196 research outputs found
Luminescence tuning of MOFs via ligand to metal and metal to metal energy transfer by co-doping of 2∞[Gd2Cl6(bipy)3]*2bipy with europium and terbium
The series of anhydrous lanthanide chlorides LnCl3, Ln=Pr–Tb, and 4,4'-bipyridine (bipy) constitute isotypic MOFs of the formula 2∞[Ln2Cl6(bipy)3]*2bipy. The europium and terbium containing compounds both exhibit luminescence of the referring trivalent lanthanide ions, giving a red luminescence for Eu3+ and a green luminescence for Tb3+ triggered by an efficient antenna effect of the 4,4'-bipyridine linkers. Mixing of different lanthanides in one MOF structure was undertaken to investigate the potential of this MOF system for colour tuning of the luminescence. Based on the gadolinium containing compound, co-doping with different amounts of europium and terbium proves successful and yields solid solutions of the formula 2∞[Gd2-x-yEuxTbyCl6(bipy)3]*2bipy (1–8), 0≤x, y≤0.5. The series of MOFs exhibits the opportunity of tuning the emission colour in-between green and red. Depending on the atomic ratio Gd:Eu:Tb, the yellow region was covered for the first time for an oxygen/carboxylate-free MOF system. In addition to a ligand to metal energy transfer (LMET) from the lowest ligand-centered triplet state of 4,4'-bipyridine, a metal to metal energy transfer (MMET) between 4f-levels from Tb3+ to Eu3+ is as well vital for the emission colour. However, no involvement of Gd3+ in energy transfers is observed rendering it a suitable host lattice ion and connectivity centre for diluting the other two rare earth ions in the solid state. The materials retain their luminescence during activation of the MOFs for microporosity
Chaos in Axially Symmetric Potentials with Octupole Deformation
Classical and quantum mechanical results are reported for the single particle
motion in a harmonic oscillator potential which is characterized by a
quadrupole deformation and an additional octupole deformation. The chaotic
character of the motion is srongly dependent on the quadrupole deformation in
that for a prolate deformation virtually no chaos is discernible while for the
oblate case the motion shows strong chaos when the octupole term is turned on.Comment: 6 pages LaTex plus 4 figures available by contacting the authors
directly, published in PHYS.REV.LETT. 72(1994) 235
Solar PV nowcasting based on skycamera observations
In recent years the installation of PV systems has
increased dramatically in many countries. Annual global installed power has
already reached more than 400 GW in 2017. A major challenge for operators is
that PV system output is highly fluctuating due to cloud movements and other
atmospheric influences. Forecasting of solar irradiation and PV power on
different time scales will, therefore, become more and more important for
different users. As part of the Austrian PV-go-Smart project, several
skycameras have been installed in the region of Upper Austria. In this paper
we show differences and advantages of two skycams and their image qualities.
Algorithms for the detection of clouds, cloud movement, and GHI forecasting
have been developed and validated with ground observation at the Wels site.
