Wetting of porous thin films exhibiting large contact angles

Porous solid films that promote large apparent contact angles are interesting systems since their wetting properties are dependent on both the surface structure and water penetration into the film. In this study, a parahydrophobic coating is made by sequential dip coating of titanium dioxide nanoparticles and stearic acid on polished copper substrates. The apparent contact angles are determined using the tilted plate method, and it is found that the liquid–vapor interaction decreases and water droplets are more likely to move off the film when the number of coated layers increases. Interestingly, it is found that under some conditions, the front contact angle can be smaller than the back contact angle. Scanning electron microscopy observations demonstrate that the coating process led to the formation of hydrophilic TiO2 nanoparticle domains and hydrophobic stearic acid flakes that allows heterogeneous wetting. By monitoring the electrical current through the water droplet to the copper substrate, it is found that the water drops penetrate the coating layer to make direct contact with the copper surface with a time delay and magnitude that depends on the coating thickness. This additional penetration of water into the porous film enhances the adhesion of the droplet to the film and provides a clue to understand the contact angle hysteresis.acceptedVersio

Long, stitch-free slot waveguide with s-bend tapered couplers for IR-sensing applications using electron beam lithography

We use the fixed beam moving stage (FBMS) electron beam lithography technique to pattern a 10 mm long slot waveguide with s-bend tapered double-tip couplers. The fabrication method solves two major limitations of the FBMS mode, namely, the requirement for fixed-width structures and the incidence of stage placement drift for patterns involving elements of different widths. This has been achieved by fracturing the outline of the structure into fixed-width elements of gradually increasing width and creating intermediate overlap areas between the elements to mitigate the stage placement drifts

Temperature induced color change in gold nanoparticle arrays: Investigating the annealing effect on the localized surface plasmon resonance

The localized surface plasmon resonance (LSPR) effect in metal nanoparticles is important for a range of applications, including photovoltaics and sensors. The actual LSPR effect is difficult to predict, because it can vary strongly with the size, shape, surface structure, and surrounding media of the nanoparticles. In order to understand this better, more experimental data are needed. Here, the authors present a study of the LSPR effect in macroscopic two-dimensional square arrays of gold nanoparticles, 50–80 nm in diameter with a pitch of approximately 160 nm, fabricated on borosilicate substrates. The arrays were exposed to different annealing temperatures in steps of 50 up to 600 °C. The authors observe an irreversible blue-shift of the LSPR extinction peak, from around 580 to around 520 nm at annealing temperatures of only 450 °C, an effect clearly visible to the naked eye. The authors also present measurements of the shape of the nanoparticles at the different annealing steps. These measurements were obtained using a combination of scanning electron microscopy (SEM) and atomic force microscopy (AFM). A carefully indexed pattern allowed us to measure the exact same nanoparticles with separate AFM and SEM instruments. The only clear effect that can be observed is that the nanoparticles appear to get smoother with annealing. Our results demonstrate that seemingly minor changes in the metal nanoparticle appearance can lead to a strong change in the LSPR effect. Our results also open up for potential applications in temperature sensing. The fact that the effect of temperature exposure can be observed with the naked eye without any need of electronic readout or power supply is particularly advantageous.publishedVersio

Large area microwave plasma CVD of diamond using composite right/left-handed materials

Diamond growth at low temperatures (≤400 °C) and over large areas is attractive for materials, which are sensitive to high temperatures and require good electronic, chemical or surface tribological properties. Resonant-cavity microwave plasma enhanced (MWPE) chemical vapor deposition (CVD) is a standard method for growing diamonds, however, with limited deposition area. An alternative method for CVD of diamond over large area and at low temperature is to use a surface wave plasma (SWP). In this work we introduce a novel method to excite SWP using composite right/left-handed (CRLH) materials and demonstrate growth of nanocrystalline diamond (NCD) on 4-inch Si wafers. The method uses a set of slotted CRLH waveguides coupled to a resonant launcher, which is connected to a deposition chamber. Each CRLH waveguide supports infinite wavelength propagation and consists of a chain of periodically cascaded unit cells. The SWP is excited by a set of slots placed to interrupt large area surface current on the resonant launcher. This configuration yields a uniform gas discharge distribution. We achieve 80 nm/h growth rate for NCD films with a low surface roughness (5–10 nm) at 395 °C and 0.5 mbar pressure using a H2/CH4/CO2 gas mixture.publishedVersio

Experimental and theoretical investigation of waveguided plasmonic surface lattice resonances

Plasmonic nanostructures are good candidates for refractive index sensing applications through the surface plasmon resonance due to their strong dependence on the surrounding dielectric media. However, typically low quality-factor limits their application in sensing devices. To improve the quality-factor, we have experimentally and theoretically investigated two-dimensional gold nanoparticle gratings situated on top of a waveguide. The coupling between the localized surface plasmon and waveguide modes results in Fano-type resonances, with high quality-factors, very similar to plasmonic surface lattice resonances. By combining plasmonic surface lattice resonance and waveguide theory, we present a theoretical framework describing the structures. By immersing the fabricated samples in three different media we find a sensitivity of ∼50 nm/RIU and figure of merit of 8.9, and demonstrate good agreement with the theory presented. Further analysis show that the sensitivity is very dependent on the waveguide parameters, grating constant and the dielectric environment, and by tuning these parameters we obtain a theoretical sensitivity of 887 nm/RIU.publishedVersio

