1,919 research outputs found
Commensurate to incommensurate magnetic phase transition in Honeycomb-lattice pyrovanadate Mn2V2O7
We have synthesized single crystalline sample of MnVO using
floating zone technique and investigated the ground state using magnetic
susceptibility, heat capacity and neutron diffraction. Our magnetic
susceptibility and heat capacity reveal two successive magnetic transitions at
19 K and 11.8 K indicating two distinct magnetically
ordered phases. The single crystal neutron diffraction study shows that in the
temperature () range 11.8 K 19 K the magnetic structure is
commensurate with propagation vector , while upon lowering
temperature below 11.8 K an incommensurate magnetic order emerges
with and the magnetic structure can be represented by
cycloidal modulation of the Mn spin in plane. We are reporting this
commensurate to incommensurate transition for the first time. We discuss the
role of the magnetic exchange interactions and spin-orbital coupling on the
stability of the observed magnetic phase transitions.Comment: 8 pages, 7 figure
Structural and Magnetic Investigations of Single-Crystals of the Neodymium Zirconate Pyrochlore, Nd2Zr2O7
We report structural and magnetic properties studies of large high quality
single-crystals of the frustrated magnet, NdZrO. Powder x-ray
diffraction analysis confirms that NdZrO adopts the pyrochlore
structure. Room-temperature x-ray diffraction and time-of-flight neutron
scattering experiments show that the crystals are stoichiometric in composition
with no measurable site disorder. The temperature dependence of the magnetic
susceptibility shows no magnetic ordering at temperatures down to 0.5 K. Fits
to the magnetic susceptibility data using a Curie-Weiss law reveal a
ferromagnetic coupling between the Nd moments. Magnetization versus field
measurements show a local Ising anisotropy along the axes of the
Nd ions in the ground state. Specific heat versus temperature
measurements in zero applied magnetic field indicate the presence of a thermal
anomaly below K, but no evidence of magnetic ordering is observed down
to 0.5 K. The experimental temperature dependence of the single-crystal bulk dc
susceptibility and isothermal magnetization are analyzed using crystal field
theory and the crystal field parameters and exchange coupling constants
determined.Comment: 10 pages, 6 figures, 4 tables. Accepted for publication in Physical
Review
Enabling Technologies for the Future of Chemical Synthesis.
Technology is evolving at breakneck pace, changing the way we communicate, travel, find out information, and live our lives. Yet chemistry as a science has been slower to adapt to this rapidly shifting world. In this Outlook we use highlights from recent literature reports to describe how progresses in enabling technologies are altering this trend, permitting chemists to incorporate new advances into their work at all levels of the chemistry development cycle. We discuss the benefits and challenges that have arisen, impacts on academic-industry relationships, and future trends in the area of chemical synthesis.We are grateful to the Woolf Fisher Trust (D.E.F), Syngenta Crop Protection AG (C.B.) and EPSRC (S.V.L., grant codes EP/K009494/1, EP/M004120/1 and EP/K039520/1) for financial assistance.This is the final version of the article. It first appeared from the American Chemical Society via https://doi.org/10.1021/acscentsci.6b0001
Inference in Probabilistic Logic Programs with Continuous Random Variables
Probabilistic Logic Programming (PLP), exemplified by Sato and Kameya's
PRISM, Poole's ICL, Raedt et al's ProbLog and Vennekens et al's LPAD, is aimed
at combining statistical and logical knowledge representation and inference. A
key characteristic of PLP frameworks is that they are conservative extensions
to non-probabilistic logic programs which have been widely used for knowledge
representation. PLP frameworks extend traditional logic programming semantics
to a distribution semantics, where the semantics of a probabilistic logic
program is given in terms of a distribution over possible models of the
program. However, the inference techniques used in these works rely on
enumerating sets of explanations for a query answer. Consequently, these
languages permit very limited use of random variables with continuous
distributions. In this paper, we present a symbolic inference procedure that
uses constraints and represents sets of explanations without enumeration. This
permits us to reason over PLPs with Gaussian or Gamma-distributed random
variables (in addition to discrete-valued random variables) and linear equality
constraints over reals. We develop the inference procedure in the context of
PRISM; however the procedure's core ideas can be easily applied to other PLP
languages as well. An interesting aspect of our inference procedure is that
PRISM's query evaluation process becomes a special case in the absence of any
continuous random variables in the program. The symbolic inference procedure
enables us to reason over complex probabilistic models such as Kalman filters
and a large subclass of Hybrid Bayesian networks that were hitherto not
possible in PLP frameworks. (To appear in Theory and Practice of Logic
Programming).Comment: 12 pages. arXiv admin note: substantial text overlap with
arXiv:1203.428