This work focusses on image quality issues related to short-term irradiance
forecasting using all-sky cameras, in particular the influence on raindrops
on forecast performance.</p
Microscopic Structure of High-Spin Vibrational Excitations in Superdeformed 190,192,194Hg
Microscopic RPA calculations based on the cranked shell model are performed
to investigate the quadrupole and octupole correlations for excited
superdeformed bands in 190Hg, 192Hg, and 194Hg. The K=2 octupole vibrations are
predicted to be the lowest excitation modes at zero rotational frequency. At
finite frequency, however, the interplay between rotation and vibrations
produces different effects depending on neutron number: The lowest octupole
phonon is rotationally aligned in 190Hg, is crossed by the aligned
two-quasiparticle bands in 192Hg, and retains the K=2 octupole vibrational
character up to the highest frequency in 194Hg. The gamma vibrations are
predicted to be higher in energy and less collective than the octupole
vibrations. From a comparison with the experimental dynamic moments of inertia,
a new interpretation of the observed excited bands invoking the K=2 octupole
vibrations is proposed, which suggests those octupole vibrations may be
prevalent in SD Hg nuclei.Comment: 22 pages, REVTeX, 12 postscript figures are available on reques
Relative spins and excitation energies of superdeformed bands in 190Hg: Further evidence for octupole vibration
An experiment using the Eurogam Phase II gamma-ray spectrometer confirms the
existence of an excited superdeformed (SD) band in 190Hg and its very unusual
decay into the lowest SD band over 3-4 transitions. The energies and dipole
character of the transitions linking the two SD bands have been firmly
established. Comparisons with RPA calculations indicate that the excited SD
band can be interpreted as an octupole-vibrational structure.Comment: 12 pages, latex, 4 figures available via WWW at
http://www.phy.anl.gov/bgo/bc/hg190_nucl_ex.htm
Evaluation of the MOCAGE Chemistry Transport Model during the ICARTT/ITOP Experiment
We evaluate the Meteo-France global chemistry transport 3D model MOCAGE (MOdele de Chimie Atmospherique a Grande Echelle) using the important set of aircraft measurements collected during the ICARRT/ITOP experiment. This experiment took place between US and Europe during summer 2004 (July 15-August 15). Four aircraft were involved in this experiment providing a wealth of chemical data in a large area including the North East of US and western Europe. The model outputs are compared to the following species of which concentration is measured by the aircraft: OH, H2O2, CO, NO, NO2, PAN, HNO3, isoprene, ethane, HCHO and O3. Moreover, to complete this evaluation at larger scale, we used also satellite data such as SCIAMACHY NO2 and MOPITT CO. Interestingly, the comprehensive dataset allowed us to evaluate separately the model representation of emissions, transport and chemical processes. Using a daily emission source of biomass burning, we obtain a very good agreement for CO while the evaluation of NO2 points out incertainties resulting from inaccurate ratio of emission factors of NOx/CO. Moreover, the chemical behavior of O3 is satisfactory as discussed in the paper
Genomic deletion and promoter methylation status of Hypermethylated in Cancer 1 (HIC1) in mantle cell lymphoma
Mantle cell lymphomas (MCL), characterized by the t(11;14)(q13;q32), frequently carry secondary genetic alterations such as deletions in chromosome 17p involving the TP53 locus. Given that the association between TP53-deletions and concurrent mutations of the remaining allele is weak and based on our recent report that the Hypermethylated in Cancer 1 (HIC1) gene, that is located telomeric to the TP53 gene, may be targeted by deletions in 17p in diffuse large B-cell lymphoma (DLBCL), we investigated whether HIC1 inactivations might also occur in MCL. Monoallelic deletions of the TP53 locus were detected in 18 out of 59 MCL (31%), while overexpression of p53 protein occurred in only 8 out of 18 of these MCL (44%). In TP53-deleted MCL, the HIC1 gene locus was co-deleted in 11 out of 18 cases (61%). However, neither TP53 nor HIC1 deletions did affect survival of MCL patients. In most analyzed cases, no hypermethylation of the HIC1 exon 1A promoter was observed (17 out of 20, 85%). However, in MCL cell lines without HIC1-hypermethylation, the mRNA expression levels of HIC1 were nevertheless significantly reduced, when compared to reactive lymph node specimens, pointing to the occurrence of mechanisms other than epigenetic or genetic events for the inactivation of HIC1 in this entity
Case Report Recombinant Chromosome 4 from a Familial Pericentric Inversion: Prenatal and Adulthood Wolf-Hirschhorn Phenotypes
Pericentric inversion of chromosome 4 can give rise to recombinant chromosomes by duplication or deletion of 4p. We report on a familial case of Wolf-Hirschhorn Syndrome characterized by GTG-banding karyotypes, FISH, and array CGH analysis, caused by a recombinant chromosome 4 with terminal 4p16.3 deletion and terminal 4q35.2 duplication. This is an aneusomy due to a recombination which occurred during the meiosis of heterozygote carrier of cryptic pericentric inversion. We also describe the adulthood and prenatal phenotypes associated with the recombinant chromosome 4
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