Structure of MnO nanoparticles embedded into channel-type matrices

X-ray diffraction experiments were performed on MnO confined in mesoporous silica SBA-15 and MCM-41 matrices with different channel diameters. The measured patterns were analyzed by profile analysis and compared to numerical simulations of the diffraction from confined nanoparticles. From the lineshape and the specific shift of the diffraction reflections it was shown that the embedded objects form ribbon-like structures in the SBA-15 matrices with channels diameters of 47-87 {\AA}, and nanowire-like structures in the MCM-41 matrices with channels diameters of 24-35 {\AA}. In the latter case the confined nanoparticles appear to be narrower than the channel diameters. The physical reasons for the two different shapes of the confined nanoparticles are discussed.Comment: 8 pages, including 9 postscript figures, uses revtex4.cl

Evolution of the magnetic phase transition in MnO confined to channel type matrices. Neutron diffraction study

Neutron diffraction studies of antiferromagnetic MnO confined to MCM-41 type matrices with channel diameters 24-87 A demonstrate a continuous magnetic phase transition in contrast to a discontinuous first order transition in the bulk. The character of the magnetic transition transforms with decreasing channel diameter, showing the decreasing critical exponent and transition temperature, however the latter turns out to be above the N\'eel temperature for the bulk. This enhancement is explained within the framework of Landau theory taking into consideration the ternary interaction of the magnetic and associated structural order parameters.Comment: 6 pages pdf file, including 4 figures, uses revtex4.cl

Spin wave resonances in La_{0.7}Sr_{0.3}MnO_{3} films: measurement of spin wave stiffness and anisotropy field

We studied magnetic field dependent microwave absorption in epitaxial La$_{0.7}$Sr$_{0.3}$MnO$_{3}$ films using an X-band Bruker ESR spectrometer. By analyzing angular and temperature dependence of the ferromagnetic and spin-wave resonances we determine spin-wave stiffness and anisotropy field. The spin-wave stiffness as found from the spectrum of the standing spin-wave resonances in thin films is in fair agreement with the results of inelastic neutron scattering studies on a single crystal of the same composition [Vasiliu-Doloc et al., J. Appl. Phys. \textbf{83}, 7343 (1998)].Comment: 15 pages, 7 figures (now figure captions are included

FERROELECTRIC NANOCOMPOSITES WITH GOVERNED INTERFACE ON BASE OF MAGNETIC POROUS GLASSES

Two-phase (nonporous) magnetic alkali borosilicate glasses have been produced by induction melting. Their macroscopic properties and crystal structure have been studied and it is shown that in the silica skeleton there are the agglomerates of Fe3O4. These agglomerates are formed by monodomain nanoparticles of magnetite and demonstrate the superparamagnetic properties. After special thermal treatment (liquation process) and chemical etching the nanoporous matrices with random dendrite pore structure and magnetic properties have been produced. The channels (porous space) were filled by ferroelectric materials KH2PO4 (KDP), KH2PO4+(NH4)H2PO4 (KDP-ADP or KADP), and NaNO2 and the effect of applied magnetic fields on phase transitions in these nanocomposite have been studied. It has also been established that a restricted geometry changed essentially the phase diagram of KADP.

Effect of nanosize BaZrO3 inclusions on vortex parameters in YBaCuO

We report on the field dependence of the microwave complex resistivity data in YBa$_2$Cu$_3$O$_{7-x}$/BaZrO$_3$ films grown by PLD at various BaZrO$_3$ content. The data, analyzed within a recently developed general framework for the mixed-state microwave response of superconductors, yield the field dependence of the fluxon parameters such as the vortex viscosity and the pinning constant. We find that pinning undergoes a change of regime when the BaZrO$_3$ content in the target increases from 2.5 mol.% to 5 mol.%. Simultaneously, the vortex viscosity becomes an increasing function of the applied magnetic field. We propose a scenario in which flux lines are pinned as bundles, and a crossover from dilute point pins to dense c-axis correlated defects takes place between 2.5 and 5 mol.% in the BZO concentration. Our data are inconsistent with vortices occupying mainly the BaZrO$_3$ sites at low fields, and suggest instead that vortices occupy both BaZrO$_3$ sites and interstitials in the YBa$_2$Cu$_3$O$_{7-x}$ matrix, even at low fields.Comment: Presented at EUCAS 2009, to be published in J. Phys.:Conf. Serie