Effective Hamiltonian approach to adiabatic approximation in open systems
The adiabatic approximation in open systems is formulated through the
effective Hamiltonian approach. By introducing an ancilla, we embed the open
system dynamics into a non-Hermitian quantum dynamics of a composite system,
the adiabatic evolution of the open system is then defined as the adiabatic
dynamics of the composite system. Validity and invalidity conditions for this
approximation are established and discussed. A High-order adiabatic
approximation for open systems is introduced. As an example, the adiabatic
condition for an open spin- particle in time-dependent magnetic
fields is analyzed.Comment: 6 pages, 2 figure
Senses of Sen: Reflections on Amartya Sen’s Ideas of Justice
This review essay explores how Amartya Sen’s recent book, The Idea of Justice, is relevant and important for the development and assessment of transnational theories and applications to transnational justice and legal education programs. The essay captures a trans-jural dialogue of multinational scholars and teachers, discussing Sen’s contributions to moral justice theory (criticizing programs for “transcendental institutionalism” (like Rawlsian theory) and instead focusing on “comparative broadening” including empirical, relative, and comparative assessments of programs to ameliorate injustice in the world in its comparative concreteness (as in Indian social justice theory and Adam Smith’s Theory of Moral Sentiments and related work). The authors are professors in the transnational legal education program, the Center for Transnational Legal Studies, sponsored by over 25 different law schools, located in London. They teach courses in a wide variety of subjects, including comparative legal theory, constitutional law, business and legal ethics, moral and legal philosophy, international and comparative law, capital markets and business law, emergency powers, international dispute resolution and a variety of other common and civil law subjects
Functional expression of NF1 tumor suppressor protein: association with keratin intermediate filaments during the early development of human epidermis
BACKGROUND: NF1 refers to type 1 neurofibromatosis syndrome, which has been linked with mutations of the large NF1 gene. NF1 tumor suppressor protein, neurofibromin, has been shown to regulate ras: the NF1 protein contains a GTPase activating protein (GAP) related domain which functions as p21rasGAP. Our studies have previously demonstrated that the NF1 protein forms a high affinity association with cytokeratin 14 during the formation of desmosomes and hemidesmosomes in cultured keratinocytes. METHODS: The expression of NF1 protein was studied in developing human epidermis using western transfer analysis, indirect immunofluorescence, confocal laser scanning microscopy, immunoelectron microscopy, and in situ hybridization. RESULTS: The expression of NF1 protein was noted to be highly elevated in the periderm at 8 weeks estimated gestational age (EGA) and in the basal cells at 8–14 weeks EGA. During this period, NF1 protein was associated with cytokeratin filaments terminating to desmosomes and hemidesmosomes. NF1 protein did not display colocalization with α-tubulin or actin of the cytoskeleton, or with adherens junction proteins. CONCLUSIONS: These results depict an early fetal period when the NF1 tumor suppressor is abundantly expressed in epidermis and associated with cytokeratin filaments. This period is characterized by the initiation of differentiation of the basal cells, maturation of the basement membrane zone as well as accentuated formation of selected cellular junctions. NF1 tumor suppressor may function in the regulation of epidermal histogenesis via controlling the organization of the keratin cytoskeleton during the assembly of desmosomes and hemidesmosomes
The presence of N-terminal methionine on nascent protein of rat liver and rabbit reticulocytes and its cleavage during polypeptide-chain elongation
Quantum hypercomputation based on the dynamical algebra su(1,1)
An adaptation of Kieu's hypercomputational quantum algorithm (KHQA) is
presented. The method that was used was to replace the Weyl-Heisenberg algebra
by other dynamical algebra of low dimension that admits infinite-dimensional
irreducible representations with naturally defined generalized coherent states.
We have selected the Lie algebra , due to that this algebra
posses the necessary characteristics for to realize the hypercomputation and
also due to that such algebra has been identified as the dynamical algebra
associated to many relatively simple quantum systems. In addition to an
algebraic adaptation of KHQA over the algebra , we
presented an adaptations of KHQA over some concrete physical referents: the
infinite square well, the infinite cylindrical well, the perturbed infinite
cylindrical well, the P{\"o}sch-Teller potentials, the Holstein-Primakoff
system, and the Laguerre oscillator. We conclude that it is possible to have
many physical systems within condensed matter and quantum optics on which it is
possible to consider an implementation of KHQA.Comment: 25 pages, 1 figure, conclusions rewritten, typing and language errors
corrected and latex format changed minor changes elsewhere and
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