Supporting Flexible Processes with Adaptive Workflow and Case Handling

Workflow management technology has profoundly transformed the way complex tasks are being handled in modern, large-scale organizations. However, it is mostly those systems’ inherent lack of flexibility that hinders their broad acceptance, and that is perceived as annoyance by users. In this context, Adaptive Process Management and Case Handling provide two very different paradigms, which both attempt to make process management more flexible and user-friendly. In this paper, we compare strengths and weaknesses of these two paradigms, and point out situations in which each is particularly appropriate. We further outline ways, in which either technology can be enhanced by crucial concepts from the other. This integration of flexibility approaches has the potential to remedy fundamental problems still present in each technology on its own

Space and Ground Based Pulsation Data of Eta Bootis Explained with Stellar Models Including Turbulence

The space telescope MOST is now providing us with extremely accurate low frequency p-mode oscillation data for the star Eta Boo. We demonstrate in this paper that these data, when combined with ground based measurements of the high frequency p-mode spectrum, can be reproduced with stellar models that include the effects of turbulence in their outer layers. Without turbulence, the l=0 modes of our models deviate from either the ground based or the space data by about 1.5-4.0 micro Hz. This discrepancy can be completely removed by including turbulence in the models and we can exactly match 12 out of 13 MOST frequencies that we identified as l=0 modes in addition to 13 out of 21 ground based frequencies within their observational 2 sigma tolerances. The better agreement between model frequencies and observed ones depends for the most part on the turbulent kinetic energy which was taken from a 3D convection simulation for the Sun.Comment: 13 pages, 7 figures, ApJ in pres

The Tropical Forest and Fire Emissions Experiment: method evaluation of volatile organic compound emissions measured by PTR-MS, FTIR, and GC from tropical biomass burning

Volatile Organic Compound (VOC) emissions from fires in tropical forest fuels were quantified using Proton-Transfer-Reaction Mass Spectrometry (PTRMS), Fourier Transform Infrared Spectroscopy (FTIR) and gas chromatography (GC) coupled to PTRMS (GC-PTR-MS). We investigated VOC emissions from 19 controlled laboratory fires at the USFS (United States Forest Service) Fire Sciences Laboratory and 16 fires during an intensive airborne field campaign during the peak of the burning season in Brazil in 2004. The VOC emissions were dominated by oxygenated VOCs (OVOC) (OVOC/NMHC ~4:1, NMHC: non-methane hydrocarbons) The specificity of the PTR-MS instrument, which measures the mass to charge ratio of VOCs ionized by H<sub>3</sub>O<sup>+</sup> ions, was validated by gas chromatography and by intercomparing in-situ measurements with those obtained from an open path FTIR instrument. Emission ratios for methyl vinyl ketone, methacrolein, crotonaldehyde, acrylonitrile and pyrrole were measured in the field for the first time. Our measurements show a higher contribution of OVOCs than previously assumed for modeling purposes. Comparison of fresh (<15 min) and aged (>1 h–1 d) smoke suggests altered emission ratios due to gas phase chemistry for acetone but not for acetaldehyde and methanol. Emission ratios for numerous, important, reactive VOCs with respect to acetonitrile (a biomass burning tracer) are presented

POLY(GLYCIDYL METHACRYLATE-DIVINYLBENZENE) MONOLITHIC CAPILLARY AS A STATIONARY PHASE FOR THE REVERSED-PHASE CHROMATOGRAPHIC SEPARATION OF PROTEINS

Capillary column with monolithic stationary phase was prepared from silanized fused-silica capillary of 200 µm I.D. by in situ free radical polymerization of divinylbenzene with glycidy methacrylate in the presence of decanol and tetrahydrofuran as porogens.  The hydrodynamic and chromatographic properties of this monolith, such as backpressure at different flow-rate, pore size distribution, van Deemter plot and the effect of varying gradient-rate were investigated.  Poly(glycidyl methacrylate-divinylbenzene) monolithic capillary has been used successfully for the reversed-phase chromatographic separation of proteins.   Keywords: monolithic stationary phase, poly(glycidyl methacrylate-divinylbenzene), protein

The Tropical Forest and Fire Emissions Experiment: Overview and Airborne Fire Emission Factor Measurements

