Featured Facsimile: Mauro Giuliani’s \u3ci\u3eZwölf neue Wald-Ländler\u3c/i\u3e (Twelve New Forest-Ländler), Op. 23

Giuliani\u27s Zwölf neue Wald-Ländler (Twelve New Forest-Ländler), Op. 23, in score. It was first published by the prestigious firm of Artaria & Co., with plate no. 2710, advertised for sale on 27 January 1810. Characteristic of these waltzes were the chordal (triadic) melodies, inspired stylistically by yodelers and yodeling. The intervallic tuning of the guitar favors the performance of such melodies as these, which evoke a style of folk music that runs deep in Austrian musical consciousness. Usually performed in sets of twelve, all in the same key, a Ländler-reihe (set, or row) usually began slowly, accelerated gradually toward the middle of the set, and slowed down again towards the end

Deal2lkit: a Toolkit Library for High Performance Programming in deal.II

We propose a software design for the efficient and flexible handling of the building blocks used in high performance finite element simulations, through the pervasive use of parameters (parsed through parameter files). In the proposed design, all the building blocks of a high performance finite element program are built according to the command and composite design patterns.We present version 1.1.0 of the deal2lkit (deal.II ToolKit) library, which is a collection of modules and classes aimed at providing high level interfaces to several deal.II classes and functions, obeying the command and composite design patterns, and controlled via parameter files. Keywords: Object-orientation, Software design, Finite element methods, C+

Interaction of Cd(II) and Ni(II) terpyridine complexes with model polynucleotides: a multidisciplinary approach

Two metal complexes of 2,2′:6′,2″-terpyridine (terpy), i.e. Cd(terpy)Cl2 and Ni(terpy)Cl2·3H2O, have been prepared and extensively characterized. The interaction of Cd(terpy)Cl2 with synthetic DNA models, poly(dA-dT)·poly(dA-dT) (polyAT) and poly(dG-dC)·poly(dG-dC) (polyGC), has been studied by CD, fluorescence and UV-vis electronic absorption spectroscopy at several metal/polynucleotide-phosphate ratios and for different NaCl concentrations. All the experimental results indicate an intercalative mechanism of interaction. The optimized geometry of the cadmium complex intercalated between the sixth and seventh base pairs of (AT) and (GC) dodecanucleotide duplexes, obtained by quantum mechanics/molecular mechanics (QM/MM) calculations, lends support to the proposed mechanism. The calculated models provide some additional structural details of the intercalation complex at the molecular level. To evidence the influence of the charge and geometry of the metal complex on the mechanism of interaction with polynucleotides, the nickel complex-polyAT system has been studied to some extent by means of CD and UV-vis spectroscopy, and by thermal melting experiments. The results suggest that the octahedral complex cation [Ni(terpy)(H2O)2Cl]+ interacts with polyAT by partial intercalation assisted by electrostatic interaction with the negative charges of the backbone phosphate groups

Influence of TiHX Addition on SHS Porous Shape Memory Alloy

Abstract Porous NiTi alloys are receiving considerable attention as they can be used as scaffold for bone replacement. Most production routes presented in the literature use metal powders as raw material (pure Ni and Ti or prealloyed NiTi powders): among these processes, Self propagating High temperature Synthesis (SHS) is investigated as a possible energy saving, quick and easy method of production. To obtain porous NiTi, compacted Ti and Ni powders are preheated and then ignited, avoiding high reaction temperatures at which the compound melts and consequently pores collapse. A drawback of low reaction temperatures is the formation of secondary phases. In this paper the addition of hydrided titanium (TiHX, x=1.5-1.9) powder is considered. During the reaction, hydrided titanium endothermically decomposes and can act as process controlling media. Reference Ni-Ti and Ni-TiHx mixed powders were reacted and the temperature evolution monitored. Differential Scanning Calorimetry was used to verify the presence of transforming phases (austenite, martensite). Microstructure characterization was performed with X-ray diffraction analysis and scanning electron microscope, equipped with EDX and EBSD detectors. The results confirmed that decomposition of hydrided titanium is the controlling process of the reaction, limiting the availability of Ti and absorbing reaction heat. The presence of TiHx can suppress SHS reaction, leaving un-reacted Ni and Ti powders and high amount of other intermetallic phases. If partial or complete decomposition of TiHx is allowed during preheating of reactants, NiTi production can occur: secondary phases content decreases for increased decomposition of TiHx before SHS reaction

Modelling Environmental Fate and Transport of POPs and Metal Usig the Fugacity/Aquivalence approach: Two Acquatic Environments as a Case Study.

