360 research outputs found
Contact angle of spherical drops inside a smooth and homogeneous cylindrical capillary with hemispherical head
To investigate the wettability of spherical drops in a smooth and homogeneous cylindrical capillary with hemispherical head, based on Gibbs’s method of dividing surface and Rusanov’s concept of dividing line, the contact angle of spherical droplets has been successfully derived considering the effects of the line tension. Additionally, under the condition of ignoring the line tension, the equation describing the contact angle is simplified as the classical Young equation
Exact treatment of magnetism-driven ferroelectricity in the one-dimensional compass model
We consider a class of one-dimensional compass models with antisymmetric
Dzyaloshinskii-Moriya exchange interaction in an external magnetic field. Based
on the exact solution derived by means of Jordan-Wigner transformation, we
study the excitation gap, spin correlations, ground-state degeneracy, and
critical properties at phase transitions. The phase diagram at finite electric
and magnetic field consists of three phases: ferromagnetic, canted
antiferromagnetic, and chiral. Dzyaloshinskii-Moriya interaction induces an
electrical polarization in the ground state of the chiral phase, where the
nonlocal string order and special features of entanglement spectra arise, while
strong chiral correlations emerge at finite temperature in the other phases and
are controlled by a gap between the nonchiral ground state and the chiral
excitations. We further show that the magnetoelectric effects in all phases
disappear above a typical temperature corresponding to the total bandwidth of
the effective fermionic model. To this end we explore the entropy, specific
heat, magnetization, electric polarization, and the magnetoelectric tensor at
finite temperature. We identify rather peculiar specific-heat and polarization
behavior of the compass model which follows from highly frustrated
interactions.Comment: 15 pages, 15 figures, Slight change comparing with the published
versio
6-Formyl-2-naphthyl cis-1,5,7-trimethyl-2,4-dioxo-3-azabicyclo[3.3.1]nonane-7-carboxylate
In the title compound, C23H23NO5, the C5N ring adopts an envelope conformation with a C atom as the flap, whilst the saturated C6 ring fused to it adopts a chair conformation. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R
2
2(8) loops
Generalized Young equation for a spherical droplet inside a smooth and homogeneous cone involved by quadratic parabola
We thermodynamically investigate the wetting characteristics of a spherical droplet in a smooth and homogeneous cone rotated by the quadratic parabola through the mechanisms of both Gibbs’s dividing surfaces and Rusanov’s dividing line. For the triple phase system including the solid, liquid and vapor phases, the derivation of a generalized Young equation containing the influences of the line tension is successfully carried out. Additionally, we as well analyze various approximate forms for this generalized Young equation by using the corresponding assumptions
Generalized Cassie-Baxter equation for wetting of a spherical droplet within a smooth and heterogeneous conical cavity
Introducing the concepts of both Gibbs’s dividing surface and Rusanov’s dividing line, the wettability behaviors of spherical drops inside a smooth and heterogeneous conical cavity are studied. A new generalized Cassie-Baxter equation for contact angles including the influences of the line tension is derived thermodynamically. Additionally, various approximate formulae of this generalized Cassie-Baxter equation are also discussed correspondingly under some assumptions
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