Adaptabilidade de linhagens e cultivares de feijao (Phaseolus vulgaris L.) em Rondonia e resistencia a "mela" (Thanatephorus cucumeris (Frank.) Donk).

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Transition to turbulence in particulate pipe flow

We investigate experimentally the influence of suspended particles on the transition to turbulence. The particles are monodisperse and neutrally-buoyant with the liquid. The role of the particles on the transition depends both upon the pipe to particle diameter ratios and the concentration. For large pipe-to-particle diameter ratios the transition is delayed while it is lowered for small ratios. A scaling is proposed to collapse the departure from the critical Reynolds number for pure fluid as a function of concentration into a single master curve.Comment: 4 pages, 4 figure

Labeling of Activity Recognition Datasets: Detection of Misbehaving Users

Automatic recognition of user’s activities by means of wearable devices is a key element of many e-health applications, ranging from rehabilitation to monitoring of elderly citizens. Activity recognition methods generally rely on the availability of annotated training sets, where the traces collected using sensors are labelled with the real activity carried out by the user. We propose a method useful to automatically identify misbehaving users, i.e. the users that introduce inaccuracies during the labeling phase. The method is semi-supervised and detects misbehaving users as anomalies with respect to accurate ones. Experimental results show that misbehaving users can be detected with more than 99% accuracy

Falling Jets of Particles in Viscous Fluids

This fluid dynamics video presents experiments and simulations of gravity-driven particulate jets in viscous fluids at low Reynolds number. An initially straight jet is shown to develop varicose modulations of its diameter as it sediments under the action of gravity. While this instability is qualitatively reminiscent of the classical Rayleigh-Plateau instability for immiscible fluids, its mechanism has yet to be understood as neither inertia nor surface tension play a role in the case of a dilute suspension at Re=0.Comment: Accompanies video submission to APS DFD 2008 Gallery of Fluid Motio

Selectively charged and zwitterionic analogues of the smallest immunogenic structure of Streptococcus pneumoniae type 14

Zwitterionic polysaccharides (ZPs) have been shown in recent years to display peculiar immunological properties, thus attracting the interest of the carbohydrate research community. To fully elucidate the mechanisms underlying these properties and exploit the potential of this kind of structures, in depth studies are still required. In this context, the preparation of two cationic, an anionic, as well as two zwitterionic tetrasaccharide analogues of the smallest immunogenic structure of Streptococcus pneumoniae type 14 (SP14) capsular polysaccharide are presented. By exploiting a block strategy, the negative charge has been installed on the non-reducing end of the lactose unit of the tetrasaccharide and the positive charge either on the non-reducing end of the lactosamine moiety or on an external linker. These structures have then been tested by competitive ELISA, showing that the structural variations we made do not modify the affinity of the neutral compound to binding to a specific antibody. However, lower efficacies than the natural SP14 compound were observed. The results obtained, although promising, point to the need to further elongate the polysaccharide structure, which is likely too short to cover the entire epitopes

Prolate and temperature-responsive self-assemblies of amphiphilic random copolymers with perfluoroalkyl and polyoxyethylene side chains in solution

Two amphiphilic random copolymers, PEGMAx-co-FAy (x = 90 and 70 mol%), were synthesized by ATRP and their solutions were investigated as a function of solvent, concentration and temperature by DLS and SANS analyses. Both copolymers self-assembled in nanostructures by single-chain folding in water solutions over a wide range of temperatures. The values of the DLS hydrodynamic radius and the SANS radius of gyration were found to be ~4 nm and ~3.4–3.7 nm, respectively. Moreover, SANS showed the self-folded nanoassemblies to be prolated spheroids with ratio of polar/equatorial axes ~5:1 for PEGMA90-co-FA10 and ~2:1 for PEGMA70-co-FA30. On heating above a critical temperature Tc, multi-chain microassemblies were formed that reverted back to nanoassemblies on cooling below Tc. This temperature-responsive transition was fully and sharply reversible

Remarkable effect of [Li(G4)]TFSI solvate ionic liquid (SIL) on the regio- And stereoselective ring opening of α-gluco carbasugar 1,2-epoxides