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Clastogenicity and aneuploidy in newborn and adult mice exposed to 50 Hz magnetic fields.

Purpose:?To detect possible clastogenic and aneugenic properties of a 50 Hz, 650 ?T magnetic field. Materials and methods:?The micronucleus test with CREST (Calcinosis, Raynaud's phenomenon, Esophageal dismotility, Sclerodactility, Telangectasia) antibody staining was performed on liver and peripheral blood sampled from newborn mice exposed to an ELF (Extremely Low Frequency) magnetic field during the whole intra-uterine life (21 days), and on bone marrow and peripheral blood sampled from adult mice exposed to the same magnetic field for the same period. Results:?Data obtained in newborn mice show a significant increase in micronuclei frequencies. In absolute terms, most of the induced micronuclei were CREST-negative (i.e., formed by a chromosome fragment). However, in relative terms, ELF exposure caused a two-fold increase in CREST-negative micronuclei and a four-fold increase in CREST-positive micronuclei (i.e., formed by a whole chromosome). No significant effect was recorded on exposed adults. Conclusions:?These findings suggest the need for investigation of aneugenic properties of ELF magnetic fields in order to establish a possible relationship to carcinogenesis

Anthracyclines gels: Chemical structure and functional behaviour

Anthracyclines are a family of antibiotics often used in cancer chemotherapy. Daunorubicin (DA) was the first isolated from a strain of Streptomyces peucetius back in 1960 and still in use for the treatment of several malignancies together with the even more frequently used analogue Doxorubicin (DX, also called Adriamycin) and its semisynthetic derivative Epirubicyn (EPI). Despite their extremely close chemical formula (Figure 1), their properties when in solution are enormously different. In fact, whereas the increase of the ionic strength induces the formation of a gel with DX1-3, in the case of the related EPI and DA molecules what is observed are only the well-known self-association phenomena documented in the literature from decades4. Please click Additional Files below to see the full abstract

Identifying sources and pathways of persistant organic pollutants in aquatic environments

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Autonomous Observations in Antarctica with AMICA

The Antarctic Multiband Infrared Camera (AMICA) is a double channel camera operating in the 2-28 micron infrared domain (KLMNQ bands) that will allow to characterize and exploit the exceptional advantages for Astronomy, expected from Dome C in Antarctica. The development of the camera control system is at its final stage. After the investigation of appropriate solutions against the critical environment, a reliable instrumentation has been developed. It is currently being integrated and tested to ensure the correct execution of automatic operations. Once it will be mounted on the International Robotic Antarctic Infrared Telescope (IRAIT), AMICA and its equipment will contribute to the accomplishment of a fully autonomous observatory.Comment: 12 pages, 4 figures, Advances in Astronomy Journal, Special Issue "Robotic Astronomy", Accepted 11 February 201

Gerenciamento de riscos em cadeia de suprimentos

A importância de uma gestão transparente com práticas efetivas de Governança Corporativa favorece o Gerenciamento de Riscos, visto que empresas devem gerenciar adequadamente as oportunidades e ameaças as suas estratégias de negócios. Não obstante, a Cadeia de Suprimentos se tornou primordial para que as empresas possam ter vantagem competitiva. Este artigo aborda conceitos do Gerenciamento de Riscos citados na literatura e sua utilização para melhor Gerenciamento das Cadeias de Suprimentos. A metodologia de pesquisa é composta de um estudo teórico com posterior análise prática em uma empresa de autopeças. O estudo destaca a crescente abordagem deste tema, apesar de observar que ainda não há uma estrutura consensual para Gerenciamento de Riscos, e propõe uma estrutura de avaliação de risco em Cadeia de Suprimentos. Quanto ao estudo de caso, a empresa possui uma estrutura avançada para Gerenciamento dos Riscos com potenciais de aprimoramento frente à teoria e a proposta dos autores