ESR of MnO embedded in silica nanoporous matrices with different topologies

Electron spin resonance (ESR) experiments were performed with antiferromagnetic MnO confined within a porous vycor-type glass and within MCM-type channel matrices. A signal from confined MnO shows two components from crystallized and amorphous MnO and depends on the pore topology. Crystallized MnO within a porous glass shows a behavior having many similarities to the bulk. In contrast with the bulk the strong ESR signal due to disordered "surface" spins is observed below the magnetic transition. With the decrease of channel diameter the fraction of amorphous MnO increases while the amount of crystallized MnO decreases. The mutual influence of amorphous and crystalline MnO is observed in the matrices with a larger channel diameter. In the matrices with a smaller channel diameter the ESR signal mainly originates from amorphous MnO and its behavior is typical for the highly disordered magnetic system.Comment: 7 pages pdf file, 5 figure

Time evolution of the microwave second-order response of YBaCuO powder

Transient effects in the microwave second-order response of YBaCuO powder are investigated. The time evolution of the second harmonic signal has been measured for about 300 s after the sample had been exposed to variations of the DC magnetic field. We show that in different time scales the transient response has different origin. In the time scale of milliseconds the transient response of samples in the critical state is ascribable to processes of flux redistribution induced by the switching on/off of the microwave field. At longer times, the time evolution of the second harmonic signal can be ascribed to motion of fluxons induced by the variation of the DC magnetic field. In particular, diffusive motion of fluxons determines the response in the first 10 seconds after the stop of the magnetic field variation; magnetic relaxation over the surface barrier determines the response in the time scale of minutes.Comment: 16 pages, 7 figures, submited to Physica

Tunable coaxial cavity resonator for linear and nonlinear microwave characterization of superconducting wires

We discuss experimental results obtained using a tunable cylindrical coaxial cavity constituted by an outer Cu cylinder and an inner Pb-BSCCO wire. We have used this device for investigating the microwave response of the superconducting wire, both in the linear and nonlinear regimes. In particular, by tuning the different modes of the cavity to make them resonant at exactly harmonic frequencies, we have detected the power emitted by the superconducting inner wire at the second- and third-harmonic frequency of the driving field. The results obtained in the nonlinear regime, whether for the microwave surface impedance or the harmonic emission, are qualitatively accounted for considering intergrain fluxon dynamics. The use of this kind of device can be of strong interest to investigate and characterise wires of large dimensions to be used for implementing superconducting-based microwave devices.Comment: 14 pages, 6 embedded figures, accepted for publication in Supercond. Sci. Techno

Unravelling the elusive antiferromagnetic order in wurtzite and zinc blende CoO polymorph nanoparticles

Although cubic rock salt‐CoO has been extensively studied, the magnetic properties of the main nanoscale CoO polymorphs (hexagonal wurtzite and cubic zinc blende structures) are rather poorly understood. Here, a detailed magnetic and neutron diffraction study on zinc blende and wurtzite CoO nanoparticles is presented. The zinc blende‐CoO phase is antiferromagnetic with a 3rd type structure in a face‐centered cubic lattice and a Néel temperature of TN (zinc‐blende) ≈225 K. Wurtzite‐CoO also presents an antiferromagnetic order, TN (wurtzite) ≈109 K, although much more complex, with a 2nd type order along the c‐axis but an incommensurate order along the y‐axis. Importantly, the overall magnetic properties are overwhelmed by the uncompensated spins, which confer the system a ferromagnetic‐like behavior even at room temperature