model derived from the dry measurements can be used to successfully approximate
empirical relationships for saturated samples of velocity-porosity-clay content taken
from the literature.Schlumberger-Doll Research CenterSchlumberger Foundation. Post-Doctoral Fellowshi
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Flame Retardant Intumescent Polyamide 11 Nanocomposites – Further Study
The objective of this research is to develop improved polyamide 11 and 12 polymers with
enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing (RM). In the present study, a nanophase was introduced into the
polyamide 11 and combine with a conventional intumescent flame retardant (FR) additive via
twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used with
two types of nanoparticles such as: chemically modified montmorillonite (MMT) organoclays
and carbon nanofibers (CNFs). Two types of Clariant’s Exolit® OP 1311 and 1312 intumescent
FR additives were used to generate a family of FR intumescent polyamide 11 nanocomposites
with anticipated synergism.Mechanical Engineerin
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Polyamide 11-Carbon Nanotubes Nanocomposites: Preliminary Investigation
The objective of this research is to develop an improved polyamide 11 (PA11) polymer with
enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing. In the present study, a nanophase was introduced into polyamide 11
via twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used
with 1, 3, 5, and 7 wt% loadings of Arkema’s GraphistrengthTM multi-wall carbon nanotubes
(MWNTs) to create a family of PA11-MWNT nanocomposites.
Transmission electron microscopy and scanning electron microscopy were used to determine
the degree and uniformity of dispersion. Injection molded test specimens were fabricated for
physical, thermal, mechanical properties, and flammability measurements. Thermal stability of
these polyamide 11-MWNT nanocomposites was examined by TGA. Mechanical properties such
as ultimate tensile strength, rupture tensile strength, and elongation at rupture were measured.
Flammability properties were also obtained using the UL 94 test method. All these different
methods and subsequent polymer characteristics are discussed in this paper.Mechanical Engineerin
Application of a Predictive Coke Temperature Model to Heat Stress Experimentation
An interactive procedure for evaluating and maintaining an individual's core temperature at a predetermined level was developed and tested. The procedure involved the use of previously developed models for predicting core temperature changes during work and rest. Various levels of metabolic activity were used for rapid core temperature elevation and adjustments in dry-bulb temperature and relative humidity maintained the desired core temperature level. Evaluation of the procedure was made using five female subjects at four different levels of elevation. Results are presented which show the accuracy of the control.Yeshttps://us.sagepub.com/en-us/nam/manuscript-submission-guideline
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