536 research outputs found
Aging and memory properties of topologically frustrated magnets
The model 2d kagome system (H3O)Fe3(SO4)2(OH)6 and the 3d pyrochlore Y2Mo2O7
are two well characterized examples of low-disordered frustrated
antiferromagnets which rather then condensing into spin liquid have been found
to undergo a freezing transition with spin glass-like properties. We explore
more deeply the comparison of their properties with those of spin glasses, by
the study of characteristic rejuvenation and memory effects in the
non-stationary susceptibility. While the pyrochlore shows clear evidence for
these non-trivial effects, implying temperature selective aging, that is
characteristic of a wide hierarchical distribution of equilibration processes,
the kagome system does n not show clearly these effects. Rather, it seems to
evolve towards the same final state independently of temperature.Comment: submitted for the proceedings of the 46th MMM conference (Seattle,
2001
Superconducting properties of the pyrochlore oxide Cd2Re2O7
We report the superconducting properties of the pyrochlore oxide Cd2Re2O7.
The bulk superconducting transition temperature Tc is about 1.0 K, and the
upper critical field Hc2 determined by the measurement of specific heat under
magnetic fields is 0.29 T. The superconducting coherence length is estimated to
be 34 nm. Specific heat data measured on single crystals suggest that the
superconducting gap of Cd2Re2O7 is nodeless.Comment: 6 pages, 6 figures, 1 table, to be published in J. Chem. Phys. Solid
Magnetic and Thermodynamic Properties of the Collective Paramagnet-Spin Liquid Pyrochlore Tb2Ti2O7
In a recent letter [Phys. Rev. Lett. {\bf 82}, 1012 (1999)] it was found that
the Tb magnetic moments in the TbTiO pyrochlore lattice of
corner-sharing tetrahedra remain in a {\it collective paramagnetic} state down
to 70mK. In this paper we present results from d.c. magnetic susceptibility,
specific heat data, inelastic neutron scattering measurements, and crystal
field calculations that strongly suggest that (1) the Tb ions in
TbTiO possess a moment of approximatively 5, and (2)
the ground state tensor is extremely anisotropic below a temperature of
K, with Ising-like Tb magnetic moments confined to point along
a local cubic direction
dramatically reduces the frustration otherwise present in a Heisenberg
pyrochlore antiferromagnet. The results presented herein underpin the
conceptual difficulty in understanding the microscopic mechanism(s) responsible
for TbTiO failing to develop long-range order at a temperature of
the order of the paramagnetic Curie-Weiss temperature K. We suggest that dipolar interactions and extra perturbative exchange
coupling(s)beyond nearest-neighbors may be responsible for the lack of ordering
of TbTiO.Comment: 8 POSTSCRIPT figures included. Submitted to Physical Review B.
Contact: [email protected]
Structural and Magnetic Properties of Pyrochlore Solid Solutions (Y,Lu)2Ti2-x(Nb,Ta)xO7+/-y
The synthesis and characterization of the pyrochlore solid solutions,
Y2Ti2-xNbxO7-y, Lu2Ti2-xNbxO7-y, Y2Ti2-xTaxO7-y and Lu2TiTaO7-y (-0.4<y<0.5),
is described. Synthesis at 1600 C, and 10-5 Torr yields oxygen deficiency in
all systems. All compounds are found to be paramagnetic and semiconducting,
with the size of the local moments being less, in some cases substantially
less, than the expected value for the number of nominally unpaired electrons
present. Thermogravimetric analysis (TGA) shows that all compounds can be fully
oxidized while retaining the pyrochlore structure, yielding oxygen rich
pyrochlores as white powders. Powder neutron diffraction of Y2TiNbO7-based
samples was done. Refinement of the data for oxygen deficient Y2TiNbO6.76
indicates the presence of a distribution of oxygen over the 8b and 48f sites.
Refinement of the data for oxygen rich Y2TiNbO7.5 shows these sites to be
completely filled, with an additional half filling of the 8a site. The magnetic
and TGA data strongly suggest a preference for a Ti3+/(Nb,Ta)5+ combination, as
opposed to Ti4+/(Nb,Ta)4+, in this pyrochlore family. In addition, the evidence
clearly points to Ti3+ as the source of the localized moments, with no evidence
for localized Nb4+ moments.Comment: Accepted to Journal of Solid State Chemistr
Frustration effects in magnetic molecules
Besides being a fascinating class of new materials, magnetic molecules
provide the opportunity to study concepts of condensed matter physics in zero
dimensions. This contribution will exemplify the impact of molecular magnetism
on concepts of frustrated spin systems. We will discuss spin rings and the
unexpected rules that govern their low-energy behavior. Rotational bands, which
are experimentally observed in various molecular magnets, provide a useful,
simplified framework for characterizing the energy spectrum, but there are also
deviations thereof with far-reaching consequences. It will be shown that
localized independent magnons on certain frustrated spin systems lead to giant
magnetization jumps, a new macroscopic quantum effect. In addition a
frustration-induced metamagnetic phase transitions will be discussed, which
demonstrates that hysteresis can exist without anisotropy. Finally, it is
demonstrated that frustrated magnetic molecules could give rise to an enhanced
magnetocaloric effect.Comment: 6 pages, 4 figures; submitted to J. Low. Temp. Phys.; proceedings of
the Sixth International Symposium on Crystalline Organic Metals,
Superconductors, and Ferromagnets (ISCOM
Static Critical Behavior of the Spin-Freezing Transition in the Geometrically Frustrated Pyrochlore Antiferromagnet Y2Mo2O7
Some frustrated pyrochlore antiferromagnets, such as Y2Mo2O7, show a
spin-freezing transition and magnetic irreversibilities below a temperature Tf
similar to what is observed nonlinear magnetization measurements on Y2Mo2O7
that provide strong evidence that there is an underlying thermodynamic phase
transition at Tf, which is characterized by critical exponents \gamma \approx
2.8 and \beta \approx 0.8. These values are typical of those found in random
spin glasses, despite the fact that the level of random disorder in Y2Mo2O7 is
immeasurably small.Comment: Latex file, calls for 4 encapsulated postscript figures (included).
Submitted to Phys. Rev. Letters
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