State Control of Interstate Air Pollution

Global warming is an unequivocal fact proved by the persistent rise of the average temperature of the earth. IPCC reported that scientists were more than 90 % certain that most of the global warming was caused by increasing concentrations of greenhouse gases (GHG) produced by human activities. One alternative to combat the GHG is to explore technologies for utilizing CO2 already generated by current energy systems and develop methods to convert CO2 into useful combustible gases. Two-step conversion of CO2 with catalysts is one of the most promising methods. Ceria (CeO2) is chosen as the main catalyst for this conversion in the thesis. It releases O2 when it is reduced in a heating process, and then absorbs O2 from CO2 to produce CO when it is re-oxidized in a cooling process. To make the conversion economic, solar power is employed to drive the conversion system. In this thesis, a flexible system with fluidized bed reactors (FBRs) is introduced. The thermogravimetric analysis (TGA) was carried out to examine the performance of ceria during its reduction and oxidation. Subsequently, the exergy analysis was used to evaluate the system’s capability on exporting work. The theoretical fuel to chemical efficiency varied from 4.85 % to 43.2 % for CO2 conversions. To investigate the operation mechanism of the system, a mathematical model was built up for the dynamic simulation of the system. Variables such as temperatures and efficiencies were calculated and recorded for different cases. The optimum working condition was found out to be at 1300 ⁰C for the commercial type of ceria. Finally, an experimental system was set up. The hydrodynamics and heat transfer in the fluidized bed reactor were studied. A CFD model was built up and validated with the experimental trials around 120 ⁰C. The model was then used as a reliable tool for the optimization of the reactor. The entire work in the thesis follows the procedure of developing an engineering system. It forms a solid basis for further improvements of the system to recycle CO2.QC 20141006</p

Managing on-farm environmental impact using EMA.

There have been many initiatives recently aimed towards delivering policies relating to agricultural sustainability, particularly with respect to minimising environmental impact without compromising profitability. The final objective of these is normally to protect food and environmental quality, and preserve biodiversity and the natural heritage. The agricultural industry is in a time of significant change, and managing change can be difficult not least when trying to ensure awareness, response to new opportunities and compliance with legislation. For changes of this type to be practical and attractive, farmers need considerable guidance on what is inevitably a more labour, resource and time demanding process. The Environmental Management for Agriculture (EMA) software provides one mechanism by which this support can be distributed. It contains a library, decision support tools, databases, planning aids and audits for farm use. It has been available for several years in England and Wales and is now available for Scotland.Non peer reviewedFinal Published versio

Wear effects and mechanisms of soot-contaminated automotive lubricants

A study has been carried out to investigate the influence of soot-contaminated automotive lubricants in the wear process of a simulated engine valve train contact. Previous research on this topic has been mainly performed from a chemical point of view in fundamental studies, with insufficient relevance to real engine conditions, i.e. load and geometry. This study investigates the conditions under which wear occurs through specimen testing. The objective of the work was to understand the wear mechanisms that occur within the contaminated contact zone, to help in future development of a predictive wear model to assist in the valve-train design process. The effects of soot in lubricants have been tested using a reciprocating test-rig specifically designed for this application, where a steel disc is held in a bath of oil and a steel ball (replicating a valve train contact) is attached to a reciprocating arm. The materials, contact geometry and loading conditions are all related to specific conditions experienced within an engine's valve train. The testing was carried out under various contact conditions, using carbon black as a soot simulant. Wear measurements were taken during the tests and wear scar morphology was studied. The results have revealed how varying lubrication conditions changes the wear rate of engine components and determines the wear mechanism that dominates for specific situations

