827 research outputs found
Cumulative structure function in terms of nucleonic wave function of the nucleus
The structure function of the nucleus in the cumulative region is
studied in terms of nucleon degrees of freedom. At high the resulting
expressions are presented as a sum of contributions from few-nucleon
correlations. Two-nucleon correlations are studied in some detail. Spin
variables are averaged out. In the region the structure functions are
calculated for the relativistic interaction proposed by F.Gross {\it et al}.
They are found to fall with faster than the exponential. For Carbon at
, where the method is not rigorously applicable, they turn out to be
rougly twice larger than the experimental data.Comment: text and 2 figures in LaTex, 7 figures in P
Bis(μ-2-tert-butylphenylimido-1:2κ2 N:N)chlorido-2κCl-(diethyl ether-1κO)(2η5-pentamethylcyclopentadienyl)lithiumtantalum(V)
In the title compound, [LiTa(C10H15)(C10H13N)2Cl(C4H10O)], the TaV atom is coordinated by a η5-pentamethylcyclopentadienyl (Cp*) ligand, a chloride ion and two N-bonded 2-tert-butylphenylimide dianions. With respect to the two N atoms, the chloride ion and the centroid of the Cp* ring, the tantalum coordination geometry is approximately tetrahedral. The lithium cation is bonded to both the 2-tert-butylphenylimide dianions and also a diethyl ether molecule, in an approximate trigonal planar arrangement. The Ta⋯Li separation is 2.681 (15) Å. In the crystal, a weak C—H⋯Cl interaction links the molecules. When compared to the 2,6-diisopropylphenylimide analogue (‘the Wigley derivative’) of the title compound, the two structures are conformationally matched with an overall r.m.s. difference of 0.461Å
Background due to stored electrons following nuclear decays in the KATRIN spectrometers and its impact on the neutrino mass sensitivity
The KATRIN experiment is designed to measure the absolute neutrino mass scale
with a sensitivity of 200 meV at 90% C.L. by high resolution tritium
beta-spectroscopy. A low background level of 10 mHz at the beta-decay endpoint
is required in order to achieve the design sensitivity. In this paper we
discuss a novel background source arising from magnetically trapped keV
electrons in electrostatic retarding spectrometers. The main sources of these
electrons are alpha-decays of the radon isotopes (219,220)Rn as well as
beta-decays of tritium in the volume of the spectrometers. We characterize the
expected background signal by extensive MC simulations and investigate the
impact on the KATRIN neutrino mass sensitivity. From these results we refine
design parameters for the spectrometer vacuum system and propose active
background reduction methods to meet the stringent design limits for the
overall background rate
Rational Engineering of a Flavoprotein Oxidase for Improved Direct Oxidation of Alcohols to Carboxylic Acids
The oxidation of alcohols to the corresponding carbonyl or carboxyl compounds represents a convenient strategy for the selective introduction of electrophilic carbon centres into carbohydrate-based starting materials. The O2-dependent oxidation of prim-alcohols by flavin-containing alcohol oxidases often yields mixtures of aldehyde and carboxylic acid, which is due to “over-oxidation” of the aldehyde hydrate intermediate. In order to directly convert alcohols into carboxylic acids, rational engineering of 5-(hydroxymethyl)furfural oxidase was performed. In an attempt to improve the binding of the aldehyde hydrate in the active site to boost aldehyde-oxidase activity, two active-site residues were exchanged for hydrogen-bond-donating and -accepting amino acids. Enhanced over-oxidation was demonstrated and Michaelis–Menten kinetics were performed to corroborate these findings
The development of parental monitoring during adolescence : A meta-analysis
As adolescents grow up, one of the important developmental tasks is to individuate themselves and to become more autonomous from parents. This requires a realignment of the parent-adolescent communication. The current meta-analytic study aims at identifying developmental changes in parent-adolescent communication, conceptualized within the parental monitoring framework, as entailing parental solicitation, control and knowledge, and adolescent’s disclosure and secrecy. Thirty-one longitudinal studies published between 2000 and 2015 were identified and included in the current meta-analysis. Informants, age at assessment and study duration were tested as moderators. Results showed a low to medium normative decline in parental control (Cohen’s d = −.395, 95% CI [−.541, −.249]), knowledge (d = −.245,95% CI [−.331, −.160] and adolescence disclosure (d = −.147, 95% CI [−.204, −.090]), and an increase in adolescent’s secrecy (d = .194, CI [031, .356]). Parental solicitation decreased based on parents’ (d = −.242, 95% CI[−.376, −.109]) but not on adolescents’ reports (d = .038, 95% CI[−.099, .175]). Another significant moderator was the duration of the study, with studies longer than 2 years being able to detect a more pronounced change in parental control than studies lasting less than 2 years (≤2 years, d = −.139 vs. duration > 2 years, d = −.581). Limitations of the current knowledge and new directions of studies are discussed.Peer reviewe
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