46,871 research outputs found
A New Equation of State for CCS Pipeline Transport: Calibration of Mixing Rules for Binary Mixtures of CO2 with N2, O2 and H2
One of the aspects currently holding back commercial scale deployment of
carbon capture and storage (CCS) is an accurate understanding of the
thermodynamic behaviour of carbon dioxide and relevant impurities during the
pipeline transport stage. In this article we develop a general framework for
deriving pressure-explicit EoS for impure CO2. This flexible framework
facilitates ongoing development of custom EoS in response to new data and
computational applications. We use our method to generalise a recent EoS for
pure CO2 [Demetriades et al. Proc IMechE Part E, 227 (2013) pp. 117] to binary
mixtures with N2, O2 and H2, obtaining model parameters by fitting to
experiments made under conditions relevant to CCS-pipeline transport. Our model
pertains to pressures up to 16MPa and temperatures between 273K and the
critical temperature of pure CO2. In this region, we achieve close agreement
with experimental data. When compared to the GERG EoS, our EoS has a comparable
level of agreement with CO2 -N2 VLE experiments and demonstrably superior
agreement with the O2 and H2 VLE data. Finally, we discuss future options to
improve the calibration of EoS and to deal with the sparsity of data for some
impurities
Survival of Theileria parva in its nymphal tick vector Rhipicephalus appendiculatus under laboratory and quasi natural conditions
Groups of nymphal Rhipicephalus appendiculatus Muguga, having a mean of 1 or 9 Theileria parva Muguga-infected salivary gland acini per tick, were kept under quasi-natural conditions at an altitude of 1950 m or 20Ā°C at a relative humidity of 85% in the laboratory and their survival and infection prevalence and abundance determined over time. Theileria parva infections for both categories of ticks survived in the nymphal ticks for 50 or 26 weeks post salivary gland infection under quasi-natural or laboratory conditions respectively. There was a distinct decline in infections in the more heavily infected nymphae under both conditions of exposure, reflecting an apparent density dependence in parasite survival. Nymphal ticks having an average infection level of 1 infected salivary gland acinus per tick, survived for up to 69 or 65 weeks post-repletion under quasi-natural or the laboratory conditions respectively. Nymphae having an average infection level of 9 infected salivary gland acini per tick survived for a similar duration under each of the 2 conditions. The infection level of 9 infected salivary gland acini per tick did not seem to significantly affect the survival of the tick vector compared to those having an average of 1 infected salivary gland acinus per tick
Synthesis and characterisation of Fe<sub>6</sub> and Fe<sub>12</sub> clusters using bicine
Reaction of bicine {BicH3, N,N-bis(2-hydroxyethyl)glycine} with an Fe(III) oxo-centered pivalate triangle in MeCN in the presence of Et<sub>2</sub>NH yields [Et<sub>2</sub>NH<sub>2</sub>]<sub>2</sub>[Fe<sub>6</sub>O<sub>2</sub>(OH)<sub>2</sub>(Bic)<sub>2</sub>(O<sub>2</sub>CCMe<sub>3</sub>)<sub>8</sub>], which possesses an S = 5 ground state.
Changing the base to NaOMe produces [Fe<sub>12</sub>O<sub>4</sub>(Bic)<sub>4</sub>(HBic)<sub>4</sub>(O<sub>2</sub>CCMe<sub>3</sub>)<sub>8</sub>], which contains two Fe6 units bridged by the carboxylate arms from the bicine ligands. The complex displays strong antiferromagnetic coupling leading to an S = 0 ground state
A Surprising Lack of LGRB Metallicity Evolution with Redshift
Recent additions to the population of Long-duration Gamma Ray Burst (LGRB)
host galaxies with measured metallicities and host masses allow us to
investigate how the distributions of both these properties change with
redshift. We form a sample out to z of 2.5 which we show does not have strong
redshift dependent populations biases in mass and metallicity measurements.
Using this sample, we find a surprising lack of evolution in the LGRB
metallicity distribution across different redshifts and in particular the
fraction of LGRB hosts with relatively high-metallicity, that is those with
12+log(O/H) > 8.4, remains essentially constant out to z = 2.5. This result is
at odds with the evolution in the mass metallicity relation of typical
galaxies, which become progressively more metal poor with increasing redshift.
By converting the measured LGRB host masses and redshifts to expected
metallicities using redshift appropriate mass-metallicity relations, we further
find that the increase in LGRB host galaxy mass distribution with redshift seen
in the Perley et al. (2016) SHOALS sample is consistent with that needed to
preserve a non-evolving LGRB metallicity distribution. However, the estimated
LGRB host metallicity distribution is at least a quarter dex higher at all
redshifts than the measured metallicity distribution. This corresponds to about
a factor of two in raw metallicity and resolves much of the difference between
the LGRB host metallicity cutoffs determined by Graham & Fruchter (2017) and
Perley et al. (2016). As LGRB hosts do not follow the general mass metallicity
relations, there is no substitute for actually measuring their metallicities.Comment: 20 pages, 7 figures, 10 table
Evolving collective behavior in an artificial ecology
Collective behavior refers to coordinated group motion, common to many animals. The dynamics of a group can be seen as a distributed model, each āanimalā applying the same rule set. This study investigates the use of evolved sensory controllers to produce schooling behavior. A set of artificial creatures āliveā in an artificial world with hazards and food. Each creature has a simple artificial neural network brain that controls movement in different situations. A chromosome encodes the network structure and weights, which may be combined using artificial evolution with another chromosome, if a creature should choose to mate. Prey and predators coevolve without an explicit fitness function for schooling to produce sophisticated, nondeterministic, behavior. The work highlights the role of speciesā physiology in understanding behavior and the role of the environment in encouraging the development of sensory systems
Multi-Behavioral Endpoint Testing Of An 87-Chemical Compound Library In Freshwater Planarians
There is an increased recognition in the field of toxicology of the value of medium-to-high-throughput screening methods using in vitro and alternative animal models. We have previously introduced the asexual freshwater planarian Dugesia japonica as a new alternative animal model and proposed that it is particularly well-suited for the study of developmental neurotoxicology. In this paper, we discuss how we have expanded and automated our screening methodology to allow for fast screening of multiple behavioral endpoints, developmental toxicity, and mortality. Using an 87-compound library provided by the National Toxicology Program (NTP), consisting of known and suspected neurotoxicants, including drugs, flame retardants, industrial chemicals, polycyclic aromatic hydrocarbons (PAHs), pesticides and presumptive negative controls, we further evaluate the benefits and limitations of the system for medium-throughput screening, focusing on the technical aspects of the system. We show that, in the context of this library, planarians are the most sensitive to pesticides with 16/16 compounds causing toxicity and the least sensitive to PAHs, with only 5/17 causing toxicity. Furthermore, while none of the presumptive negative controls were bioactive in adult planarians, 2/5, acetaminophen and acetylsalicylic acid, were bioactive in regenerating worms. Notably, these compounds were previously reported as developmentally toxic in mammalian studies. Through parallel screening of adults and developing animals, planarians are thus a useful model to detect such developmental-specific effects, which was observed for 13 chemicals in this library. We use the data and experience gained from this screen to propose guidelines for best practices when using planarians for toxicology screens
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