685 research outputs found
Simulation study of pressure and temperature dependence of the negative thermal expansion in Zn(CN)(2)
12 pages, 16 figures12 pages, 16 figures12 pages, 16 figures12 pages, 16 figure
Are Simple Real Pole Solutions Physical?
We consider exact solutions generated by the inverse scattering technique,
also known as the soliton transformation. In particular, we study the class of
simple real pole solutions. For quite some time, those solutions have been
considered interesting as models of cosmological shock waves. A coordinate
singularity on the wave fronts was removed by a transformation which induces a
null fluid with negative energy density on the wave front. This null fluid is
usually seen as another coordinate artifact, since there seems to be a general
belief that that this kind of solution can be seen as the real pole limit of
the smooth solution generated with a pair of complex conjugate poles in the
transformation. We perform this limit explicitly, and find that the belief is
unfounded: two coalescing complex conjugate poles cannot yield a solution with
one real pole. Instead, the two complex conjugate poles go to a different
limit, what we call a ``pole on a pole''. The limiting procedure is not unique;
it is sensitive to how quickly some parameters approach zero. We also show that
there exists no improved coordinate transformation which would remove the
negative energy density. We conclude that negative energy is an intrinsic part
of this class of solutions.Comment: 13 pages, 3 figure
Dissipation, noise and vacuum decay in quantum field theory
We study the process of vacuum decay in quantum field theory focusing on the
stochastic aspects of the interaction between long and short-wavelength modes.
This interaction results in a diffusive behavior of the reduced Wigner function
describing the state of the long-wavelength modes, and thereby to a finite
activation rate even at zero temperature. This effect can make a substantial
contribution to the total decay rate.Comment: 5 page
Design strategies for shape-controlled magnetic iron oxide nanoparticles
Ferrimagnetic iron oxide nanoparticles (magnetite or maghemite) have been the subject of an intense research, not only for fundamental research but also for their potentiality in a widespread number of practical applications. Most of these studies were focused on nanoparticles with spherical morphology but recently there is an emerging interest on anisometric nanoparticles. This review is focused on the synthesis routes for the production of uniform anisometric magnetite/maghemite nanoparticles with different morphologies like cubes, rods, disks, flowers and many others, such as hollow spheres, worms, stars or tetrapods. We critically analyzed those procedures, detected the key parameters governing the production of these nanoparticles with particular emphasis in the role of the ligands in the final nanoparticle morphology. The main structural and magnetic features as well as the nanotoxicity as a function of the nanoparticle morphology are also described. Finally, the impact of each morphology on the different biomedical applications (hyperthermia, magnetic resonance imaging and drug delivery) are analysed in detail. We would like to dedicate this work to Professor Carlos J. Serna, Instituto de Ciencia de Materiales de Madrid, ICMM/CSIC, for his outstanding contribution in the field of monodispersed colloids and iron oxide nanoparticles. We would like to express our gratitude for all these years of support and inspiration on the occasion of his retirement
Real time approach to tunneling in open quantum systems: decoherence and anomalous diffusion
Macroscopic quantum tunneling is described using the master equation for the
reduced Wigner function of an open quantum system at zero temperature. Our
model consists of a particle trapped in a cubic potential interacting with an
environment characterized by dissipative and normal and anomalous diffusion
coefficients. A representation based on the energy eigenfunctions of the
isolated system, i.e. the system uncoupled to the environment, is used to write
the reduced Wigner function, and the master equation becomes simpler in that
representation. The energy eigenfunctions computed in a WKB approximation
incorporate the tunneling effect of the isolated system and the effect of the
environment is described by an equation that it is in many ways similar to a
Fokker-Planck equation. Decoherence is easily identified from the master
equation and we find that when the decoherence time is much shorter than the
tunneling time the master equation can be approximated by a Kramers like
equation describing thermal activation due to the zero point fluctuations of
the quantum environment. The effect of anomalous diffusion can be dealt with
perturbatively and its overall effect is to inhibit tunneling.Comment: 25 pages, 1 figur