The Tropical Forest and Fire Emissions Experiment (TROFFEE) used laboratory measurements followed by airborne and ground based field campaigns during the 2004 Amazon dry season to quantify the emissions from pristine tropical forest and several plantations as well as the emissions, fuel consumption, and fire ecology of tropical deforestation fires. The airborne campaign used an Embraer 110B aircraft outfitted with whole air sampling in canisters, mass-calibrated nephelometry, ozone by UV absorbance, Fourier transform infrared spectroscopy (FTIR), and proton-transfer mass spectrometry (PTR-MS) to measure PM(10), O(3), CO(2), CO, NO, NO(2), HONO, HCN, NH(3), OCS, DMS, CH(4), and up to 48 non-methane organic compounds (NMOC). The Brazilian smoke/haze layers extended to 2 - 3 km altitude, which is much lower than the 5 - 6 km observed at the same latitude, time of year, and local time in Africa in 2000. Emission factors (EF) were computed for the 19 tropical deforestation fires sampled and they largely compare well to previous work. However, the TROFFEE EF are mostly based on a much larger number of samples than previously available and they also include results for significant emissions not previously reported such as: nitrous acid, acrylonitrile, pyrrole, methylvinylketone, methacrolein, crotonaldehyde, methylethylketone, methylpropanal, \u27\u27 acetol plus methylacetate,\u27\u27 furaldehydes, dimethylsulfide, and C(1)-C(4) alkyl nitrates. Thus, we recommend these EF for all tropical deforestation fires. The NMOC emissions were similar to 80% reactive, oxygenated volatile organic compounds (OVOC). Our EF for PM(10) (17.8 +/- 4 g/kg) is similar to 25% higher than previously reported for tropical forest fires and may reflect a trend towards, and sampling of, larger fires than in earlier studies. A large fraction of the total burning for 2004 likely occurred during a two-week period of very low humidity. The combined output of these fires created a massive \u27\u27 mega-plume \u27\u27 \u3e 500 km across that we sampled on 8 September. The mega-plume contained high PM(10) and 10 - 50 ppbv of many reactive species such as O(3), NH(3), NO(2), CH(3)OH, and organic acids. This is an intense and globally important chemical processing environment that is still poorly understood. The mega-plume or \u27\u27 white ocean \u27\u27 of smoke covered a large area in Brazil, Bolivia, and Paraguay for about one month. The smoke was transported \u3e 2000 km to the southeast while remaining concentrated enough to cause a 3 - 4-fold increase in aerosol loading in the S (a) over tildeo Paulo area for several days

Line-profile tomography of exoplanet transits -- II. A gas-giant planet transiting a rapidly-rotating A5 star

Most of our knowledge of extrasolar planets rests on precise radial-velocity measurements, either for direct detection or for confirmation of the planetary origin of photometric transit signals. This has limited our exploration of the parameter space of exoplanet hosts to solar- and later-type, sharp-lined stars. Here we extend the realm of stars with known planetary companions to include hot, fast-rotating stars. Planet-like transits have previously been reported in the lightcurve obtained by the SuperWASP survey of the A5 star HD15082 (WASP-33; V=8.3, v sin i = 86 km/sec). Here we report further photometry and time-series spectroscopy through three separate transits, which we use to confirm the existence of a gas giant planet with an orbital period of 1.22d in orbit around HD15082. From the photometry and the properties of the planet signal travelling through the spectral line profiles during the transit we directly derive the size of the planet, the inclination and obliquity of its orbital plane, and its retrograde orbital motion relative to the spin of the star. This kind of analysis opens the way to studying the formation of planets around a whole new class of young, early-type stars, hence under different physical conditions and generally in an earlier stage of formation than in sharp-lined late-type stars. The reflex orbital motion of the star caused by the transiting planet is small, yielding an upper mass limit of 4.1 Jupiter masses on the planet. We also find evidence of a third body of sub-stellar mass in the system, which may explain the unusual orbit of the transiting planet. In HD 15082, the stellar line profiles also show evidence of non-radial pulsations, clearly distinct from the planetary transit signal. This raises the intriguing possibility that tides raised by the close-in planet may excite or amplify the pulsations in such stars.Comment: 9 pages, 6 figures, accepted for publication in MNRA

