A simple reactive-transport model of calcite precipitation in soils and other porous media

Calcite formation in soils and other porous media generally occurs around a localised source of reactants, such as a plant root or soil macro-pore, and the rate depends on the transport of reactants to and from the precipitation zone as well as the kinetics of the precipitation reaction itself. However most studies are made in well mixed systems, in which such transport limitations are largely removed. We developed a mathematical model of calcite precipitation near a source of base in soil, allowing for transport limitations and precipitation kinetics. We tested the model against experimentally-determined rates of calcite precipitation and reactant concentration–distance profiles in columns of soil in contact with a layer of HCO3−-saturated exchange resin. The model parameter values were determined independently. The agreement between observed and predicted results was satisfactory given experimental limitations, indicating that the model correctly describes the important processes. A sensitivity analysis showed that all model parameters are important, indicating a simpler treatment would be inadequate. The sensitivity analysis showed that the amount of calcite precipitated and the spread of the precipitation zone were sensitive to parameters controlling rates of reactant transport (soil moisture content, salt content, pH, pH buffer power and CO2 pressure), as well as to the precipitation rate constant. We illustrate practical applications of the model with two examples: pH changes and CaCO3 precipitation in the soil around a plant root, and around a soil macro-pore containing a source of base such as urea

Optically pure heterobimetallic helicates from self-assembly and click strategies

Single diastereomer, diamagnetic, octahedral Fe(II) tris chelate complexes are synthesised that contain three pendant pyridine proligands pre-organised for coordination to a second metal. They bind Cu(I) and Ag(I) with coordination geometry depending on the identity of the metal and the detail of the ligand structure, but for example homohelical (ΔFe,ΔCu) configured systems with unusual trigonal planar Cu cations are formed exclusively in solution as shown by VT-NMR and supported by DFT calculations. Similar heterobimetallic tris(triazole) complexes are synthesised via clean CuAAC reactions at a tris(alkynyl) complex, although here the configurations of the two metals differ (ΔFe,ΛCu), leading to the first optically pure heterohelicates. A second series of Fe complexes perform less well in either strategy as a result of lack of preorganisation

Rice genotype differences in tolerance of zinc-deficient soils: evidence for the importance of root-induced changes in the rhizosphere

The Supplementary Material for this article can be found online at: http://journal.frontiersin.org/article/10.3389/fpls.2015.01160Zinc (Zn) deficiency is a major constraint to rice production and Zn is also often deficient in humans with rice-based diets. Efforts to breed more Zn-efficient rice are constrained by poor understanding of the mechanisms of tolerance to deficiency. Here we assess the contributions of root growth and root Zn uptake efficiency, and we seek to explain the results in terms of specific mechanisms. We made a field experiment in a highly Zn-deficient rice soil in the Philippines with deficiency-tolerant and -sensitive genotypes, and measured growth, Zn uptake and root development. We also measured the effect of planting density. Tolerant genotypes produced more crown roots per plant and had greater uptake rates per unit root surface area; the latter was at least as important as root number to overall tolerance. Tolerant and sensitive genotypes took up more Zn per plant at greater planting densities. The greater uptake per unit root surface area, and the planting density effect can only be explained by root-induced changes in the rhizosphere, either solubilizing Zn, or neutralizing a toxin that impedes Zn uptake (possibly HCO − 3 HCO3− or Fe2+), or both. Traits for these and crown root number are potential breeding targets.This research was funded by a grant from the UK's Biotechnology and Biological Sciences Research Council (BBSRC, Grant Ref. BB/J011584/1) under the Sustainable Crop Production Research for International Development (SCPRID) programme, a joint multi-national initiative of BBSRC, the UK Government's Department for International Development (DFID) and (through a grant awarded to BBSRC) the Bill & Melinda Gates Foundation. Support to AKN in the form of a fellowship awarded by the Japan Society for the Promotion of Science (JSPS) is gratefully acknowledged

Constructing Spin Interference Devices from Nanometric Rings

The study of nanospintronic devices utilizing coherent transport through molecular scale multiply-connected geometries in the presence of moderate magnetic fields is presented. It is shown how two types of simple devices, spin filters and spin splitters (or Stern-Gerlach devices) may be constructed from molecular nanometric rings utilizing the Aharonov-Bohm effect. The current is calculated within a single electron approximation and within a many-body master equation approach where charging effects are accounted for in the Coulomb Blockade regime. We provide rules and tools to develop and analyze efficient spintronic devices based on nanometric interferometers.Comment: 16 pages, 8 figures, submitted to Phys. Rev.

