28,804 research outputs found
Potential structural material problems in a hydrogen energy system
Potential structural material problems that may be encountered in the three components of a hydrogen energy system - production, transmission/storage, and utilization - were identified. Hydrogen embrittlement, corrosion, oxidation, and erosion may occur during the production of hydrogen. Hydrogen embrittlement is of major concern during both transmission and utilization of hydrogen. Specific materials research and development programs necessary to support a hydrogen energy system are described
Molecular Density Functional Theory of Water describing Hydrophobicity at Short and Long Length Scales
We present an extension of our recently introduced molecular density
functional theory of water [G. Jeanmairet et al., J. Phys. Chem. Lett. 4, 619,
2013] to the solvation of hydrophobic solutes of various sizes, going from
angstroms to nanometers. The theory is based on the quadratic expansion of the
excess free energy in terms of two classical density fields, the particle
density and the multipolar polarization density. Its implementation requires as
input a molecular model of water and three measurable bulk properties, namely
the structure factor and the k-dependent longitudinal and transverse dielectric
susceptibilities. The fine three-dimensional water structure around small
hydrophobic molecules is found to be well reproduced. In contrast the computed
solvation free-energies appear overestimated and do not exhibit the correct
qualitative behavior when the hydrophobic solute is grown in size. These
shortcomings are corrected, in the spirit of the Lum-Chandler-Weeks theory, by
complementing the functional with a truncated hard-sphere functional acting
beyond quadratic order in density. It makes the resulting functional compatible
with the Van-der-Waals theory of liquid-vapor coexistence at long range.
Compared to available molecular simulations, the approach yields reasonable
solvation structure and free energy of hard or soft spheres of increasing size,
with a correct qualitative transition from a volume-driven to a surface-driven
regime at the nanometer scale.Comment: 24 pages, 8 figure
Contributions to the Nearby Stars (NStars) Project: Spectroscopy of Stars Earlier than M0 within 40 parsecs: The Northern Sample I
We have embarked on a project, under the aegis of the Nearby Stars (NStars)/
Space Interferometry Mission Preparatory Science Program to obtain spectra,
spectral types, and, where feasible, basic physical parameters for the 3600
dwarf and giant stars earlier than M0 within 40 parsecs of the sun. In this
paper we report on the results of this project for the first 664 stars in the
northern hemisphere. These results include precise, homogeneous spectral types,
basic physical parameters (including the effective temperature, surface gravity
and the overall metallicity, [M/H]) and measures of the chromospheric activity
of our program stars. Observed and derived data presented in this paper are
also available on the project's website at http://stellar.phys.appstate.edu/
Quantum Channels with Memory
We present a general model for quantum channels with memory, and show that it
is sufficiently general to encompass all causal automata: any quantum process
in which outputs up to some time t do not depend on inputs at times t' > t can
be decomposed into a concatenated memory channel. We then examine and present
different physical setups in which channels with memory may be operated for the
transfer of (private) classical and quantum information. These include setups
in which either the receiver or a malicious third party have control of the
initializing memory. We introduce classical and quantum channel capacities for
these settings, and give several examples to show that they may or may not
coincide. Entropic upper bounds on the various channel capacities are given.
