35: Justice of the Peace appointment, 1792: Manuel Gayoso do Lemos to William Dunbar

Justice of the Peace appointment, 1792: Manuel Gayoso do Lemos to William Dunbarhttps://scholarlycommons.obu.edu/dunbar/1037/thumbnail.jp

Synthesis of high molecular weight water-soluble polymers as low-viscosity latex particles by RAFT aqueous dispersion polymerization in highly salty media

We report the synthesis of sterically-stabilized diblock copolymer particles at 20% w/w solids via reversible addition–fragmentation chain transfer (RAFT) aqueous dispersion polymerization of N,N′-dimethylacrylamide (DMAC) in highly salty media (2.0 M (NH4)2SO4). This is achieved by selecting a well-known zwitterionic water-soluble polymer, poly(2-(methacryloyloxy)ethyl phosphorylcholine) (PMPC), to act as the salt-tolerant soluble precursor block. A relatively high degree of polymerization (DP) can be targeted for the salt-insoluble PDMAC block, which leads to the formation of a turbid free-flowing dispersion of PDMAC-core particles by a steric stabilization mechanism. 1H NMR spectroscopy studies indicate that relatively high DMAC conversions (>99%) can be achieved within a few hours at 30 °C. Aqueous GPC analysis indicates high blocking efficiencies and unimodal molecular weight distributions, although dispersities increase monotonically as higher degrees of polymerization (DPs) are targeted for the PDMAC block. Particle characterization techniques include dynamic light scattering (DLS) and electrophoretic light scattering (ELS) using a state-of-the-art instrument that enables accurate ζ potential measurements in a concentrated salt solution. 1H NMR spectroscopy studies confirm that dilution of the as-synthesized dispersions using deionized water lowers the background salt concentration and hence causes in situ molecular dissolution of the salt-intolerant PDMAC chains, which leads to a substantial thickening effect and the formation of transparent gels. Thus, this new polymerization-induced self-assembly (PISA) formulation enables high molecular weight water-soluble polymers to be prepared in a highly convenient, low-viscosity form. In principle, such aqueous PISA formulations are highly attractive: there are various commercial applications for high molecular weight water-soluble polymers, while the well-known negative aspects of using a RAFT agent (i.e., its cost, color, and malodor) are minimized when targeting such high DPs

An Ultra-Wideband Leaky Lens Antenna for Broadband Spectroscopic Imaging Applications

We present the design, fabrication and characterisation of a broadband leaky lens antenna for broadband, spectroscopic imaging applications. The antenna is designed for operation in the 300-900 GHz band. We integrate the antenna directly into an Al-NbTiN hybrid MKID to measure the beam pattern and absolute coupling efficiency at three frequency bands centred around 350, 650 and 850 GHz, covering the full antenna band. We find an aperture efficiency $\eta_{ap} \approx 0.4$ over the whole frequency band, limited by lens reflections. We find a good match with simulations for both the patterns and efficiency, demonstrating a 1:3 bandwidth in the sub-mm wavelength range for future on-chip spectrometers.Comment: Accepted for Publication at IEEE Transactions on Antennas and Propagatio

On Semantic Gamification

The purpose of this essay is to study the extent in which the semantics for different logical systems can be represented game theoretically. I will begin by considering different definitions of what it means to gamify a semantics, and show completeness and limitative results. In particular, I will argue that under a proper definition of gamification, all finitely algebraizable logics can be gamified, as well as some infinitely algebraizable ones (like Łukasiewicz) and some non-algebraizable (like intuitionistic and van Fraassen supervaluation logic)