11,356 research outputs found
THE CONSTITUTIONAL SIGNIFICANCE OF DELEGATED LEGISLATION IN ENGLAND
The Committee on Ministers\u27 Powers defined delegated legislation as the exercise by a subordinate authority, such as a Minister, of the legislative power delegated to him by Parliament. This definition followed logically from the terms of reference which required the Committee to report what safeguards are desirable or necessary to secure the constitutional principles of the sovereignty of Parliament and the supremacy of the Law. \u27 Behind these two statements lie certain assumptions which coloured the Report of the Committee and influenced its recommendations. One of these assumptions is that Ministers of the Crown are subordinate to Parliament so that any great increase in their powers may threaten Parliamentary sovereignty. A second assumption is that the phrase legislative power of Parliament is self-explanatory and free from ambiguity. These two assumptions are closely connected for they appear to answer implicitly the questions of the relationship of the Executive to Parliament and of the functions which the latter body performs under the Constitution today
EPR studies of manganese centers in SrTiO3: Non-Kramers Mn3+ ions and spin-spin coupled Mn4+ dimers
X- and Q-band electron paramagnetic resonance (EPR) study is reported on the
SrTiO3 single crystals doped with 0.5-at.% MnO. EPR spectra originating from
the S = 2 ground state of Mn3+ ions are shown to belong to the three distinct
types of Jahn-Teller centres. The ordering of the oxygen vacancies due to the
reduction treatment of the samples and consequent formation of oxygen vacancy
associated Mn3+ centres are explained in terms of the localized charge
compensation. The EPR spectra of SrTiO3: Mn crystals show the presence of next
nearest neighbor exchange coupled Mn4+ pairs in the directions.Comment: 17 pages, 8 figure
Linear Chains of Styrene and Methyl-Styrene Molecules and their Heterojunctions on Silicon: Theory and Experiment
We report on the synthesis, STM imaging and theoretical studies of the
structure, electronic structure and transport properties of linear chains of
styrene and methyl-styrene molecules and their heterojunctions on
hydrogen-terminated dimerized silicon (001) surfaces. The theory presented here
accounts for the essential features of the experimental STM data including the
nature of the corrugation observed along the molecular chains and the
pronounced changes in the contrast between the styrene and methyl-styrene parts
of the molecular chains that are observed as the applied bias is varied. The
observed evolution with applied bias of the STM profiles near the ends of the
molecular chains is also explained. Calculations are also presented of electron
transport along styrene linear chains adsorbed on the silicon surface at
energies in the vicinity of the molecular HOMO and LUMO levels. For short
styrene chains this lateral transport is found to be due primarily to direct
electron transmission from molecule to molecule rather than through the silicon
substrate, especially in the molecular LUMO band. Differences between the
calculated position-dependences of the STM current around a junction of styrene
and methyl-styrene molecular chains under positive and negative tip bias are
related to the nature of lateral electron transmission along the molecular
chains and to the formation in the LUMO band of an electronic state localized
around the heterojunction.Comment: 17 pages plus 11 figures. To appear in Physical Review
Spectroscopy on two coupled flux qubits
We have performed spectroscopy measurements on two coupled flux qubits. The
qubits are coupled inductively, which results in a
interaction. By applying microwave radiation, we observe resonances due to
transitions from the ground state to the first two excited states. From the
position of these resonances as a function of the magnetic field applied we
observe the coupling of the qubits. The coupling strength agrees well with
calculations of the mutual inductance
Generalized Stacking Fault Energy Surfaces and Dislocation Properties of Silicon: A First-Principles Theoretical Study
The generalized stacking fault (GSF) energy surfaces have received
considerable attention due to their close relation to the mechanical properties
of solids. We present a detailed study of the GSF energy surfaces of silicon
within the framework of density functional theory. We have calculated the GSF
energy surfaces for the shuffle and glide set of the (111) plane, and that of
the (100) plane of silicon, paying particular attention to the effects of the
relaxation of atomic coordinates. Based on the calculated GSF energy surfaces
and the Peierls-Nabarro model, we obtain estimates for the dislocation
profiles, core energies, Peierls energies, and the corresponding stresses for
various planar dislocations of silicon.Comment: 9 figures (not included; send requests to [email protected]
A Preliminary Report on Unique Hail and Tornadic Storm Observations in Central Illinois and Eastern Indiana on 3 April 1974
published or submitted for publicationis peer reviewedOpe
Spin-controlled Mott-Hubbard bands in LaMnO_3 probed by optical ellipsometry
Spectral ellipsometry has been used to determine the dielectric function of
an untwinned crystal of LaMnO_3 in the spectral range 0.5-5.6 eV at
temperatures 50 K < T < 300 K. A pronounced redistribution of spectral weight
is found at the Neel temperature T_N = 140 K. The anisotropy of the spectral
weight transfer matches the magnetic ordering pattern. A superexchange model
quantitatively describes spectral weight transfer induced by spin correlations.
