A quantum mechanical approach to establishing the magnetic field orientation from a maser Zeeman profile

Recent comparisons of magnetic field directions derived from maser Zeeman splitting with those derived from continuum source rotation measures have prompted new analysis of the propagation of the Zeeman split components, and the inferred field orientation. In order to do this, we first review differing electric field polarization conventions used in past studies. With these clearly and consistently defined, we then show that for a given Zeeman splitting spectrum, the magnetic field direction is fully determined and predictable on theoretical grounds: when a magnetic field is oriented away from the observer, the left-hand circular polarization is observed at higher frequency and the right-hand polarization at lower frequency. This is consistent with classical Lorentzian derivations. The consequent interpretation of recent measurements then raises the possibility of a reversal between the large-scale field (traced by rotation measures) and the small-scale field (traced by maser Zeeman splitting).Comment: 10 pages, 5 Figures, accepted for publication in MNRA

Microwave oven fabricated hybrid memristor devices for non-volatile memory storage

© 2014 IOP Publishing Ltd. Novel hybrid non-volatile memories made using an ultra-fast microwave heating method are reported for the first time. The devices, consisting of aligned ZnO nanorods embedded in poly (methyl methacrylate), require no forming step and exhibit reliable and reproducible bipolar resistive switching at low voltages and with low power usage. We attribute these properties to a combination of the high aspect ratio of the nanorods and the polymeric hybrid structure of the device. The extremely easy, fast and low-cost solution based method of fabrication makes possible the simple and quick production of cheap memory cells

Multi-component particle-size segregation in shallow granular avalanches

A general continuum theory for particle-size segregation and diffusive remixing in polydisperse granular avalanches is formulated using mixture theory. Comparisons are drawn to existing segregation theories for bi-disperse mixtures and the case of a ternary mixture of large, medium and small particles is investigated. In this case, the general theory reduces to a system of two coupled parabolic segregation-remixing equations, which have a single diffusion coefficient and three parameters which control the segregation rates between each pair of constituents. Considerable insight into many problems where the effect of diffusive remixing is small is provided by the non-diffusive case. Here the equations reduce to a system of two first-order conservation laws, whose wave speeds are real for a very wide class of segregation parameters. In this regime, the system is guaranteed to be non-strictly hyperbolic for all admissible concentrations. If the segregation rates do not increase monotonically with the grain-size ratio, it is possible to enter another region of parameter space, where the equations may either be hyperbolic or elliptic, depending on the segregation rates and the local particle concentrations. Even if the solution is initially hyperbolic everywhere, regions of ellipticity may develop during the evolution of the problem. Such regions in a time-dependent problem necessarily lead to short wavelength Hadamard instability and ill-posedness. A linear stability analysis is used to show that the diffusive remixing terms are sufficient to regularize the theory and prevent unbounded growth rates at high wave numbers. Numerical solutions for the time-dependent segregation of an initially almost homogeneously mixed state are performed using a standard Galerkin finite element method. The diffuse solutions may be linearly stable or unstable, depending on the initial concentrations. In the linearly unstable region, ‘sawtooth' concentration stripes form that trap and focus the medium-sized grains. The large and small particles still percolate through the avalanche and separate out at the surface and base of the flow due to the no-flux boundary conditions. As these regions grow, the unstable striped region is annihilated. The theory is used to investigate inverse distribution grading and reverse coarse-tail grading in multi-component mixtures. These terms are commonly used by geologists to describe particle-size distributions in which either the whole grain-size population coarsens upwards, or just the coarsest clasts are inversely graded and a fine-grained matrix is found everywhere. An exact solution is constructed for the steady segregation of a ternary mixture as it flows down an inclined slope from an initially homogeneously mixed inflow. It shows that for distribution grading, the particles segregate out into three inversely graded sharply segregated layers sufficiently far downstream, with the largest particles on top, the fines at the bottom and the medium-sized grains sandwiched in between. The heights of the layers are strongly influenced by the downstream velocity profile, with layers becoming thinner in the faster moving near-surface regions of the avalanche, and thicker in the slowly moving basal layers, for the same mass flux. Conditions for the existence of the solution are discussed and a simple and useful upper bound is derived for the distance at which all the particles completely segregate. When the effects of diffusive remixing are included, the sharp concentration discontinuities are smoothed out, but the simple shock solutions capture many features of the evolving size distribution for typical diffusive remixing rates. The theory is also used to construct a simple model for reverse coarse-tail grading, in which the fine-grained material does not segregate. The numerical method is used to calculate diffuse solutions for a ternary mixture and a sharply segregated shock solution is derived that looks similar to the segregation of a bi-disperse mixture of large and medium grains. The presence of the fine-grained material, however, prevents high concentrations of large or medium particles being achieved and there is a significant lengthening of the segregation distanc

