1,608 research outputs found
Full characterization of vibrational coherence in a porphyrin chromophore by two-dimensional electronic spectroscopy
In this work we present experimental and calculated two-dimensional electronic spectra for a 5,15-bisalkynyl porphyrin chromophore. The lowest energy electronic Qy transition couples mainly to a single 380 cm–1 vibrational mode. The two-dimensional electronic spectra reveal diagonal and cross peaks which oscillate as a function of population time. We analyze both the amplitude and phase distribution of this main vibronic transition as a function of excitation and detection frequencies. Even though Feynman diagrams provide a good indication of where the amplitude of the oscillating components are located in the excitation-detection plane, other factors also affect this distribution. Specifically, the oscillation corresponding to each Feynman diagram is expected to have a phase that is a function of excitation and detection frequencies. Therefore, the overall phase of the experimentally observed oscillation will reflect this phase dependence. Another consequence is that the overall oscillation amplitude can show interference patterns resulting from overlapping contributions from neighboring Feynman diagrams. These observations are consistently reproduced through simulations based on third order perturbation theory coupled to a spectral density described by a Brownian oscillator model
Vortex-antivortex wavefunction of a degenerate quantum gas
A mechanism of a pinning of the quantized matter wave vortices by optical
vortices in a specially arranged optical dipole traps is discussed. The
vortex-antivortex optical arrays of rectangular symmetry are shown to transfer
angular orbital momentum and form the "antiferromagnet"-like matter waves. The
separable Hamiltonian for matter waves in pancake trapping geometry is proposed
and 3D-wavefunction is factorized in a product of wavefunctions of the 1D
harmonic oscillator and 2D vortex-antivortex quantum state. The 2D
wavefunction's phase gradient field associated via Madelung transform with the
field of classical velocities forms labyrinth-like structure. The macroscopic
quantum state composed of periodically spaced counter-rotating BEC superfluid
vortices has zero angular momentum and nonzero rotational energy.Comment: 11 pages, 5 figure
Resonant Two-Magnon Raman Scattering in Cuprate Antiferromagnetic Insulators
We present results of low-temperature two-magnon resonance Raman excitation
profile measurements for single layer Sr_2CuO_2Cl_2 and bilayer YBa_2Cu_3O_{6 +
\delta} antiferromagnets over the excitation region from 1.65 to 3.05 eV. These
data reveal composite structure of the two-magnon line shape and strong
nonmonotic dependence of the scattering intensity on excitation energy. We
analyze these data using the triple resonance theory of Chubukov and Frenkel
(Phys. Rev. Lett., 74, 3057 (1995)) and deduce information about magnetic
interaction and band parameters in these materials.Comment: REVTeX, 4 pages + 2 PostScript (compressed) figure
Test of exotic scalar and tensor interactions in K_e3 decay using stopped positive kaons
The form factors of the decay K+ --> pi0 e+ nu (K_e3) have been determined
from the comparison of the experimental and Monte Carlo Dalitz distributions
containing about 10^5 K_e3 events. The following values of the parameters were
obtained: lambda_+ = 0.0278 +- 0.0017(stat) +- 0.0015(syst), f_S/f_+(0) =
0.0040 +- 0.0160(stat) +- 0.0067(syst) and f_T/f_+(0) = 0.019 +- 0.080(stat) +-
0.038(syst). Both scalar f_S and tensor f_T form factors are consistent with
the Standard Model predictions of zero values.Comment: 10 pages, 5 figures, contributed to the proceedings of NANP
Conference, Dubna, June 19-23, 200
Measurement of the branching ratio of the decay KL -> pi e nu and extraction of the CKM parameter |Vus|
We present a new measurement of the branching ratio R of the decay KL -> pi e
nu (Ke3), relative to all charged KL decays with two tracks, based on data
taken with the NA48 detector at the CERN SPS. We measure R = 0.4978 +- 0.0035.
From this we derive the Ke3 branching fraction and the weak coupling
parameter |Vus| in the CKM matrix. We obtain |Vus|f+(0) = 0.2146 +- 0.0016,
where f+(0) is the vector form factor in the Ke3 decay.Comment: 18 pages, 8 figures. accepted by Phys Lett.