Identifying integrated options for agricultural climate change mitigation

Purpose: In order to achieve reductions in greenhouse gas emissions it is essential that all industry sectors have the appropriate knowledge and tools to contribute. This includes agriculture, which is considered to contribute about a third of emissions globally. This paper reports on one such tool: IMPACCT: Integrated Management oPtions for Agricultural Climate Change miTigation. Design/methodology/approach: IMPACCT focuses on greenhouse gas emissions, carbon sequestration and associated mitigation options. However, it also attempts to include information on economic and other environmental impacts in order to provide a more holistic perspective. The model identifies mitigation options, likely economic impacts and any synergies and trade-offs with other environmental objectives. The model has been applied on 22 case study farms in seven member states. Findings: The tool presents some useful concepts for developing carbon calculators in the future. It has highlighted that calculators need to evolve from simply calculating emissions to identifying cost effective and integrated emissions reduction options. Practical implications: IMPACCT has potential to become an effective means of provided targeted guidance, as part of a broader knowledge transfer programme based on an integrated suite of guidance, tools and advice delivered via different media. Originality/value: IMPACCT is a new model that demonstrates how to take a more integrated approach to mitigating greenhouse gas emissions on farms across Europe. It is a holistic carbon calculator that presents mitigation options in the context other environmental and economic objectives in the search for more sustainable methods of food production.Peer reviewedFinal Accepted Versio

Spatial analysis of the benefits and burdens of ecological focus areas for water-related ecosystem services vulnerable to climate change in Europe

There are many concerns regarding the effects of climate change including threats to ecosystem services. Rural land use can influence these services and there is scope for associated policies to steer decisions towards maximising benefits and minimising burdens. In Europe, for example, ecological focus areas (EFAs), introduced in the last reform of the Common Agricultural Policy, can have impacts on ecosystem services which vary with location, including potential trade-offs between benefits and burdens in some regions. This study combines the outputs from two continental-scale projects to provide a new perspective on the potential impact of EFAs for water-related ecosystem services under threat from climate change. An ecosystem service impact indicator framework was applied in conjunction with a climate change vulnerability assessment. This resulted in vulnerability and area weighted performance scores for dilution, filtration, water provision, and flood regulation services for 10 EFAs in 1256 regions. Best, average and worst case scenario maps were created that highlight the relative benefits and burdens of EFAs. Six EFAs have been identified which have not been activated in nine European Member States but which have potential to provide benefits. Eleven Member States have been identified which have regions where 3 EFAs should be avoided due to potential burdens. This analysis facilitates broad spatial targeting on a continental-scale of specific EFAs which may help maintain (and ideally increase) ecosystem service capacity and resilience in vulnerable regions.Peer reviewedFinal Accepted Versio

Chromatographic separation and identification of some peptides in partial hydroylsates of gelatin

Recently we have been engaged in a study of the chemical structure of collagen and gelatin with the object of determining the sequence of the amino acid residues in the polypeptide chains of these proteins. In the course of this study we have made considerable progress in the chromatographic analysis of complex mixtures of peptides and we have isolated and identified several simple peptides which occur in partial hydrolysates of gelatin. The initial separation of the mixture into zones of one or more peptides has been made on a column of ion exchange resin; further separation of the peptides in each zone has been achieved by chromatographing in the form of dinitrophenyl (DNP) peptides on columns of silicic acid-Celite. It is to be hoped that the particular combination of chromatographic methods which has been successfully used in the present study will be helpful in the resolution of the complex mixtures which result from the partial hydrolysis of other proteins

Adapting to climate change : Assessing the vulnerability of ecosystem services in Europe in the context of rural development

This document is the Accepted Manuscript version. The final publication is available at Springer via https://doi.org/10.1007/s11027-013-9507-6.Over the past decade, efforts to move towards a low carbon economy have been increasingly coupled with the acknowledgement that we also need to develop climate resilient economies, capable of adapting and responding to changes in climate. To shift society in these directions we need to quantify impacts in relation to these objectives and develop cost-effective interventions. Techniques for quantifying greenhouse gas emissions are relatively well established and enable identification of hotspots where there is emissions reduction potential. However, there are no established techniques to assess and quantify adaptation vulnerability issues and identify hotspots for intervention. This paper presents work undertaken at a European level with the objective of identifying potential hotspots where ecosystem services may be vulnerable to climate change and thus where intervention may be required under the European Rural Development Programme. A pragmatic and relatively simple approach is presented, based on data that is readily available across Europe. The vulnerability assessments cover: Water (quality: dilution and filtration, regulation: flooding and provision); soils (erosion and organic matter); and biodiversity (forest fires, migration and pollination). The framework and assessments presented are considered fit for purpose (at a basic level) and they are potentially valuable tools for targeting limited resources to achieve desirable outcomes. They also contribute towards providing a better understanding of the climate change challenges we face and support the formulation of solutions to optimally address those challenges. There is scope to further improvement and a number of options are discussed and explored within this paperPeer reviewe