Segregation, recirculation and deposition of coarse particles near two-dimensional avalanche fronts

Stratification patterns are formed when a bidisperse mixture of large rough grains and smaller more mobile particles is poured between parallel plates to form a heap. At low flow rates discrete avalanches flow down the free surface and are brought to rest by the propagation of shock waves. Experiments performed in this paper show that the larger particles are segregated to the top of the avalanche, where the velocity is greatest, and are transported to the flow front. Here the particles are overrun but may rise to the free surface again by size segregation to create a recirculating coarse-grained front. Once the front is established composite images show that there is a steady regime in which any additional large grains that reach the front are deposited. This flow is therefore analogous to finger formation in geophysical mass flows, where the larger less mobile particles are shouldered aside to spontaneously form static lateral levees rather than being removed by basal deposition in two dimensions. At the heart of all these phenomena is a dynamic feedback between the bulk flow and the evolving particle-size distribution within the avalanche. A fully coupled theory for such segregation-mobility feedback effects is beyond the scope of this paper. However, it is shown how to derive a simplified uncoupled travelling-wave solution for the avalanche motion and reconstruct the bulk two-dimensional flow field using assumed velocity profiles through the avalanche depth. This allows a simple hyperbolic segregation theory to be used to construct exact solutions for the particle concentration and for the recirculation within the bulk flow. Depending on the material composition and the strength of the segregation and deposition, there are three types of solution. The coarse-particle front grows in length if more large particles arrive than can be deposited. If there are fewer large grains and if the segregation is strong enough, a breaking size-segregation wave forms at a unique position behind the front. It consists of two expansion fans, two shocks and a central ‘eye' of constant concentration that are arranged in a ‘lens-like' structure. Coarse grains just behind the front are recirculated, while those reaching the head are overrun and deposited. Upstream of the wave, the size distribution resembles a small-particle ‘sandwich' with a raft of rapidly flowing large particles on top and a coarse deposited layer at the bottom, consistent with the experimental observations made here. If the segregation is weak, the central eye degenerates, and all the large particles are deposited without recirculatio

Particle-size and -density segregation in granular free-surface flows

When a mixture of particles, which differ in both their size and their density, avalanches downslope, the grains can either segregate into layers or remain mixed, dependent on the balance between particle-size and particle-density segregation. In this paper, binary mixture theory is used to generalize models for particle-size segregation to include density differences between the grains. This adds considerable complexity to the theory, since the bulk velocity is compressible and does not uncouple from the evolving concentration fields. For prescribed lateral velocities, a parabolic equation for the segregation is derived which automatically accounts for bulk compressibility. It is similar to theories for particle-size segregation, but has modified segregation and diffusion rates. For zero diffusion, the theory reduces to a quasilinear first-order hyperbolic equation that admits solutions with discontinuous shocks, expansion fans and one-sided semi-shocks. The distance for complete segregation is investigated for different inflow concentrations, particle-size segregation rates and particle-density ratios. There is a significant region of parameter space where the grains do not separate completely, but remain partially mixed at the critical concentration at which size and density segregation are in exact balance. Within this region, a particle may rise or fall dependent on the overall composition. Outside this region of parameter space, either size segregation or density segregation dominates and particles rise or fall dependent on which physical mechanism has the upper hand. Two-dimensional steady-state solutions that include particle diffusion are computed numerically using a standard Galerkin solver. These simulations show that it is possible to define a Péclet number for segregation that accounts for both size and density differences between the grains. When this Péclet number exceeds 10 the simple hyperbolic solutions provide a very useful approximation for the segregation distance and the height of rapid concentration changes in the full diffusive solution. Exact one-dimensional solutions with diffusion are derived for the steady-state far-field concentration.</jats:p

An experimental scaling law for particle-size segregation in dense granular flows