Carba analogues of biologically relevant natural carbohydrates are promising structures for the development of future drugs endowed with enhanced hydrolytic stability. An open synthetic challenge in this field is the optimization of new methodologies for the stereo- and regioselective opening of α-gluco carbasugar 1,2-epoxides that allow for the preparation of pseudo mono- and disaccharides of great interest. Therefore, we investigated the effect of Lewis acids and solvate ionic liquids (SILs) on the epoxide ring opening of a model substrate. Of particular interest was the complete stereo- and regioselectivity, albeit limited to simple nucleophiles, toward the desired C(1) isomer that was observed using LiClO4. The results obtained with SILs were also remarkable. In particular, Li[NTf2]/tetraglyme ([Li(G4)]TFSI) was able to function as a Lewis acid and to direct the attack of the nucleophile preferentially at the pseudo anomeric position, even with a more complex and synthetically interesting nucleophile. The regioselectivity observed for LiClO4 and [Li(G4)]TFSI was tentatively ascribed to the formation of a bidentate chelating system, which changed the conformational equilibrium and ultimately permitted a trans-diaxial attack on C(1). To the best of our knowledge, we report here the first case in which SILs were successfully employed in a ring-opening process of epoxides

Adaptive filtering for removing nonstationary physiological noise from resting state fMRI BOLD signals

fMRI is used to investigate brain functional connectivity after removing nonneural components by General Linear Model (GLM) approach with a reference ventricle-derived signal as covariate. Ventricle signals are related to low-frequency modulations of cardiac and respiratory rhythms, which are nonstationary activities. Herein, we employed an adaptive filtering approach to improve removing physiological noise from BOLD signals. Comparisons between filtering approaches were performed by evaluating the amount of removed signal variance and the connectivity between homologous contralateral regions of interest (ROIs). The global connectivity between ROIs was estimated with a generalized correlation named RV coefficient. The mean ROI decrease of variance was -52% and -11%, for adaptive filtering and GLM, respectively. Adaptive filtering led to higher connectivity between grey matter ROIs than that obtained with GLM. Thus, adaptive filtering is a feasible method for removing the physiological noise in the low frequency band and to highlight resting state functional networks

On the Effect of the Reaction Medium on the HydroClaus Process: A Novel Sustainable H2S Valorization Strategy

Hydrogen sulfide (H2S) is becoming a critical issue to manage, due to the increasing sulfur content in the processed gas together with the stricter environmental regulations. Novel alternatives are being developed for the H2S abatement and conversion to valuable chemicals. Among them, the HydroClaus process, patented by Eni S.p.A., deserves attention. This technology aims at converting H2S and SO2 into a hydrophilic mixture of sulfur and sulfur-rich compounds, polythionates, to be used as a fertilizer. An improved configuration for an efficient water management is proposed in this work. The process operability has been demonstrated at the bench scale, through an ad hoc experimental campaign. For the technology scale-up, a flowsheet has been set up and its performances have been assessed in terms of heat and material balances and CO2 emissions. Results reveal that the modified HydroClaus process can be a valid solution for an effective H2S valorization, also considering that no direct CO2 emissions are released. Moreover, since only electric power is required, a further reduction of the indirect CO2 emissions is expected, if renewable sources can be exploited for this purpose

Offending behaviour in antisocial youths : psychological causes and practical implications

The aim of this thesis was to examine the role of biobehavioural and social variables in explaining adolescent antisocial behaviour. One study examined neuropsychological functioning in 115 young offenders. A more extensive second study was carried out on a sub-sample of the original young offender group, consisting of 48 participants. This second study used more detailed neuropsychological assessments and assessed participants' responses to emotional stimuli. Emotional functioning was assessed in 3 ways: by recording electrodermal responses during a fear conditioning task, by recording the eye-blink startle reflex while participants passively viewed different types of affective pictures, and by examining facial affect recognition. It was expected, first, that antisocial teenagers would be characterised by a sensation-seeking personality, neuropsychological impairments as evidenced by executive functioning tasks, low IQ, poor electrodermal fear conditioning, and reduced startle amplitudes, compared to age and sex matched controls. Second, it was expected that biobehavioural risk factors would interact with social risk factors in explaining ASB, and that social factors would moderate the biobehavioural - ASB relationship. We found that young offenders differed from matched controls in terms of personality traits, and neuropsychological and emotional functioning. With respect to the second hypothesis, it was found that biobehavioural risk factors did not interact with social variables in explaining different types of offending behaviour, contrary to previous studies. Specifically, the research findings indicated that young offenders were characterised by lower IQ and specific neuropsychological deficits in terms of working memory, planning and decision-making. Additionally, they had problems with the learning, processing, and recognition of emotions. Finally, we showed that different risk factors were associated with different types of offending, with both social and biobehavioural variables predicting prolific and persistent offending, and only biobehavioural factors predicting severe offending. The implications of these findings for policy and practitioners working with young offenders were discussed.EThOS - Electronic Theses Online ServiceGBUnited Kingdo