Tuning the magnetic ground state of a novel tetranuclear Nickel(II) molecular complex by high magnetic fields
Electron spin resonance and magnetization data in magnetic fields up to 55 T
of a novel multicenter paramagnetic molecular complex [L_2Ni_4(N_3)(O_2C
Ada)_4](Cl O_4) are reported. In this compound, four Ni centers each having a
spin S = 1 are coupled in a single molecule via bridging ligands (including a
\mu_4-azide) which provide paths for magnetic exchange. Analysis of the
frequency and temperature dependence of the ESR signals yields the relevant
parameters of the spin Hamiltonian, in particular the single ion anisotropy gap
and the g factor, which enables the calculation of the complex energy spectrum
of the spin states in a magnetic field. The experimental results give
compelling evidence for tuning the ground state of the molecule by magnetic
field from a nonmagnetic state at small fields to a magnetic one in strong
fields owing to the spin level crossing at a field of ~25 T.Comment: revised version, accepted for publication in Physical Review
Size dependence of the photoinduced magnetism and long-range ordering in Prussian blue analog nanoparticles of rubidium cobalt hexacyanoferrate
Nanoparticles of rubidium cobalt hexacyanoferrate
(RbCo[Fe(CN)]HO) were synthesized using different
concentrations of the polyvinylpyrrolidone (PVP) to produce four different
batches of particles with characteristic diameters ranging from 3 to 13 nm.
Upon illumination with white light at 5 K, the magnetization of these particles
increases. The long-range ferrimagnetic ordering temperatures and the coercive
fields evolve with nanoparticle size. At 2 K, particles with diameters less
than approximately 10 nm provide a Curie-like magnetic signal.Comment: 10 pages, 6 figures in text, expanded text and dat
Backreaction from non-conformal quantum fields in de Sitter spacetime
We study the backreaction on the mean field geometry due to a non-conformal
quantum field in a Robertson-Walker background. In the regime of small mass and
small deviation from conformal coupling, we compute perturbatively the
expectation value of the stress tensor of the field for a variety of vacuum
states, and use it to obtain explicitly the semiclassical gravity solutions for
isotropic perturbations around de Sitter spacetime, which is found to be
stable. Our results show clearly the crucial role of the non-local terms that
appear in the effective action: they cancel the contribution from local terms
proportional to the logarithm of the scale factor which would otherwise become
dominant at late times and prevent the existence of a stable self-consistent de
Sitter solution. Finally, the opposite regime of a strongly non-conformal field
with a large mass is also considered.Comment: 31 page
Canonical Quantization of the Gowdy Model
The family of Gowdy universes with the spatial topology of a three-torus is
studied both classically and quantum mechanically. Starting with the Ashtekar
formulation of Lorentzian general relativity, we introduce a gauge fixing
procedure to remove almost all of the non-physical degrees of freedom. In this
way, we arrive at a reduced model that is subject only to one homogeneous
constraint. The phase space of this model is described by means of a canonical
set of elementary variables. These are two real, homogeneous variables and the
Fourier coefficients for four real fields that are periodic in the angular
coordinate which does not correspond to a Killing field of the Gowdy
spacetimes. We also obtain the explicit expressions for the line element and
reduced Hamiltonian. We then proceed to quantize the system by representing the
elementary variables as linear operators acting on a vector space of analytic
functionals. The inner product on that space is selected by imposing Lorentzian
reality conditions. We find the quantum states annihilated by the operator that
represents the homogeneous constraint of the model and construct with them the
Hilbert space of physical states. Finally, we derive the general form of the
quantum observables of the model.Comment: 13 pages, Revte
Nuclear Spin-Lattice Relaxation in One-Dimensional Heisenberg Ferrimagnets: Three-Magnon versus Raman Processes
Nuclear spin-lattice relaxation in one-dimensional Heisenberg ferrimagnets is
studied by means of a modified spin-wave theory. We consider the second-order
process, where a nuclear spin flip induces virtual spin waves which are then
scattered thermally via the four-magnon exchange interaction, as well as the
first-order process, where a nuclear spin directly interacts with spin waves
via the hyperfine interaction. We point out a possibility of the three-magnon
relaxation process predominating over the Raman one and suggest model
experiments.Comment: to be published in J. Phys. Soc. Jpn. 73, No. 6 (2004
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