Embodied energy and operational energy evaluation in tall buildings according to different typologies of façade

Abstract Although recent studies demonstrate the importance of including the Embodied Energy (EE) in building analysis, only the Operational Energy (OE) is currently taken into account in building energy demand calculation method. In particular, the EE plays an important role in tall buildings evaluation, because the energy demand increases with building height. Aim of this study was to assess the Embodied Energy in evaluation of different types of tall building facade systems performances along with the Operational Energy, pointing out the importance of taking into account both these aspects. Within the research activity here presented, 8 glazed envelope typologies, in 5 different climate zones, have been evaluated

Al, cu and zr addition to high entropy alloys: The effect on recrystallization temperature

The equimolar Cr, Mn, Fe, Co and Ni alloy, first produced in 2004, was unexpectedly found to be single-phase. Consequently, a new concept of materials was developed: high entropy alloys (HEA) forming a single solid-solution with a near equiatomic composition of the constituting elements. In this study, an equimolar CoCrFeMnNi HEA was modified by the addition of 5 at% of either Al, Cu or Zr. The cold-rolled alloys were annealed for 30 minutes at high temperature to investigate the recrystallization kinetics. The evolution of the grain boundary and the grain size were investigated, from the as-cast to the recrystallized state. Results show that the recrystallized single phase FCC structures exhibits different twin grains density, grain size and recrystallization temperatures as a function of the at.% of modifier alloying elements added. In comparison to the equimolar CoCrFeMnNi, the addition of modifier elements increases significantly the recrystallization temperature after cold deformation. The sluggish diffusion (typical of HEA alloys), the presence of a solute in solid solution as well as the low twin boundary energy are responsible for the lower driving force for recrystallization

Optimization of laser welding of dissimilar corrosion resistant alloys

The use of multi-materials components has the benefit of coupling each material's benefit where it is needed, thus achieving, for instance, heat, wear and corrosion resistance. Joining of dissimilar metals is a challenging task due to the large differences in properties. In this framework, the use of (Quasi Continuous Wave (QCW) Fiber Lasers) proved to be effective in multi-materials components assembly thanks to the high power density but low energy-input. In this paper the laser welding of dissimilar materials, namely stellite and stainless steel, is investigated and optimized in terms of corrosion resistance, comparing the results to conventional brazing joining. Results demonstrate that the optimized laser welding conditions, with the use of a proper filler material, lead to the obtainment of defect-free joints, with minimum alteration of the base materials

Attachment patterns and complex trauma in a sample of adults diagnosed with gender dysphoria

The current study investigated attachment representations and complex trauma in a sample of gender dysphoric adults. Although it has been proven that the psychological wellbeing of gender diverse persons is largely mediated by family acceptance and support, research on their relationships with parental figures is scarce. A total of 95 adults took part in the study. The attachment distribution was as follows: 27% secure, 27% insecure and 46% disorganized. Regarding early traumas, 56% experienced four or more traumatic forms. Further, gender dysphoric adults showed significantly higher levels of attachment disorganization and polyvictimisation, relative to controls. Comparisons of subgroups, defined by natal gender, showed that trans women, compared to control males, had more involving and physically and psychologically abusive fathers, and were more often separated from their mothers; trans men, relative to female controls, had more involving mothers and were more frequently separated from and neglected by their fathers. The research has several implications for treatment, clinical health psychology, family support and education

Coating of Titanium Substrates with ZrO2 and ZrO2-SiO2 Composites by Sol-Gel Synthesis for Biomedical Applications: Structural Characterization, Mechanical and Corrosive Behavior

The use of metallic materials as implants presents some major drawbacks, such as their harmful effects on the living organism, especially those induced by corrosion. To overcome this problem, the implant surface of titanium implants can be improved using a coating of bioactive and biocompatible materials. The aim of this work is the synthesis of SiO2/ZrO2 composites with different percentages of zirconia matrix (20, 33 and 50 wt.%), by the sol-gel method to coat commercial Grade 4 titanium disks using a dip coater. Attenuated total reflectance Fourier transform infrared (ATR/FTIR) spectroscopy was used to evaluate the interactions between the inorganic matrices. Furthermore, the mechanical properties and corrosive behavior of the SiO2/ZrO2 coatings were evaluated as a function of the ZrO2 content. The bioactive properties of the substrate coated with different composites were evaluated using simulated body fluid (SBF). The antibacterial activity was tested against gram-negative and gram-positive Escherichia coli and Enterococcus faecalis, respectively, to assess the release of toxic products from the different composites and to evaluate the possibility of using them in the biomedical field