295 research outputs found
Disorder-Induced Shift of Condensation Temperature for Dilute Trapped Bose Gases
We determine the leading shift of the Bose-Einstein condensation temperature
for an ultracold dilute atomic gas in a harmonic trap due to weak disorder by
treating both a Gaussian and a Lorentzian spatial correlation for the quenched
disorder potential. Increasing the correlation length from values much smaller
than the geometric mean of the trap scale and the mean particle distance to
much larger values leads first to an increase of the positive shift to a
maximum at this critical length scale and then to a decrease.Comment: Author information under
http://www.theo-phys.uni-essen.de/tp/ags/pelster_di
Condensation of Ideal Bose Gas Confined in a Box Within a Canonical Ensemble
We set up recursion relations for the partition function and the ground-state
occupancy for a fixed number of non-interacting bosons confined in a square box
potential and determine the temperature dependence of the specific heat and the
particle number in the ground state. A proper semiclassical treatment is set up
which yields the correct small-T-behavior in contrast to an earlier theory in
Feynman's textbook on Statistical Mechanics, in which the special role of the
ground state was ignored. The results are compared with an exact quantum
mechanical treatment. Furthermore, we derive the finite-size effect of the
system.Comment: 18 pages, 8 figure
Platinum Group Metal-Doped Tungsten Phosphates for Selective C-H Activation of Lower Alkanes
Platinum group metal (PGM)-based catalysts are known to be highly active in the total combustion of lower hydrocarbons. However, through an alternative catalyst design reported in this paper by isolating PGM-based active sites in a tungsten phosphate matrix, we present a class of catalysts for selective oxidation of n-butane, propane, and propylene that do not contain Mo or V as redox-active elements. Two different catalyst concepts have been pursued. Concept A: isolating Ru-based active sites in a tungsten phosphate matrix coming upon as ReO3-type structure. Concept B: dilution of PGM-based active sites through the synthesis of X-ray amorphous Ru tungsten phosphates supported on SiO2. Using a high-throughput screening approach, model catalysts over a wide compositional range were evaluated for C3 and C4 partial oxidation. Bulk crystalline and supported XRD amorphous phases with similar Ru/W/P compositions showed comparable performance. Hence, for these materials, composition is more crucial than the degree of crystallinity. Further studies for optimization on second-generation supported systems revealed even better results. High selectivity for n-butane oxidation to maleic anhydride and propane oxidation to an acrolein/acrylic acid has been achieved
Orbital order in the low-dimensional quantum spin system TiOCl probed by ESR
We present electron spin resonance data of Ti (3) ions in single
crystals of the novel layered quantum spin magnet TiOCl. The analysis of the g
tensor yields direct evidence that the d_{xy} orbital from the t_{2g} set is
predominantly occupied and owing to the occurrence of orbital order a linear
spin chain forms along the crystallographic b axis. This result corroborates
recent theoretical LDA+U calculations of the band structure. The temperature
dependence of the parameters of the resonance signal suggests a strong coupling
between spin and lattice degrees of freedom and gives evidence for a transition
to a nonmagnetic ground state at 67 K.Comment: revised version, accepted for publication in Phys. Rev. B, Rapid Com
Frequency dependent polarisation switching in h-ErMnO
We report an electric-field poling study of the geometric-driven improper
ferroelectric h-ErMnO. From a detailed dielectric analysis we deduce the
temperature and frequency dependent range for which single-crystalline
h-ErMnO exhibits purely intrinsic dielectric behaviour, i.e., free from
extrinsic so-called Maxwell-Wagner polarisations that arise, for example, from
surface barrier layers. In this regime ferroelectric hysteresis loops as
function of frequency, temperature and applied electric fields are measured
revealing the theoretically predicted saturation polarisation in the order of 5
- 6 C/cm. Special emphasis is put on frequency-dependent polarisation
switching, which is explained in terms of domain-wall movement similar to
proper ferroelectrics. Controlling the domain walls via electric fields brings