This analysis implies that the lowest-energy transitions around 2 eV are
intersite d-d transitions, and that LaMnO_3 is a Mott-Hubbard insulator.Comment: 4 pages, 4 figure
Stochastic Modelling Approach to the Incubation Time of Prionic Diseases
Transmissible spongiform encephalopathies like the bovine spongiform
encephalopathy (BSE) and the Creutzfeldt-Jakob disease (CJD) in humans are
neurodegenerative diseases for which prions are the attributed pathogenic
agents. A widely accepted theory assumes that prion replication is due to a
direct interaction between the pathologic (PrPsc) form and the host encoded
(PrPc) conformation, in a kind of an autocatalytic process. Here we show that
the overall features of the incubation time of prion diseases are readily
obtained if the prion reaction is described by a simple mean-field model. An
analytical expression for the incubation time distribution then follows by
associating the rate constant to a stochastic variable log normally
distributed. The incubation time distribution is then also shown to be log
normal and fits the observed BSE data very well. The basic ideas of the
theoretical model are then incorporated in a cellular automata model. The
computer simulation results yield the correct BSE incubation time distribution
at low densities of the host encoded protein
Low-energy Mott-Hubbard excitations in LaMnO_3 probed by optical ellipsometry
We present a comprehensive ellipsometric study of an untwinned, nearly
stoichiometric LaMnO_3 crystal in the spectral range 1.2-6.0 eV at temperatures
20 K < T < 300 K. The complex dielectric response along the b and c axes of the
Pbnm orthorhombic unit cell, \epsilon^b(\nu) and \epsilon^c(\nu), is highly
anisotropic over the spectral range covered in the experiment. The difference
between \epsilon^b(\nu) and \epsilon^c(\nu) increases with decreasing
temperature, and the gradual evolution observed in the paramagnetic state is
strongly enhanced by the onset of A-type antiferromagnetic long-range order at
T_N = 139.6 K. In addition to the temperature changes in the lowest-energy gap
excitation at 2 eV, there are opposite changes observed at higher energy at 4 -
5 eV, appearing on a broad-band background due to the strongly dipole-allowed O
2p -- Mn 3d transition around the charge-transfer energy 4.7 eV. Based on the
observation of a pronounced spectral-weight transfer between low- and
high-energy features upon magnetic ordering, they are assigned to high-spin and
low-spin intersite d^4d^4 - d^3d^5 transitions by Mn electrons. The anisotropy
of the lowest-energy optical band and the spectral weight shifts induced by
antiferromagnetic spin correlations are quantitatively described by an
effective spin-orbital superexchange model. An analysis of the multiplet
structure of the intersite transitions by Mn e_g electrons allowed us to
estimate the effective intra-atomic Coulomb interaction, the Hund exchange
coupling, and the Jahn-Teller splitting energy between e_g orbitals in LaMnO_3.
This study identifies the lowest-energy optical transition at 2 eV as an
intersite d-d transition, whose energy is substantially reduced compared to
that obtained from the bare intra-atomic Coulomb interaction.Comment: 10 pages, 14 figure
Ames collaborative study of cosmic ray neutrons
The results of a collaborative study to define both the neutron flux and the spectrum more precisely and to develop a dosimetry package that can be flown quickly to altitude for solar flare events are described. Instrumentation and analysis techniques were used which were developed to measure accelerator-produced radiation. The instruments were flown in the Ames Research Center high altitude aircraft. Neutron instrumentation consisted of Bonner spheres with both active and passive detector elements, threshold detectors of both prompt-counter and activation-element types, a liquid scintillation spectrometer based on pulse-shape discrimination, and a moderated BF3 counter neutron monitor. In addition, charged particles were measured with a Reuter-Stokes ionization chamber system and dose equivalent with another instrument. Preliminary results from the first series of flights at 12.5 km (41,000 ft) are presented, including estimates of total neutron flux intensity and spectral shape and of the variation of intensity with altitude and geomagnetic latitude
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