Fast resolution change in neutral helium atom microscopy

In neutral helium atom microscopy, a beam of atoms is scanned across a surface. Though still in its infancy, neutral helium microscopy has seen a rapid development over the last few years. The inertness and low energy of the helium atoms (less than 0.1 eV) combined with a very large depth of field and the fact that the helium atoms do not penetrate any solid material at low energies open the possibility for a non-destructive instrument that can measure topology on the nanoscale even on fragile and insulating surfaces. The resolution is determined by the beam spot size on the sample. Fast resolution change is an attractive property of a microscope because it allows different aspects of a sample to be investigated and makes it easier to identify specific features. However up till now it has not been possible to change the resolution of a helium microscope without breaking the vacuum and changing parts of the atom source. Here we present a modified source design, which allows fast, step wise resolution change. The basic design idea is to insert a moveable holder with a series of collimating apertures in front of the source, thus changing the effective source size of the beam and thereby the spot size on the surface and thus the microscope resolution. We demonstrate a design with 3 resolution steps. The number of resolution steps can easily be extended.publishedVersio

Data on association between QRS duration on prehospital ECG and mortality in patients with confirmed STEMI

Data presented in this article relates to the research article entitled âAssociation between QRS duration on prehospital ECG and mortality in patients with suspected STEMIâ (Hansen et al., in press) [1].Data on the prognostic effect of automatically recoded QRS duration on prehospital ECG and presence of classic left and right bundle branch block in 1777 consecutive patients with confirmed ST segment elevation AMI is presented. Multivariable analysis, suggested that QRS duration >111 ms, left bundle branch block and right bundle branch block were independent predictors of 30 days all-cause mortality. For interpretation and discussion of these data, refer to the research article referenced above

Polycrystalline Diamond Coating on Orthopedic Implants: Realization and Role of Surface Topology and Chemistry in Adsorption of Proteins and Cell Proliferation

Polycrystalline diamond has the potential to improve the osseointegration of orthopedic implants compared to conventional materials such as titanium. However, despite the excellent biocompatibility and superior mechanical properties, the major challenge of using diamond for implants, such as those used for hip arthroplasty, is the limitation of microwave plasma chemical vapor deposition (CVD) techniques to synthesize diamond on complex-shaped objects. Here, for the first time, we demonstrate diamond growth on titanium acetabular shells using the surface wave plasma CVD method. Polycrystalline diamond coatings were synthesized at low temperatures (∼400 °C) on three types of acetabular shells with different surface structures and porosities. We achieved the growth of diamond on highly porous surfaces designed to mimic the structure of the trabecular bone and improve osseointegration. Biocompatibility was investigated on nanocrystalline diamond (NCD) and ultrananocrystalline diamond (UNCD) coatings terminated either with hydrogen or oxygen. To understand the role of diamond surface topology and chemistry in the attachment and proliferation of mammalian cells, we investigated the adsorption of extracellular matrix proteins and monitored the metabolic activity of fibroblasts, osteoblasts, and bone-marrow-derived mesenchymal stem cells (MSCs). The interaction of bovine serum albumin and type I collagen with the diamond surfaces was investigated by confocal fluorescence lifetime imaging microscopy (FLIM). We found that the proliferation of osteogenic cells was better on hydrogen-terminated UNCD than on the oxygen-terminated counterpart. These findings correlated with the behavior of collagen on diamond substrates observed by FLIM. Hydrogen-terminated UNCD provided better adhesion and proliferation of osteogenic cells, compared to titanium, while the growth of fibroblasts was poorest on hydrogen-terminated NCD and MSCs behaved similarly on all tested surfaces. These results open new opportunities for application of diamond coatings on orthopedic implants to further improve bone fixation and osseointegration.publishedVersio

Nanostructuring of free-standing, dielectric membranes using electron-beam lithography

Nanostructured dielectric membranes are used in several applications ranging from de Broglie matter-wave optical elements to photonic crystals. Precise pattern transfer and high aspect ratio structures are crucial for many applications. The authors present an improved method for direct patterning on free-standing, dielectric membranes using electron-beam (e-beam) lithography. The method is based on an advanced etchmask that both reduces charging and allows for tuning of the etch mask thickness to support high aspect ratios even for small structures. The authors etched structures as small as 50 nm radius holes in a 150 nm thick membrane and achieved aspect ratios of up to 1.3 for this structure size range. The etch mask thickness can be tuned to achieve the required aspect ratio. The etchmask is composed of a three layer stack consisting of poly(methyl methacrylate), SiO2 and an antireflective coating polymer. Scanning-electron micrographs of membranes produced with the fabrication method are presented