Two-year continuous measurements of carbonaceous aerosols in urban Beijing, China: temporal variations, characteristics and source analyses

Organic carbon (OC) and elemental carbon (EC) in the PM2.5 of urban Beijing were measured hourly with a semi-continuous thermal-optical analyzer from Jan 1, 2013 to Dec 31, 2014. The annual average OC and EC concentrations in Beijing were 17.0 ± 12.4 and 3.4 ± 2.0 μg/m3 for 2013, and 16.8 ± 14.5 and 3.5 ± 2.9 μg/m3 for 2014. It is obvious that the annual average concentrations of OC and EC in 2014 were not less than those in 2013 while the annual average PM2.5 concentration (89.4 μg/m3) in 2014 was slightly reduced as compared to that (96.9 μg/m3) in 2013. Strong seasonality of the OC and EC concentrations were found with high values during the heating seasons and low values during the non-heating seasons. The diurnal cycles of OC and EC characterized by higher values at night and in the morning were caused by primary emissions, secondary transformation and stable meteorological condition. Due to increasing photochemical activity, the OC peaks were observed at approximately noon. No clear weekend effects were observed. Interestingly, in the early mornings on weekends in the autumn and winter, the OC and EC concentrations were close to or higher than those on weekdays. Our data also indicate that high OC and EC concentrations were closely associated with their potential source areas which were determined based on the potential source contribution function analysis. High potential source areas were identified and were mainly located in the south of Beijing and the plain of northern China. A much denser source region was recorded in the winter than in the other seasons, indicating that local and regional transport over regional scales are the most important. These results demonstrate that both regional transport from the southern regions and local accumulation could lead to the enhancements of OC and EC and likely contribute to the severe haze pollution in Beijing

Exploring the inorganic and organic nitrate aerosol formation regimes at a suburban site on the North China Plain

Nitrate-driven aerosol pollution frequently occurs during winter over the North China Plain (NCP). Extensive studies have focused on inorganic nitrate formation, but few have focused on organic nitrates in China, preduding a thorough understanding of the nitrogen cycle and nitrate aerosol formation. Here, the inorganic (NO3,inorg) and organic nitrate (NO3,org) formation regimes under aerosol liquid water (ALW) and aerosol acidity (pH) influences were investigated during winter over the NCP based on data derived from an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). The campaign-averaged concentration of the total nitrate was 53 mu g m(3), with a 13% contribution from NO3,org, which exhibited a significantly decreased contribution with increasing haze episode evolution. The diurnal cycles of NO3,inorg and NO3,org were similar, with high concentrations during the nighttime at a high ALW level, revealing the important role of aqueous-phase processes. However, the correlations between the aerosol pH and NO3,inorg (R-2 = 0.13, P <0.01) and NO3,org (R-2 = 0.63, P <0.01) during polluted periods indicated a contrasting effect of aerosol pH on inorganic and organic nitrate formation. Our results provide a useful reference for smog chamber studies and promote a better understanding of organic nitrate formation via a nthropogenic emissions. (C) 2021 Elsevier B.V. All rights reserved.Peer reviewe

Rapid formation of intense haze episodes via aerosol-boundary layer feedback in Beijing

Although much effort has been put into studying air pollution, our knowledge of the mechanisms of frequently occurring intense haze episodes in China is still limited. In this study, using 3 years of measurements of air pollutants at three different height levels on a 325m Beijing meteorology tower, we found that a positive aerosol-boundary layer feedback mechanism existed at three vertical observation heights during intense haze polluted periods within the mixing layer. This feedback was characterized by a higher loading of PM2.5 with a shallower mixing layer. Modelling results indicated that the presence of PM2.5 within the boundary layer led to reduced surface temperature, relative humidity and mixing layer height during an intensive haze episode. Measurements showed that the aerosol-boundary layer feedback was related to the decrease in solar radiation, turbulent kinetic energy and thereby suppression of the mixing layer. The feedback mechanism can explain the rapid formation of intense haze episodes to some extent, and we suggest that the detailed feedback mechanism warrants further investigation from both model simulations and field observations.Peer reviewe

The interaction between urbanization and aerosols during a typical winter haze event in Beijing

Aerosols cause cooling at the surface by reducing shortwave radiation, while urbanization causes warming by altering the surface albedo and releasing anthropogenic heat. The combined effect of the two phenomena needs to be studied in depth. The effects of urbanization and aerosols were investigated during a typical winter haze event. The event, which occurred in Beijing from 15 to 22 December 2016, was studied via the Rapid-Refresh Multiscale Analysis and Prediction System - Short Term (RMAPS-ST) model. The mechanisms of the impacts of aerosols and urbanization were analyzed and quantified. Aerosols reduced urban-related warming during the daytime by 20 % (from 30 % to 50 %) as concentrations of fine particulate matter (PM2.5) increased from 200 to 400 mu g m(-3). Conversely, aerosols also enhanced urban-related warming at dawn, and the increment was approximately 28 %, which contributed to haze formation. Urbanization reduced the aerosol-related cooling effect by approximately 54 % during the haze event, and the strength of the impact changed little with increasing aerosol content. The impact of aerosols on urban-related warming was more significant than the impact of urbanization on aerosol-related cooling. Aerosols decreased the urban impact on the mixing-layer height by 148 % and on the sensible heat flux by 156 %. Furthermore, aerosols decreased the latent heat flux; however, this reduction decreased by 48.8 % due to urbanization. The impact of urbanization on the transport of pollutants was more important than that of aerosols. The interaction between urbanization and aerosols may enhance the accumulation of pollution and weigh against diffusion.Peer reviewe

The Stimulatory Effect of Cerebral Intraventricular Injection of cNPY on Precocial Feeding Behavior in Neonatal Chicks (Gallus domesticus).

