627 research outputs found
Thermal phase diagrams of columnar liquid crystals
In order to understand the possible sequence of transitions from the
disordered columnar phase to the helical phase in hexa(hexylthio)triphenylene
(HHTT), we study a three-dimensional planar model with octupolar interactions
inscribed on a triangular lattice of columns. We obtain thermal phase diagrams
using a mean-field approximation and Monte Carlo simulations. These two
approaches give similar results, namely, in the quasi one-dimensional regime,
as the temperature is lowered, the columns order with a linear polarization,
whereas helical phases develop at lower temperatures. The helicity patterns of
the helical phases are determined by the exact nature of the frustration in the
system, itself related to the octupolar nature of the molecules.Comment: 12 pages, 9 figures, ReVTe
Pair formation and collapse in imbalanced Fermion populations with unequal masses
We present an exact Quantum Monte Carlo study of the effect of unequal masses
on pair formation in Fermionic systems with population imbalance loaded into
optical lattices. We have considered three forms of the attractive interaction
and find in all cases that the system is unstable and collapses as the mass
difference increases and that the ground state becomes an inhomogeneous
collapsed state. We also address the question of canonical vs grand canonical
ensemble and its role, if any, in stabilizing certain phases
The impact of charge transfer and structural disorder on the thermoelectric properties of cobalt intercalated TiS2
A family of phases, CoxTiS2 (0 †x †0.75) has been prepared and characterised by powder X-ray and neutron diffraction, electrical and thermal transport property measurements, thermal analysis and SQUID magnetometry. With increasing cobalt content, the structure evolves from a disordered arrangement of cobalt ions in octahedral sites located in the van der Waalsâ gap (x †0.2), through three different ordered vacancy phases, to a second disordered phase at x â„ 0.67. Powder neutron diffraction reveals that both octahedral and tetrahedral inter-layer sites are occupied in Co0.67TiS2. Charge transfer from the cobalt guest to the TiS2 host affords a systematic tuning of the electrical and thermal transport properties. At low levels of cobalt intercalation (x < 0.1), the charge transfer increases the electrical conductivity sufficiently to offset the concomitant reduction in |S|. This, together with a reduction in the overall thermal conductivity leads to thermoelectric
figures of merit that are 25 % higher than that of TiS2, ZT reaching 0.30 at 573 K for CoxTiS2 with 0.04 †x †0.08. Whilst the electrical conductivity is further increased at higher cobalt contents, the reduction in |S| is more marked due to the higher charge carrier concentration. Furthermore both the charge carrier and lattice contributions to the thermal conductivity are
increased in the electrically conductive ordered-vacancy phases, with the result that the thermoelectric performance is significantly degraded. These results illustrate the competition between the effects of charge transfer from guest to host and the disorder generated when cobalt cations are incorporated in the inter-layer space
Superconductivity and antiferromagnetism in a hard-core boson spin-1 model in two dimensions
A model of hard-core bosons and spin-1 sites with single-ion anisotropy is
proposed to approximately describe hole pairs moving in a background of
singlets and triplets with the aim of exploring the relationship between
superconductivity and antiferromagnetism. The properties of this model at zero
temperature were investigated using quantum Monte Carlo techniques. The most
important feature found is the suppression of superconductivity, as long range
coherence of preformed pairs, due to the presence of both antiferromagnetism
and excitations. Indications of charge ordered and other phases are
also discussed.Comment: One figure, one reference, adde
Regional but not global temperature variability underestimated by climate models at supradecadal timescales
Knowledge of the characteristics of natural climate variability is vital when assessing the range of plausible future climate trajectories in the next decades to centuries. The reliable detection of climate fluctuations on multidecadal to centennial timescales depends on proxy reconstructions and model simulations, as the instrumental record extends back only a few decades in most parts of the world. Systematic comparisons between model-simulated and proxy-based inferences of natural variability, however, often seem contradictory. Locally, simulated temperature variability is consistently smaller on multidecadal and longer timescales than is indicated by proxy-based reconstructions, implying that climate models or proxy interpretations might have deficiencies. In contrast, at global scales, studies found agreement between simulated and proxy reconstructed temperature variations. Here we review the evidence regarding the scale of natural temperature variability during recent millennia. We identify systematic reconstruction deficiencies that may contribute to differing local and global modelâproxy agreement but conclude that they are probably insufficient to resolve such discrepancies. Instead, we argue that regional climate variations persisted for longer timescales than climate models simulating past climate states are able to reproduce. This would imply an underestimation of the regional variability on multidecadal and longer timescales and would bias climate projections and attribution studies. Thus, efforts are needed to improve the simulation of natural variability in climate models accompanied by further refining proxy-based inferences of variability.This study was undertaken by members of CVAS and 2k Network, working groups of the Past Global Changes (PAGES) Global Research association. This is a contribution to the SPACE ERC, STACY and PALMOD projects. The SPACE ERC project has received funding from the European Research Council (ERC) under the European Unionâs Horizon 2020 research and innovation programme (grant agreement no. 716092). STACY has been funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation, project no. 395588486). This work has also been supported by the German Federal Ministry of Education and Research (BMBF), through the PalMod project (subprojects 01LP1926B (O.B.), 01LP1926D (M.C.) and 01LP1926C (B.E., P.S. and N.W.)) from the Research for Sustainability initiative (FONA). B.E. is supported by the Heinrich Böll Foundation. E.M.