Critical temperature of an anisotropic superconductor containing both nonmagnetic and magnetic impurities
The combined effect of both nonmagnetic and magnetic impurities on the
superconducting transition temperature is studied theoretically within the BCS
model. An expression for the critical temperature as a function of potential
and spin-flip scattering rates is derived for a two-dimensional superconductor
with arbitrary in-plane anisotropy of the superconducting order parameter,
ranging from isotropic s-wave to d-wave (or any pairing state with nonzero
angular momentum) and including anisotropic s-wave and mixed (d+s)-wave as
particular cases. This expression generalizes the well-known Abrikosov-Gor'kov
formula for the critical temperature of impure superconductors. The effect of
defects and impurities in high temperature superconductors is discussed.Comment: 4 eps figure
Measurement of K^0_e3 form factors
The semileptonic decay of the neutral K meson, KL -> pi e nu (Ke3), was used
to study the strangeness-changing weak interaction of hadrons. A sample of 5.6
million reconstructed events recorded by the NA48 experiment was used to
measure the Dalitz plot density. Admitting all possible Lorentz-covariant
couplings, the form factors for vector (f_+(q^2)), scalar (f_S) and tensor
(f_T) interactions were measured. The linear slope of the vector form factor
lambda_+ = 0.0284+-0.0007+-0.0013 and values for the ratios |f_S/f_+(0)| =
0.015^{+0.007}_{-0.010}+-0.012 and |f_T/f_+(0)| = 0.05^{+0.03}_{-0.04}+-0.03
were obtained. The values for f_S and f_T are consistent with zero. Assuming
only Vector-Axial vector couplings, lambda_+ = 0.0288+-0.0004+-0.0011 and a
good fit consistent with pure V-A couplings were obtained. Alternatively, a fit
to a dipole form factor yields a pole mass of M = 859+-18 MeV, consistent with
the K^*(892) mass.Comment: 16 pages, 7 figures. submitted to Phys. Lett.
Metaphors in search of a target: the curious case of epigenetics
Carrying out research in genetics and genomics and communicating about them would not be possible without metaphors such as "information," "code," "letter" or "book." Genetic and genomic metaphors have remained relatively stable for a long time but are now beginning to shift in the context of synthetic biology and epigenetics. This article charts the emergence of metaphors in the context of epigenetics, first through collecting some examples of metaphors in scientific and popular writing and second through a systematic analysis of metaphors used in two UK broadsheets. Findings show that while source domains for metaphors can be identified, such as our knowledge of electrical switches or of bookmarks, it is difficult to pinpoint target domains for such metaphors. This may be indicative both of struggles over what epigenetics means for scientists (natural and social) and of difficulties associated with talking about this, as yet, young field in the popular press
Treatment response and remission in a double-blind, randomized, head-to-head study of lisdexamfetamine dimesylate and atomoxetine in children and adolescents with attention-deficit hyperactivity disorder
The Author(s) 2014. This article is published with open access at Springerlink.com Objectives A secondary objective of this head-to-head study of lisdexamfetamine dimesylate (LDX) and ato-moxetine (ATX) was to assess treatment response rates in children and adolescents with attention-deficit hyperactiv-ity disorder (ADHD) and an inadequate response to methylphenidate (MPH). The primary efficacy and safety outcomes of the study, SPD489-317 (ClinicalTrials.gov NCT01106430), have been published previously. Methods In this 9-week, double-blind, active-controlled study, patients aged 6–17 years with a previous inadequate response to MPH were randomized (1:1) to dose-optimized LDX (30, 50 or 70 mg/day) or ATX (patients \70 kg: 0.5–1.2 mg/kg/day, not to exceed 1.4 mg/kg/day; patients C70 kg: 40, 80 or 100 mg/day). Treatment response was a secondary efficacy outcome and was predefined as a reduction from baseline in ADHD Rating Scale IV (ADHD-RS-IV) total score of at least 25, 30 or 50 %. Sustained response was predefined as a reduction from baseline in ADHD-RS-IV total score (C25, C30 or C50 %) or a Clinical Global Impressions (CGI)–Improvement (CGI–I) score of 1 or 2 throughout weeks 4–9. CGI– Severity (CGI–S) scores were also assessed, as an indicator of remission. Results A total of 267 patients were enrolled (LDX, n = 133; ATX, n = 134) and 200 completed the study (LDX, n = 99; ATX, n = 101). By week 9, significantly (p \ 0.01) greater proportions of patients receiving LDX than ATX met the response criteria of a reduction from baseline in ADHD-RS-IV total score of at least 25 % (90.5 vs. 76.7 %), 30 % (88.1 vs. 73.7 %) or 50 % (73.0 vs. 50.4 %). Sustained response rates were also signifi-cantly (p \ 0.05) higher among LDX-treated patient
A meta-analysis of state-of-the-art electoral prediction from Twitter data
Electoral prediction from Twitter data is an appealing research topic. It
seems relatively straightforward and the prevailing view is overly optimistic.
This is problematic because while simple approaches are assumed to be good
enough, core problems are not addressed. Thus, this paper aims to (1) provide a
balanced and critical review of the state of the art; (2) cast light on the
presume predictive power of Twitter data; and (3) depict a roadmap to push
forward the field. Hence, a scheme to characterize Twitter prediction methods
is proposed. It covers every aspect from data collection to performance
evaluation, through data processing and vote inference. Using that scheme,
prior research is analyzed and organized to explain the main approaches taken
up to date but also their weaknesses. This is the first meta-analysis of the
whole body of research regarding electoral prediction from Twitter data. It
reveals that its presumed predictive power regarding electoral prediction has
been rather exaggerated: although social media may provide a glimpse on
electoral outcomes current research does not provide strong evidence to support
it can replace traditional polls. Finally, future lines of research along with
a set of requirements they must fulfill are provided.Comment: 19 pages, 3 table
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