For forgetful quantum channels, in which the effect of the initializing memory
dies out as time increases, coding theorems are presented to show that these
bounds may be saturated. Forgetful quantum channels are shown to be open and
dense in the set of quantum memory channels.Comment: 21 pages with 5 EPS figures. V2: Presentation clarified, references
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The Molonglo Galactic Plane Survey: I. Overview and Images
The first epoch Molonglo Galactic Plane Survey (MGPS1) is a radio continuum
survey made using the Molonglo Observatory Synthesis Telescope (MOST) at 843
MHz with a resolution of 43" X 43" cosec |delta|. The region surveyed is 245
deg < l < 355 deg, |b| < 1.5 deg. The thirteen 9 deg X 3 deg mosaic images
presented here are the superposition of over 450 complete synthesis
observations, each taking 12 h and covering 70' X 70' cosec |delta|. The
root-mean-square sensitivity over much of the mosaiced survey is 1-2 mJy/beam
(1 sigma), and the positional accuracy is approximately 1" X 1" cosec |delta|
for sources brighter than 20 mJy. The dynamic range is no better than 250:1,
and this also constrains the sensitivity in some parts of the images. The
survey area of 330 sq deg contains well over 12,000 unresolved or barely
resolved objects, almost all of which are extra-galactic sources lying in the
Zone of Avoidance. In addition a significant fraction of this area is covered
by extended, diffuse emission associated with thermal complexes, discrete H II
regions, supernova remnants, and other structures in the Galactic interstellar
medium.Comment: Paper with 3 figures and 1 table + Table 2 + 7 jpg grayscales for Fig
4. Astrophysical Journal Supplement (in press) see also
http://www.astrop.physics.usyd.edu.au/MGP
Diagnosing students' difficulties in learning mathematics
This study considers the results of a diagnostic test of student difficulty and contrasts the difference in performance between the lower attaining quartile and the higher quartile. It illustrates a difference in qualitative thinking between those who succeed and those who fail in mathematics, illustrating a theory that those who fail are performing a more difficult type of mathematics (coordinating procedures) than those who succeed (manipulating concepts). Students who have to coordinate or reverse processes in time will encounter far greater difficulty than those who can manipulate symbols in a flexible way. The consequences of such a dichotomy and implications for remediation are then considered
Effect of high temperature heat treatments on the quality factor of a large-grain superconducting radio-frequency niobium cavity
Large-grain Nb has become a viable alternative to fine-grain Nb for the
fabrication of superconducting radio-frequency cavities. In this contribution
we report the results from a heat treatment study of a large-grain 1.5 GHz
single-cell cavity made of "medium purity" Nb. The baseline surface preparation
prior to heat treatment consisted of standard buffered chemical polishing. The
heat treatment in the range 800 - 1400 C was done in a newly designed vacuum
induction furnace. Q0 values of the order of 2x1010 at 2.0 K and peak surface
magnetic field (Bp) of 90 mT were achieved reproducibly. A Q0-value of
(5+-1)1010 at 2.0 K and Bp = 90 mT was obtained after heat treatment at 1400 C.
This is the highest value ever reported at this temperature, frequency and
field. Samples heat treated with the cavity at 1400 C were analyzed by
secondary ion mass spectrometry, secondary electron microscopy, energy
dispersive X-ray, point contact tunneling and X-ray diffraction and revealed a
complex surface composition which includes titanium oxide, increased carbon and
nitrogen content but reduced hydrogen concentration compared to a non
heat-treated sample
Evaluation of Ultrasonic Beam Models for the Case fo a Piston Transducer Radiating Through A Liquid-Solid Interface
In order to accurately predict the performance of immersion ultrasonic inspection techniques, it is necessary to have a model for the transducer radiation process. This model should include the case of propagation of the ultrasonic beam at oblique incidence through liquid-solid interfaces of complex geometries. Included should be the effects of diffraction, refraction, focussing and aberrations upon the beam shape
The effect of Fe atoms on the adsorption of a W atom on W(100) surface
We report a first-principles calculation that models the effect of iron (Fe)
atoms on the adsorption of a tungsten (W) atom on W(100) surfaces. The
adsorption of a W atom on a clean W(100) surface is compared with that of a W
atom on a W(100) surface covered with a monolayer of Fe atoms. The total energy
of the system is computed as the function of the height of the W adatom. Our
result shows that the W atom first adsorbs on top of the Fe monolayer. Then the
W atom can replace one of the Fe atoms through a path with a moderate energy
barrier and reduce its energy further. This intermediate site makes the
adsorption (and desorption) of W atoms a two-step process in the presence of Fe
atoms and lowers the overall adsorption energy by nearly 2.4 eV. The Fe atoms
also provide a surface for W atoms to adsorb facilitating the diffusion of W
atoms. The combination of these two effects result in a much more efficient
desorption and diffusion of W atoms in the presence of Fe atoms. Our result
provides a fundamental mechanism that can explain the activated sintering of
tungsten by Fe atoms.Comment: 9 pages, 2 figure
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