An exactly solvable lattice model for inhomogeneous interface growth

We study the dynamics of an exactly solvable lattice model for inhomogeneous interface growth. The interface grows deterministically with constant velocity except along a defect line where the growth process is random. We obtain exact expressions for the average height and height fluctuations as functions of space and time for an initially flat interface. For a given defect strength there is a critical angle between the defect line and the growth direction above which a cusp in the interface develops. In the mapping to polymers in random media this is an example for the transverse Meissner effect. Fluctuations around the mean shape of the interface are Gaussian.Comment: 10 pages, late

Importance of boundary effects in diffusion of hydrocarbon molecules in a one-dimensional zeolite channel

Single-file diffusion of propane and toluene molecules inside a narrow, effectively one-dimensional zeolite pore was experimentally studied by Czaplewski {\sl et al.} Using a stochastic lattice gas approach, we obtain an analytical description of this process for the case of single-component loading. We show that a good quantitative agreement with the experimental data for the desorption temperature of the hydrocarbon molecules can be obtained if the desorption process from the boundary is associated with a higher activation energy than the diffusion process in the bulk. We also present Dynamical Monte Carlo simulation results for two-component loading which demonstrate in agreement with the experimental findings the effects of mutual blockage of the molecules due to single-file diffusion.Comment: Revised and final versio

Diffusion of a hydrocarbon mixture in a one-dimensional zeolite channel: an exclusion model approach

Zeolite channels can be used as effective hydrocarbon traps. Earlier experiments (Czaplewski {\sl et al.}, 2002) show that the presence of large aromatic molecules (toluene) block the diffusion of light hydrocarbon molecules (propane) inside the narrow pore of a zeolite sample. As a result, the desorption temperature of propane is significantly higher in the binary mixture than in the single component case. In order to obtain further insight into these results, we use a simple lattice gas model of diffusion of hard-core particles to describe the diffusive transport of two species of molecules in a one-dimensional zeolite channel. Our dynamical Monte Carlo simulations show that taking into account an Arrhenius dependence of the single molecule diffusion coefficient on temperature, one can explain many significant features of the temperature programmed desorption profile observed in experiments. However, on a closer comparison of the experimental curve and our simulation data, we find that it is not possible to reproduce the higher propane current than toluene current near the desorption peak seen in experiment. We argue that this is caused by a violation of strict single-file behavior.Comment: Accepted for publication in the special issue "Diffusion in Micropores" of the journal Microporous and Mesoporous Material

Nonequilibrium field-induced phase separation in single-file diffusion

Using an analytically tractable lattice model for reaction-diffusion processes of hard-core particles we demonstrate that under nonequilibrium conditions phase coexistence may arise even if the system is effectively one-dimensional as e.g. in the channel system of some zeolites or in artificial optical lattices. In our model involving two species of particles a steady-state particle current is maintained by a density gradient between the channel boundaries and by the influence of an external driving force. This leads to the development of a fluctuating but always microscopically sharp interface between two domains of different densities which are fixed by the boundary chemical potentials. The internal structure of the interface becomes very simple for strong driving force. We calculate the drift velocity and diffusion coefficient of the interface in terms of the microscopic model parameters.Comment: 38 pages, 2 figure

Density profiles, dynamics, and condensation in the ZRP conditioned on an atypical current

We study the asymmetric zero-range process (ZRP) with L sites and open boundaries, conditioned to carry an atypical current. Using a generalized Doob h-transform we compute explicitly the transition rates of an effective process for which the conditioned dynamics are typical. This effective process is a zero-range process with renormalized hopping rates, which are space dependent even when the original rates are constant. This leads to non-trivial density profiles in the steady state of the conditioned dynamics, and, under generic conditions on the jump rates of the unconditioned ZRP, to an intriguing supercritical bulk region where condensates can grow. These results provide a microscopic perspective on macroscopic fluctuation theory (MFT) for the weakly asymmetric case: It turns out that the predictions of MFT remain valid in the non-rigorous limit of finite asymmetry. In addition, the microscopic results yield the correct scaling factor for the asymmetry that MFT cannot predict.Comment: 26 pages, 4 figure

Robustness of spontaneous symmetry breaking in a bridge model

A simple two-species asymmetric exclusion model in one dimension with bulk and boundary exchanges of particles is investigated for the existence of spontaneous symmetry breaking. The model is a generalization of the bridge model for which earlier studies have confirmed the existence of symmetry-broken phases, and the motivation here is to check the robustness of the observed symmetry breaking with respect to additional dynamical moves, in particular, the boundary exchange of the two species of particles. Our analysis, based on general considerations, mean-field approximation and numerical simulations, shows that the symmetry breaking in the bridge model is sustained for a range of values of the boundary exchange rate. Moreover, the mechanism through which symmetry is broken is similar to that in the bridge model. Our analysis allows us to plot the complete phase diagram of the model, demarcating regions of symmetric and symmetry-broken phases.Comment: 26 pages, 12 figures, v2: minor changes with an added appendix, published versio