us an important step closer to their utilization in domain-wall-based
electronics.Comment: 5 pages, 3 figure
Sleep-wake sensitive mechanisms of adenosine release in the basal forebrain of rodents : an in vitro study
Adenosine acting in the basal forebrain is a key mediator of sleep homeostasis. Extracellular adenosine concentrations increase during wakefulness, especially during prolonged wakefulness and lead to increased sleep pressure and subsequent rebound sleep. The release of endogenous adenosine during the sleep-wake cycle has mainly been studied in vivo with microdialysis techniques. The biochemical changes that accompany sleep-wake status may be preserved in vitro. We have therefore used adenosine-sensitive biosensors in slices of the basal forebrain (BFB) to study both depolarization-evoked adenosine release and the steady state adenosine tone in rats, mice and hamsters. Adenosine release was evoked by high K+, AMPA, NMDA and mGlu receptor agonists, but not by other transmitters associated with wakefulness such as orexin, histamine or neurotensin. Evoked and basal adenosine release in the BFB in vitro exhibited three key features: the magnitude of each varied systematically with the diurnal time at which the animal was sacrificed; sleep deprivation prior to sacrifice greatly increased both evoked adenosine release and the basal tone; and the enhancement of evoked adenosine release and basal tone resulting from sleep deprivation was reversed by the inducible nitric oxide synthase (iNOS) inhibitor, 1400 W. These data indicate that characteristics of adenosine release recorded in the BFB in vitro reflect those that have been linked in vivo to the homeostatic control of sleep. Our results provide methodologically independent support for a key role for induction of iNOS as a trigger for enhanced adenosine release following sleep deprivation and suggest that this induction may constitute a biochemical memory of this state
Quasi-one-dimensional antiferromagnetism and multiferroicity in CuCrO
The bulk magnetic properties of the new quasi-one-dimensional Heisenberg
antiferromagnet, CuCrO, were characterized by magnetic susceptibility, heat
capacity, optical spectroscopy, EPR and dielectric capacitance measurements and
density functional evaluations of the intra- and interchain spin exchange
interactions. We found type-II multiferroicity below the N\'{e}el temperature
of 8.2(5) K, arising from competing antiferromagnetic nearest-neighbor () and next-nearest-neighbor () intra-chain spin exchange
interactions. Experimental and theoretical results indicate that the ratio
is close to 2, putting CuCrO in the vicinity of
the Majumdar-Ghosh point.Comment: 9 pages, 8 figures, submitted to PR
Air–liquid interface cultures enhance the oxygen supply and trigger the structural and functional differentiation of intestinal porcine epithelial cells (IPEC)
The specific function of the epithelium as critical barrier between the intestinal lumen and the organism’s internal microenvironment is reflected by permanent maintenance of intercellular junctions and cellular polarity. The intestinal epithelial cells are responsible for absorption of nutritional components, facing mechanical stress and a changing oxygen supplementation via blood stream. Oxygen itself can regulate the barrier and the absorptive function of the epithelium. Therefore, we compared the dish cell culture, the transwell-like membrane culture and the oxygen enriched air–liquid interface (ALI) culture. We demonstrated strong influence of the different culture conditions on morphology and function of intestinal porcine epithelial cell lines in vitro. ALI culture resulted in a significant increase in cell number, epithelial cell layer thickness and expression as well as apical localisation of the microvilli-associated protein villin. Remarkable similarities regarding the morphological parameters were observed between ALI cultures and intestinal epithelial cells in vivo. Furthermore, the functional analysis of protein uptake and degradation by the epithelial cells demonstrated the necessity of sufficient oxygen supply as achieved in ALI cultures. Our study is the first report providing marked evidence that optimised oxygen supply using ALI cultures directly affects the morphological differentiation and functional properties of intestinal epithelial cells in vitro
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