Electron spin resonance (ESR) experiments were performed with
antiferromagnetic MnO confined within a porous vycor-type glass and within
MCM-type channel matrices. A signal from confined MnO shows two components from
crystallized and amorphous MnO and depends on the pore topology. Crystallized
MnO within a porous glass shows a behavior having many similarities to the
bulk. In contrast with the bulk the strong ESR signal due to disordered
"surface" spins is observed below the magnetic transition. With the decrease of
channel diameter the fraction of amorphous MnO increases while the amount of
crystallized MnO decreases. The mutual influence of amorphous and crystalline
MnO is observed in the matrices with a larger channel diameter. In the matrices
with a smaller channel diameter the ESR signal mainly originates from amorphous
MnO and its behavior is typical for the highly disordered magnetic system.Comment: 7 pages pdf file, 5 figure