1,092 research outputs found

    Response to the DECC Consultation of the siting process for a Geological Disposal Facility, 2013

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    Several members of SEG (Matt Gross, Phil Johnstone, Florian Kern, Gordon MacKerron, and Andy Stirling) have participated in a written response to the Department of Energy and Climate Change’s (DECC) consultation of the siting process for a Geological Disposal Facility (GDF) for nuclear waste. This consultation follows the rejection by Cumbria County Council earlier this year to hosting a Geological Disposal Facility. The government have therefore gone back to the national level to find a suitable location, and the issue remains a multifaceted and controversial one. Matt Gross and Phil Johnstone also represented SEG at the one day consultation on the same issue run by DECC at Centre Hall, Westminster, involving several round-table discussions with civil service, nuclear regulators, and local politicians on the various issues surrounding the siting of a GDF

    The Political Economy of Public Debt Management. Institutional Setting and Political Influence

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    This dissertation investigates the overarching research question of the relationship between politics and PDM. Given that public budgets ultimately collateralize the associated risks involved in actively managing public debt and using innovative financial instruments, the relationship between politics and modern PDM is of major relevance for legitimacy in democratic capitalism. As debt instrument selection is a crucial and strategic aspect of PDM to optimize debt portfolios, chapter 2 examines the question which economic and political factors have an impact on the use and extent of short-term debt instruments on the municipal level. Finding that the municipalities’ budgetary situation represents the key determining factor of their share of short-term debt, the results demonstrate the need for different approaches to grasp the phenomenon of PDM and ultimately raises the questions of whether or not politicians have influence on PDM at all. Consequently, chapter 3 investigates the institutional setting of DMOs on the national level by analyzing the relationship between DMOs and their respective parent ministry. The analysis focusses on the variation of autonomy across countries resulting out of this delegation process. The finding that DMOs have substantial autonomy in decision-making competencies, while especially DMOs separated from the core administration are subject of relatively low reporting obligations, naturally raises doubts concerning political control. Chapter 4 consequently addresses the question whether PDM is subject of parliamentary control. The results show that parliaments have relatively low control of PDM, which indicates a trade-off between expertise and control. Moreover, this chapter underlines the necessity to differentiate between budget and debt policy and subsequently between debt level and debt structure

    Evaluating a possible new paradigm for recruitment dynamics: predicting poor recruitment for striped bass (Morone saxatilis) from an environmental variable

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    Understanding what causes large year classes and predicting them has been called the holy grail of fisheries science, one of the last great unanswered questions. Recruitment prediction, or forecasting, is an important component for setting fishery catch limits. We propose a new approach, called the “poor-recruitment paradigm”, for predicting recruitment using environmental variables. This approach hypothesizes that it is easier to predict poor recruitment rather than good recruitment because an environmental variable affects recruitment only when its value is extreme (lethal); otherwise, the variable may be benign and not influence recruitment. Thus, good recruitment necessitates all environmental conditions not be harmful and for some to be especially favorable; poor recruitment, however, requires only one environmental variable to be extreme. This idea was evaluated using recruitment and river discharge data for striped bass (Morone saxatilis) from seven major spawning tributaries of Chesapeake Bay. Low spring river discharge reliably resulted in poor recruitment of striped bass. Specifically, in all rivers, median recruitment and standard deviation of recruitment were lower when spring river discharge was low compared to when it was average or high; additionally, the proportion of years with poor recruitment was higher in years of low discharge than in years of average to high discharge. The consistent predictability of poor recruitment has the potential to improve stock projections, and therefore, has the potential to improve catch advice

    Visualizing the 'invisible'

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    The ability of scientists to image and manipulate matter at the (sub)atomic scale is a result of stunning advances in microscopy. Foremost amongst these was the invention of the scanning probe microscope, which, despite its classification as a microscope, does not rely on optics to generate images. Instead, images are produced via the interaction of an atomically sharp probe with a surface. Here the author considers to what extent those images represent an accurate picture of ‘reality’ at a size regime where quantum physics holds sway, and where the image data can be acquired and manipulated in a variety of ways

    Silicate-analogous borosulfates featuring promising luminescence and frequency-doubling (SHG) properties based on a rich crystal chemistry

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    Our contribution adresses important features of the emerging compound class of silicate-analogous borosulfates, i.e. their rich crystal chemistry, their exciting optical properties and of course their syntheses – the chemistry behind. Silicate-analogous materials comprise tetrahedral anionic basic building units lacking an inversion centre enhancing the chance of non-centrosymmetric surroundings of metal ions promoting excellent optical properties. Since the very first characterization of crystalline borosulfates in 2012 over sixty members have been found. Therein, the reaction of boric and sulfuric acid yields supertetrahedral BX4 (X=SO4) moieties giving rise to a rich crystal chemistry from non-condensed [B(SO4)4]5– anions via band (see Fig.) and layer structures to anionic frameworks [B(SO4)2]– – which can be understood by principles well known from silicates (see Fig.). The selective synthesis of borosulfates can be challenging but we meanwhile found some basic principles helping to selectively synthesize new compounds as phase-pure samples. Great impact is ascribed to the nature of the boron source, the metal (salt) employed and the amount of oleum added. On one hand, borosulfates feature a low coordination strength which is beneficial for the luminescence and UV-Vis properties of compounds containing lanthanide and transition metal ions, such as Ce3+ (see Fig.), Eu3+, Tb3+ or Co2+ and Ni2+. On the other hand, borosulfates frequently adopt non-centrosysmmetric structures yielding optical properties like SHG (second harmonic generation) which – in combination with large band-gaps – makes them highly promising materials for frequency doubling in the high energy regime. Also ionic conductivity was observed recently
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