The Behavior of Soluble Salt in Sharkey Clay

Soluble salt problems do exist and are significant in Arkansas. Studies have been conducted on Crowley silt loam (Typic Albaqualfs) which have established the behavior of soluble salt in that soil. The major objective of this study was to quantify the behavior of soluble salt in a second important Mississippi River Delta soil - the Sharkey (Vertic Haplaquepts). To this end, estimation of the downward redistribution of salt and the estimation of various components of the water balance for this soil served as specific objectives. Field studies were designed to monitor the movement of salt in the Sharkey soil and to characterize selected components of the water balance. In total, three tentative conclusions may be drawn from the data. First, the infiltration for the Sharkey soil was approximately three times that of the Crowley silt loam. The average value was 29 cm for the rice season. Second, levee seepage, while significant for small plots, was shown to be small for production-sized fields. Levee seepage remained relatively constant throughout the season and averaged 0.025 nvfym/d. And third, downward redistribution of salt was large and appeared to follow a pattern where a peak occurred at the surface and, possibly, at the lower soil depths

A Comparison of Rainfall Estimation Techniques

This study compares two techniques that have been developed for rainfall and streamflow estimation with the aim of identifying strengths and weaknesses of each. The first technique utilises thin plate smoothing splines to develop rainfall surfaces for the catchment, which are then, in conjunction with daily point-wise rainfall data used to determine areal catchment estimates. The second technique develops a regression-based model relating elevation to total annual rainfall in order to scale rainfall for daily mean catchment rainfall estimates. Both approaches are compared in common catchments in the upper Murrumbidgee catchment. The comparison includes using the data from each of the approaches as input to a rainfall-runoff model and by comparison of the quality of modelled results to observed streamflow. The strengths, weaknesses and use for catchment managers in decision making are identified. The study results revealed that where rain station spatial density and data quality are high, both regression and the spline method perform equally as well in estimating long term rainfall trends. In conclusion, catchment managers could apply the simple regression technique over the sophisticated spline method to achieve the comparable results. This is particularly useful where an efficient yet simple method is required for assessing streamflow within similar catchments

Pyrolysis-GC×GC-TOFMS to characterize carbonaceous chondrites

Using pyrolysis-GCxGC-TOFMS to analyze organic carbon in carbonaceous chondrites gives a massive increase in both sensitivity and structural information from samples when compared to traditional Py-GC-MS

The Behavior of Soluble Salt in Sharkey Clay- II

Soluble salts have been shown to accumulate in Arkansas soils in sufficient quantities to impair crop plant growth. The major objective of this study was to describe the behavior of soluble chloride salt over long time periods in Sharkey clay - a major Mississippi Delta soil. Prior to flooding rice, leaching of chloride in response to rainfall was observed. The inclusion of a sandy subsoil layer reduced this effect presumably by limiting downward movement of water under unsaturated conditions. No lateral movement of the chloride salt was found during the period prior to flooding. Removal of soluble chloride salts from the top 100 cm of Sharkey soil was complete in a 1-2 year period depending on weather conditions. In a year where the rice cropping season was followed by a wet winter, losses were smaller than in a year where the rice cropping season was followed by a drier winter. These results suggested that removal of soluble salts via leaching in this soil was more efficient under less saturated soil conditions

Fractionated Martian Atmosphere – the Case of the Nakhlites, Revisited with Experiments

We report on fractionated noble gases in the Martian meterorites - a literature survey and new data

Aromatic moieties in meteorites: relics of interstellar grain processes?

The carbonaceous chondrite meteorites contain a record of the formation of the solar system, part of which is present within organic matter. This organic matter is predominantly aromatic, and its sources remain controversial. The δ13C values for individual free and macromolecular aromatic moieties from Cold Bokkeveld and Murchison suggest that these units originate from radiation-induced ``circle'' reactions involving simultaneous bond synthesis and cracking. Large carbon isotope fractionations and a deuterium enrichment for these entities suggest that these reactions occurred in a dense interstellar cloud. The juxtaposition of the synthesis and cracking products implies that the reactions occurred in a restricting medium, the most likely candidate for which is the icy organic mantles of interstellar grains. In contrast, the δ13C record in aromatic moieties from Orgueil is mostly obscured, possibly due to the increased levels of parent body aqueous alteration experienced by this meteorite. These novel observations are consistent with the interstellar-parent body hypothesis, where the final form of meteoritic organic matter results from the transfiguration of interstellar organic precursors by aqueous reactions on the meteorite parent body

Does body size predict the buzz-pollination frequencies used by bees?

Body size is an important trait linking pollinators and plants. Morphological matching between pollinators and plants is thought to reinforce pollinator fidelity, as the correct fit ensures that both parties benefit from the interaction. We investigated the influence of body size in a specialized pollination system (buzz‐pollination) where bees vibrate flowers to release pollen concealed within poricidal stamens. Specifically, we explored how body size influences the frequency of buzz‐pollination vibrations. Body size is expected to affect frequency as a result of the physical constraints it places on the indirect flight muscles that control the production of floral vibrations. Larger insects beat their wings less rapidly than smaller‐bodied insects when flying, but whether similar scaling relationships exist with floral vibrations has not been widely explored. This is important because the amount of pollen ejected is determined by the frequency of the vibration and the displacement of a bee's thorax. We conducted a field study in three ecogeographic regions (alpine, desert, grassland) and recorded flight and floral vibrations from freely foraging bees from 27 species across four families. We found that floral vibration frequencies were significantly higher than flight frequencies, but never exceeded 400 Hz. Also, only flight frequencies were negatively correlated with body size. As a bee's size increased, its buzz ratio (floral frequency/flight frequency) increased such that only the largest bees were capable of generating floral vibration frequencies that exceeded double that of their flight vibrations. These results indicate size affects the capacity of bees to raise floral vibration frequencies substantially above flight frequencies. This may put smaller bees at a competitive disadvantage because even at the maximum floral vibration frequency of 400 Hz, their inability to achieve comparable thoracic displacements as larger bees would result in generating vibrations with lower amplitudes, and thus less total pollen ejected for the same foraging effort

Better Nonlinear Models from Noisy Data: Attractors with Maximum Likelihood

A new approach to nonlinear modelling is presented which, by incorporating the global behaviour of the model, lifts shortcomings of both least squares and total least squares parameter estimates. Although ubiquitous in practice, a least squares approach is fundamentally flawed in that it assumes independent, normally distributed (IND) forecast errors: nonlinear models will not yield IND errors even if the noise is IND. A new cost function is obtained via the maximum likelihood principle; superior results are illustrated both for small data sets and infinitely long data streams.Comment: RevTex, 11 pages, 4 figure