Core Overshoot: An Improved Treatment and Constraints from Seismic Data

We present a comprehensive set of stellar evolution models for Procyon A in an effort to guide future measurements of both traditional stellar parameters and seismic frequencies towards constraining the amount of core overshoot in Procyon A and possibly other stars. Current observational measurements of Procyon A when combined with traditional stellar modeling only place a large upper limit on overshoot of alphaOV < 1.1. By carrying out a detailed pulsation analysis, we further demonstrate, how p- and g-mode averaged spacings can be used to gain better estimates of the core size. For both p- and g-modes, the frequency spacings for models without overshoot are clearly separated from the models with overshoot. In addition, measurements of the l=0 averaged small p-mode spacings could be used to establish Procyon A's evolutionary stage. For a fixed implementation of overshoot and under favorable circumstances, the g-mode spacings can be used to determine the overshoot extent to an accuracy of +-0.05 Hp. However, we stress that considerable confusion is added due to the unknown treatment of the overshoot region. This ambiguity might be removed by analyzing many different stars. A simple non-local convection theory developed by Kuhfuss is implemented in our stellar evolution code and contrasted with the traditional approaches. We show that this theory supports a moderate increase of the amount of convective overshoot with stellar mass of Delta(alphaOV) = +0.10 between 1.5 Msun and 15 Msun. This theory places an upper limit on Procyon A's core overshoot extent of ~0.4 Hp which matches the limit imposed by Roxburgh's integral criterion.Comment: 45 pages, 26 figures, accepted in Ap

Impact of an in-hospital endocarditis team and a state-wide endocarditis network on perioperative outcomes

Background: Infective endocarditis (IE) requires multidisciplinary management. We established an endocarditis team within our hospital in 2011 and a state-wide endocarditis network with referring hospitals in 2015. We aimed to investigate their impact on perioperative outcomes. Methods: We retrospectively analyzed data from patients operated on for IE in our center between 01/2007 and 03/2018. To investigate the impact of the endocarditis network on referral latency and pre-operative complications we divided patients into two eras: before ( n = 409) and after ( n = 221) 01/2015. To investigate the impact of the endocarditis team on post-operative outcomes we conducted multivariate binary logistic regression analyses for the whole population. Kaplan–Meier estimates of 5-year survival were reported. Results: In the second era, after establishing the endocarditis network, the median time from symptoms to referral was halved (7 days (interquartile range: 2–19) vs. 15 days (interquartile range: 6–35)), and pre-operative endocarditis-related complications were reduced, i.e., stroke (14% vs. 27%, p < 0.001), heart failure (45% vs. 69%, p < 0.001), cardiac abscesses (24% vs. 34%, p = 0.018), and acute requirement of hemodialysis (8% vs. 14%, p = 0.026). In both eras, a lack of recommendations from the endocarditis team was an independent predictor for in-hospital mortality (adjusted odds ratio: 2.12, 95% CI: 1.27–3.53, p = 0.004) and post-operative stroke (adjusted odds ratio: 2.23, 95% CI: 1.12–4.39, p = 0.02), and was associated with worse 5-year survival (59% vs. 40%, log-rank < 0.001). Conclusion: The establishment of an endocarditis network led to the earlier referral of patients with fewer pre-operative endocarditis-related complications. Adhering to endocarditis team recommendations was an independent predictor for lower post-operative stroke and in-hospital mortality, and was associated with better 5-year survival

Current Issues in Asteroseismology

In this contribution we briefly review some of the current issues and promises for the future by asteroseismology. We are entering a new phase in this field driven by the wealth of data that has been collected and data that will soon be available for asteroseismology across the HR Diagram. Major difficulties in the descriptions of stellar interiors that arose in the second half of the 20th century may now be in part addressed and solved (this is the expectation!) by asteroseismology with unprecedented precision. In this contribution we list some of the key open questions in stellar physics, the seismic data we expect to collect in the near future, and some techniques that will provide the tools to connect data and models.Comment: 9 pages, 2 figures - to appear in Helioseismology, Asteroseismology and MHD Connections, (Eds) L. Gizon et al., Journal of Physics Conference Series, 2008 [Revision 1 - english; Revision 2 - references