Two geometrically frustrated magnets studied by neutron diffraction

In the pyrochlore compounds, Tb$_2$Ti$_2$O$_7$ and Tb$_2$Sn$_2$O$_7$, only the Tb$^{3+}$ ions are magnetic. They exhibit quite abnormal -- and, in view of their chemical similarity, strikingly different -- magnetic behaviour, as probed by neutron diffraction at ambient and applied pressure. Tb$_2$Ti$_2$O$_7$ is a cooperative paramagnet (`spin liquid'), without long range order at ambient pressure; however, it does become ordered under pressure. By contrast, Tb$_2$Sn$_2$O$_7$ enters an "ordered spin ice" state already at ambient pressure. We analyse a simple model which already clearly exhibits some of the qualitative features observed experimentally. Overall, comparing these two compounds emphasizes the power of small perturbations in selecting low-temperature states in geometrically frustrated systems.Comment: 6 pages, 4 figures, International Conference on Neutron Scattering Sydney(2005

Influence of hydrogen supply on emissive characteristics of pig with metal-hydride cathode

The experimental studies of the Penning-type charged particle source with metal hydride cathode are presented. In order to determine the mechanisms responsible for the emission of negative particles in the axial direction, the influence of different hydrogen feeding methods were studied. To simulate hydrogen desorption the cathode of special design was applied and to force only hydrogen ion-stimulated desorption the forced cooling metal hydride cathode was used.Представлены результаты экспериментального исследования источника заряженных частиц пеннинговского типа с металлогидридным катодом. С целью определения факторов, ответственных за эмиссию отрицательных частиц в аксиальном направлении, изучено влияние разных способов напуска водорода в ячейку. Для имитации десорбции применены катоды специальной конструкции и ион-стимулированная десорбция водорода за счет принудительного охлаждения металлогидридного катода.Представлено результати експериментального дослідження джерела заряджених частинок пенінговського типу з металогідридним катодом. З метою визначення факторів, що відповідають за емісію негативних частинок в аксіальному напрямку, вивчено вплив різних способів напуску водню в проміжок. Для імітації десорбції застосовані катода спеціальної конструкції і іон-стимульована десорбція водню за рахунок примусового охолодження металогідридного катоду

Magnetic fluctuations in frustrated Laves hydrides R(Mn_{1-x}Al_{x})_{2}H_{y}

By neutron scattering, we have studied the spin correlations and spin fluctuations in frustrated Laves hydrides, where magnetic disorder sets in the topologically frustrated Mn lattice. Below the transition towards short range magnetic order, static spin clusters coexist with fluctuating and alsmost uncorrelated spins. The magnetic response shows a complexe lineshape, connected with the presence of the magnetic inhomogeneities. Its analysis shows the existence of two different processes, relaxation and local excitations, for the spin fluctuations below the transition. The paramagnetic fluctuations are discussed in comparison with classical spin glasses, cluster glasses, and non Fermi liquid itinerant magnets

Magnetic Structure Of Cerhin5 As A Function Of Pressure And Temperature

We report magnetic neutron-diffraction and electrical resistivity studies on single crystals of the heavy-fermion antiferromagnet CeRhIn5 at pressures up to 2.3 GPa. These experiments show that the staggered moment of Ce and the incommensurate magnetic structure change weakly with applied pressure up to 1.63 GPa, where resistivity, specific heat and nuclear quadrupole resonance measurements confirm the presence of bulk superconductivity. This work places important constraints on an interpretation of the relationship between antiferromagnetism and unconventional superconductivity in CeRhIn 5.692244031244036Heffner, R.H., Norman, M.R., (1996) Comments Condens. Matter Phys., 17, p. 361Stewart, G.R., (2001) Rev. Mod. 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Interlayer Exchange Coupling Mediated by Valence Band Electrons

The interlayer exchange coupling mediated by valence band electrons in all-semiconductor IV-VI magnetic/nonmagnetic superlattices is studied theoretically. A 3D tight-binding model, accounting for the band and magnetic structure of the constituent superlattice components is used to calculate the spin-dependent part of the total electronic energy. The antiferromagnetic coupling between ferromagnetic layers in EuS/PbS superlattices is obtained, in agreement with the experimental evidences. The results obtained for the coupling between antiferromagnetic layers in EuTe/PbTe superlattices are also presented.Comment: 8 pages, 6 figures, to be submitted to Phys.Rev.

Electronic Structure of the Complex Hydride NaAlH4

Density functional calculations of the electronic structure of the complex hydride NaAlH4 and the reference systems NaH and AlH3 are reported. We find a substantially ionic electronic structure for NaAlH4, which emphasizes the importance of solid state effects in this material. The relaxed hydrogen positions in NaAlH4 are in good agreement with recent experiment. The electronic structure of AlH3 is also ionic. Implications for the binding of complex hydrides are discussed.Comment: 4 pages, 5 figure

Magnetic interactions in EuTe epitaxial layers and EuTe/PbTe superlattices

The magnetic properties of antiferromagnetic (AFM) EuTe epitaxial layers and short period EuTe/PbTe superlattices (SLs), grown by molecular beam epitaxy on (111) BaF$_2$ substrates, were studied by magnetization and neutron diffraction measurements. Considerable changes of the N\'eel temperature as a function of the EuTe layer thickness as well as of the strain state were found. A mean field model, taking into account the variation of the exchange constants with the strain-induced lattice distortions, and the nearest neighbor environment of a Eu atoms, was developed to explain the observed $T_{\text N}$ changes in wide range of samples. Pronounced interlayer magnetic correlations have been revealed by neutron diffraction in EuTe/PbTe SLs with PbTe spacer thickness up to 60 \AA. The observed diffraction spectra were analyzed, in a kinematical approximation, assuming partial interlayer correlations characterized by an appropriate correlation parameter. The formation of interlayer correlations between the AFM EuTe layers across the nonmagnetic PbTe spacer was explained within a framework of a tight-binding model. In this model, the interlayer coupling stems from the dependence of the total electronic energy of the EuTe/PbTe SL on the spin configurations in adjacent EuTe layers. The influence of the EuTe and PbTe layer thickness fluctuations, inherent in the epitaxial growth process, on magnetic properties and interlayer coupling is discussed.Comment: 17 pages, 19 figures, accepted to PR