Neuropeptide Y (NPY) is one of the most potent stimulants of food intake in many animals. Most of the supporting evidence for the effects of NPY has been gathered in mammalian species using porcine NPY. To investigate the effects of NPY on precocial feeding initiation in chicks, we firstly used chicken NPY (cNPY) to study its role in food intake and spontaneous activities in 3-day-old male chicks. Food intake was monitored at different times after intracerebroventricular (ICV) injection of cNPY (2.5, 5.0 or 10.0 μg/10 μL) and anti-cNPY antibody (anti-cNPY) (1:9000, 1:3000 or 1:1000 in dilution). cNPY given at different doses significantly increased food intake at 30 min, 60 min, 90 min and 120 min after injection. Chicks treated with 5.0 μg/10 μL of cNPY showed a maximal 4.48 fold increase in food intake comparing to the control at 30 min. There is still more than 2 fold increase in food intake at 120 min after injection of cNPY. Food intake was significantly inhibited by a single ICV injection of anti-cNPY diluted to 1:9000 (60% inhibition), 1:3000 (92% inhibition), and 1:1000 (95% inhibition) at 30 min with 1:1000 being the maximally effective concentration. The inhibitory effects of anti-cNPY (diluted to1:9000, 1:3000, 1:1000) at 120 min post ICV injection were 22%, 42% and 46%, respectively. But ICV of anti-cNPY (1:3000 in dilution) did not block the orexigenic effect of 2.5 μg/10 μL of cNPY. ICV injection of different concentrations of cNPY increases locomotor activity in a dose-dependent manner while ICV anti-cNPY greatly decreased the distance moved by each chick compared to control groups. Taken together, our results demonstrated that cNPY has a promoting effect on chick food intake and locomotor activity, and that endogenous cNPY might play a positive role in regulating precocial feeding behavior in newly hatched chicks

Research on the Hot Deformation Process of A100 Steel Based on High-Temperature Rheological Behavior and Microstructure

To obtain the optimal hot deformation process, the rheological and dynamic recrystallization behaviors of A100 steel were researched through isothermal compression tests. Firstly, a Hensel-Spittel constitutive model was established based on the stress–strain curves. Secondly, dynamic recrystallization percentage and grain size models were established to identify the necessary conditions for complete dynamic recrystallization. Finally, microstructural analysis was employed to validate the accuracy of the recrystallization model. The results indicate that the flow stress is highly sensitive to both the strain rate and the temperature, and the HS model demonstrates a high predictive accuracy, with a correlation coefficient of 0.9914. There exists a contradictory relationship between decreasing the average grain size and increasing the recrystallization percentage. The higher the percentage of dynamic recrystallization, the larger the average grain size tends to be. This situation should be avoided when devising the actual processing procedures. The optimal hot working processes for achieving complete dynamic recrystallization and a smaller average grain size are as follows: a strain equal to or greater than 0.6, a temperature between 1193 and 1353 K, and a strain rate between 0.1 and 1 s−1

Specific and spatial labeling of P0â Cre versus Wnt1â Cre in cranial neural crest in early mouse embryos

P0â Cre and Wnt1â Cre mouse lines have been widely used in combination with loxPâ flanked mice to label and genetically modify neural crest (NC) cells and their derivatives. Wnt1â Cre has been regarded as the gold standard and there have been concerns about the specificity of P0â Cre because it is not clear about the timing and spatial distribution of the P0â Cre transgene in labeling NC cells at early embryonic stages. We reâ visited P0â Cre and Wnt1â Cre models in the labeling of NC cells in early mouse embryos with a focus on cranial NC. We found that R26â lacZ Cre reporter responded to Cre activity more reliably than CAAGâ lacZ Cre reporter during early embryogenesis. Cre immunosignals in P0â Cre and reporter (lacZ and RFP) activity in P0â Cre/R26â lacZ and P0â Cre/R26â RFP embryos was detected in the cranial NC and notochord regions in E8.0â 9.5 (4â 19 somites) embryos. P0â Cre transgene expression was observed in migrating NC cells and was more extensive in the forebrain and hindbrain but not apparent in the midbrain. Differences in the Cre distribution patterns of P0â Cre and Wnt1â Cre were profound in the midbrain and hindbrain regions, that is, extensive in the midbrain of Wnt1â Cre and in the hindbrain of P0â Cre embryos. The difference between P0â Cre and Wnt1â Cre in labeling cranial NC may provide a better explanation of the differential distributions of their NC derivatives and of the phenotypes caused by Creâ driven genetic modifications.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/137503/1/dvg23034_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/137503/2/dvg23034.pd

Effects of ICV injection of cNPY on food intake in free-feeding chicks.

<p>The numbers of chicks in each group are shown in parentheses. Values shown are presented as the means ± SEM. Columns with different letters are significantly different among groups at each time (<i>P</i> < 0.05).</p

Typical profiles of effects of ICV injection of cNPY and anti-cNPY on moving track and distance for 10 min in unrestrained chicks.

<p>A: Vechile (0), B: cNPY (2.5 μg), C: anti-cNPY (1:3000 in dilution), D: cNPY (2.5 μg) + anti-cNPY (1:3000 in dilution).</p

Effect of ICV mixture injection of cNPY and anti-cNPY on food intake in free-feeding chicks.

<p>The numbers of chicks in each group are shown in parentheses. Values shown are presented as the means ± SEM. Columns with different letters are significantly different among groups at each time (<i>P</i> < 0.05).</p