Evidence for a Young Stellar Population in NGC 5018

Two absorption line indices, Ca II and Hdelta/FeI4045, measured from high resolution spectra are used with evolutionary synthesis models to verify the presence of a young stellar population in NGC 5018. The derived age of this population is about ~2.8 Gyr with a metallicity roughly solar and it completely dominates the integrated light of the galaxy near 4000 A.Comment: 13 pages, 7 figures (figs 3-7 are color figures), to be published in the May 2000 issue of the Astrophysical Journa

Diffuse retro-reflective imaging for improved mosquito tracking around human baited bednets

Robust imaging techniques for tracking insects have been essential tools in numerous laboratory and field studies on pests, beneficial insects and model systems. Recent innovations in optical imaging systems and associated signal processing have enabled detailed characterisation of nocturnal mosquito behaviour around bednets and improvements in bednet design, a global essential for protecting populations against malaria. Nonetheless, there remain challenges around ease of use for large scale in situ recordings and extracting data reliably in the critical areas of the bednet where the optical signal is attenuated. Here we introduce a retro-reflective screen at the back of the measurement volume, which can simultaneously provide diffuse illumination, and remove optical alignment issues whilst requiring only one-sided access to the measurement space. The illumination becomes significantly more uniform, although, noise removal algorithms are needed to reduce the effects of shot noise particularly across low intensity bednet regions. By systematically introducing mosquitoes in front and behind the bednet in lab experiments we are able to demonstrate robust tracking in these challenging areas. Overall, the retro-reflective imaging setup delivers mosquito segmentation rates in excess of 90% compared to less than 70% with back-lit systems

Flutter Research on Skin Panels

Representative experimental results are presented to show the current status of the panel flutter problem. Results are presented for unstiffened rectangular panels and for rectangular panels stiffened by corrugated backing. Flutter boundaries are established for all types of panels when considered on the basis of equivalent isotropic plates. The effects of Mach number, differential pressure, and aerodynamic heating on panel flutter are discussed. A flutter analysis of orthotropic panels is presented in the appendix

Nonperturbative QCD Coupling and its β\beta function from Light-Front Holography

The light-front holographic mapping of classical gravity in AdS space, modified by a positive-sign dilaton background, leads to a nonperturbative effective coupling $\alpha_s^{AdS}(Q^2)$. It agrees with hadron physics data extracted from different observables, such as the effective charge defined by the Bjorken sum rule, as well as with the predictions of models with built-in confinement and lattice simulations. It also displays a transition from perturbative to nonperturbative conformal regimes at a momentum scale $\sim 1$ GeV. The resulting $\beta$ function appears to capture the essential characteristics of the full $\beta$ function of QCD, thus giving further support to the application of the gauge/gravity duality to the confining dynamics of strongly coupled QCD. Commensurate scale relations relate observables to each other without scheme or scale ambiguity. In this paper we extrapolate these relations to the nonperturbative domain, thus extending the range of predictions based on $\alpha_s^{AdS}(Q^2)$.Comment: 32 pages, 7 figures. Final version published in Phys. Rev.

Light-Front Quantization and AdS/QCD: An Overview

We give an overview of the light-front holographic approach to strongly coupled QCD, whereby a confining gauge theory, quantized on the light front, is mapped to a higher-dimensional anti de Sitter (AdS) space. The framework is guided by the AdS/CFT correspondence incorporating a gravitational background asymptotic to AdS space which encodes the salient properties of QCD, such as the ultraviolet conformal limit at the AdS boundary at $z \to 0$, as well as modifications of the geometry in the large $z$ infrared region to describe confinement and linear Regge behavior. There are two equivalent procedures for deriving the AdS/QCD equations of motion: one can start from the Hamiltonian equation of motion in physical space time by studying the off-shell dynamics of the bound state wavefunctions as a function of the invariant mass of the constituents. To a first semiclassical approximation, where quantum loops and quark masses are not included, this leads to a light-front Hamiltonian equation which describes the bound state dynamics of light hadrons in terms of an invariant impact variable $\zeta$ which measures the separation of the partons within the hadron at equal light-front time. Alternatively, one can start from the gravity side by studying the propagation of hadronic modes in a fixed effective gravitational background. Both approaches are equivalent in the semiclassical approximation. This allows us to identify the holographic variable $z$ in AdS space with the impact variable $\zeta$. Light-front holography thus allows a precise mapping of transition amplitudes from AdS to physical space-time. The internal structure of hadrons is explicitly introduced and the angular momentum of the constituents plays a key role.Comment: Invited talk presented by GdT at the XIV School of Particles and Fields, Morelia, Mexico, November 8-12, 201

SiFTO: An Empirical Method for Fitting SNe Ia Light Curves

We present SiFTO, a new empirical method for modeling type Ia supernovae (SNe Ia) light curves by manipulating a spectral template. We make use of high-redshift SN observations when training the model, allowing us to extend it bluer than rest frame U. This increases the utility of our high-redshift SN observations by allowing us to use more of the available data. We find that when the shape of the light curve is described using a stretch prescription, applying the same stretch at all wavelengths is not an adequate description. SiFTO therefore uses a generalization of stretch which applies different stretch factors as a function of both the wavelength of the observed filter and the stretch in the rest-frame B band. We compare SiFTO to other published light-curve models by applying them to the same set of SN photometry, and demonstrate that SiFTO and SALT2 perform better than the alternatives when judged by the scatter around the best fit luminosity distance relationship. We further demonstrate that when SiFTO and SALT2 are trained on the same data set the cosmological results agree.Comment: Modified to better match published version in Ap