Particles of differing sizes are notoriously prone to segregation in shear driven flows under the action of gravity. This has important implications in many industrial processes, where particle-size segregation can lead to flow problems and reduced product quality, as well as longer product development and start-up times. Particle-size segregation also readily occurs in many hazardous geophysical mass flows (such as snow avalanches, debris flows and volcanic pyroclastic flows) and can lead to the formation of destructive bouldery flow fronts and significantly longer runouts. Although general theories exist to model particle-size segregation, the detailed functional dependence of the segregation flux on the shear rate, gravity, pressure, particle concentration, grain size and grain-size ratio is still not known. This paper describes refractive-index matched oscillatory shear-cell experiments that shed light on the segregation velocity in the two extreme cases of (i) a single large intruder rising up through a matrix of smaller grains, and (ii) a single small intruder percolating down through a matrix of large particles. Despite the sometimes markedly different time scales for segregation in these two situations, a unifying scaling law has been found that is able to collapse all the experimental data over a wide range of shear rates and grain-size ratios in the range . The resulting functional form is easily generalizable to intermediate concentrations and can quantitatively capture laboratory experiments and numerical simulations with a mix of large and small grains

Investigating hair zinc concentrations in children with and without atopic dermatitis

Background. Atopic dermatitis (AD) is a common chronic inflammatory skin condition that disproportionately affects children and is associated with reduced quality of life. Zinc deficiency may contribute to the pathogenesis of AD because zinc plays a role in epidermal barrier integrity and the immune system. Systematic review evidence suggests that low zinc is associated with AD, but limitations of included studies support further investigation.Objectives. To investigate hair zinc concentrations in children with AD v. healthy controls in a low- to middle-income country setting.Methods. One hundred and five children aged 1 - 12 yea­rs participated in a frequency-matched for age case-control study. The outcome variable, AD, was confirmed by a clinician and corroborated using the UK Working Party criteria. The primary predictor, long-term average zinc concentration, was determined by measuring hair zinc using inductively coupled mass spectrometry. Baseline demographic characteristics, anthropometry and measures of socioeconomic status were included in our logistic regression analysis. Subgroup analysis was performed where interaction terms suggested effect modification.Results. Using data from the overall sample, population median hair zinc was not significantly different between children with AD and healthy controls. However, subgroup analysis suggested a clinically and statistically significant difference in median zinc between children with AD (175.35 µg/g) and healthy controls (206.4 µg/g) in the older age group (5 - 12 years) (p=0.01). In this age group, multivariable logistic regression analysis also found significantly decreased hair zinc concentrations in AD (odds ratio 0.83; 95% confidence interval 0.66 - 0.96; p=0.046).Conclusions. The inverse association between zinc status and AD in children aged 5 - 12 years in our setting is consistent with the international literature. The clinical importance of decreased zinc levels in AD is not yet known. Further investigation into relevant underlying mechanisms seems warranted given the global reach of AD, its effect on quality of life, and the low cost of potential zinc-based interventions.

Ion and polymer dynamics in polymer electrolytes PPO-LiClO4: II. 2H and 7Li NMR stimulated-echo experiment

We use 2H NMR stimulated-echo spectroscopy to measure two-time correlation functions characterizing the polymer segmental motion in polymer electrolytes PPO-LiClO4 near the glass transition temperature Tg. To investigate effects of the salt on the polymer dynamics, we compare results for different ether oxygen to lithium ratios, namely, 6:1, 15:1, 30:1 and infinity. For all compositions, we find nonexponential correlation functions, which can be described by a Kohlrausch function. The mean correlation times show quantitatively that an increase of the salt concentration results in a strong slowing down of the segmental motion. Consistently, for the high 6:1 salt concentration, a high apparent activation energy E_a=4.1eV characterizes the temperature dependence of the mean correlation times at Tg < T< 1.1T_g, while smaller values E_a=2.5eV are observed for moderate salt contents. The correlation functions are most nonexponential for 15:1 PPO-LiClO4, whereas the stretching is reduced for higher and lower salt concentrations. A similar dependence of the correlation functions on the evolution time in the presence and in the absence of ions indicates that addition of salt hardly affects the reorientational mechanism. For all compositions, mean jump angles of about 15 degree characterize the segmental reorientation. In addition, comparison of results from 2H and 7Li NMR stimulated-echo experiments suggests a coupling of ion and polymer dynamics in 15:1 PPO-LiClO4.Comment: 14 pages, 12 figure

Delivering services by building and running virtual organisations

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