-C. was supported by the PARAMOUR project, funded by the Fonds de la Recherche ScientifiqueâFNRS and the FWO under the Excellence of Science (EOS) programme (grant no. O0100718F, EOS ID no. 30454083). A.H. was supported by a Legacy Grant from the Australian Research Council Centre of Excellence for Australian Biodiversity and Heritage. B.M. was supported by LINKA20102 and the Spanish Ministry of Science and Innovation project CEX2018â000794âS. The work originated from discussions at the CVAS working group of PAGES at a workshop at the Internationales Wissenschaftsforum Heidelberg, which was funded by a Hengstberger Prize. We thank N. Beech, C. Brierley, F. Gonzalez-Rouco and M. MacPartland for comments on earlier drafts of the manuscript. This manuscript uses data provided by the World Climate Research Programmeâs Working Group on Coupled Modelling, which is responsible for CMIP and PMIP. We thank the research groups for producing and kindly making their model outputs, measurements and palaeoclimate reconstructions available to us. Editorial assistance, in the form of language editing and correction, was provided by XpertScientific Editing and Consulting Services. We acknowledge support by the Open Access Publication Funds of Alfred-Wegener-Institut Helmholtz Zentrum fĂŒr Polar- und Meeresforschung.Peer ReviewedPostprint (author's final draft
Teensâ Self-Efficacy to Deal with Dating Violence as Victim, Perpetrator or Bystander
Multiple studies have demonstrated that adolescent dating violence is highly prevalent and is associated with internalizing and externalizing problems. A number of prevention initiatives are being implemented in North American high schools. Such initiatives aim to raise awareness among potential victims and offenders, and also among peer bystanders. As teenagers mainly reach out to their peers when experiencing adversity, it is important to address adolescentsâ efficacy in dealing with witnessing dating violence or with friends disclosing dating abuse, in addition to increasing their ability to deal with experienced dating violence victimization or perpetration. The aim of this study is to explore adolescentsâ self-efficacy to deal with dating violence victimization and perpetration in their relationships and those of their peers. A paper-and-pencil questionnaire was completed by 259 14â18-year-olds in Quebec, Canada. The data allow building insight into adolescentsâ confidence to reach out for help or to help others in a situation of dating violence victimization and perpetration. We also considered the impact of gender and dating victimization history. Results suggest that dating violence prevention can build on teensâ self-efficacy to deal with dating violence and offer them tools to do so efficiently
Epidemics on contact networks: a general stochastic approach
Dynamics on networks is considered from the perspective of Markov stochastic
processes. We partially describe the state of the system through network motifs
and infer any missing data using the available information. This versatile
approach is especially well adapted for modelling spreading processes and/or
population dynamics. In particular, the generality of our systematic framework
and the fact that its assumptions are explicitly stated suggests that it could
be used as a common ground for comparing existing epidemics models too complex
for direct comparison, such as agent-based computer simulations. We provide
many examples for the special cases of susceptible-infectious-susceptible (SIS)
and susceptible-infectious-removed (SIR) dynamics (e.g., epidemics propagation)
and we observe multiple situations where accurate results may be obtained at
low computational cost. Our perspective reveals a subtle balance between the
complex requirements of a realistic model and its basic assumptions.Comment: Main document: 16 pages, 7 figures. Electronic Supplementary Material
(included): 6 pages, 1 tabl
Dopant-dependent impact of Mn-site doping on the critical-state manganites: R0.6Sr0.4MnO3 (R=La, Nd, Sm, and Gd)
Versatile features of impurity doping effects on perovskite manganites,
SrMnO, have been investigated with varying the doing
species as well as the -dependent one-electron bandwidth. In
ferromagnetic-metallic manganites (=La, Nd, and Sm), a few percent of Fe
substitution dramatically decreases the ferromagnetic transition temperature,
leading to a spin glass insulating state with short-range charge-orbital
correlation. For each species, the phase diagram as a function of Fe
concentration is closely similar to that for SrMnO
obtained by decreasing the ionic radius of site, indicating that Fe doping
in the phase-competing region weakens the ferromagnetic double-exchange
interaction, relatively to the charge-orbital ordering instability. We have
also found a contrastive impact of Cr (or Ru) doping on a spin-glass insulating
manganite (=Gd). There, the impurity-induced ferromagnetic magnetization is
observed at low temperatures as a consequence of the collapse of the inherent
short-range charge-orbital ordering, while Fe doping plays only a minor role.
The observed opposite nature of impurity doping may be attributed to the
difference in magnitude of the antiferromagnetic interaction between the doped
ions.Comment: 7 pages, 6 figure
Hatano-Nelson model with a periodic potential
We study a generalisation of the Hatano-Nelson Hamiltonian in which a
periodic modulation of the site energies is present in addition to the usual
random distribution. The system can then become localized by disorder or
develop a band gap, and the eigenspectrum shows a wide variety of topologies.
We determine the phase diagram, and perform a finite size scaling analysis of
the localization transition.Comment: 7 pages, 10 figure
Nature of the quantum phase transitions in the two-dimensional hardcore boson model
We use two Quantum Monte Carlo algorithms to map out the phase diagram of the
two-dimensional hardcore boson Hubbard model with near () and next near
() neighbor repulsion. At half filling we find three phases: Superfluid
(SF), checkerboard solid and striped solid depending on the relative values of
, and the kinetic energy. Doping away from half filling, the
checkerboard solid undergoes phase separation: The superfluid and solid phases
co-exist but not as a single thermodynamic phase. As a function of doping, the
transition from the checkerboard solid is therefore first order. In contrast,
doping the striped solid away from half filling instead produces a striped
supersolid phase: Co-existence of density order with superfluidity as a single
phase. One surprising result is that the entire line of transitions between the
SF and checkerboard solid phases at half filling appears to exhibit dynamical
O(3) symmetry restoration. The transitions appear to be in the same
universality class as the special Heisenberg point even though this symmetry is
explicitly broken by the interaction.Comment: 10 pages, 14 eps figures, include
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