An indirect limit on the amplitude of primordial Gravitational Wave Background from CMB-Galaxy Cross Correlation

While large scale cosmic microwave background (CMB) anisotropies involve a combination of the scalar and tensor fluctuations, the scalar amplitude can be independently determined through the CMB-galaxy cross-correlation. Using recently measured cross-correlation amplitudes, arising from the cross-correlation between galaxies and the Integrated Sachs Wolfe effect in CMB anisotropies, we obtain a constraint r < 0.5 at 68% confidence level on the tensor-to-scalar fluctuation amplitude ratio. The data also allow us to exclude gravity waves at a level of a few percent, relative to the density field, in a low - Lambda dominated universe(Omega_Lambda~0.5). In future, joining cross-correlation ISW measurements, which captures cosmological parameter information, with independent determinations of the matter density and CMB anisotropy power spectrum, may constrain the tensor-to-scalar ratio to a level above 0.05. This value is the ultimate limit on tensor-to-scalar ratio from temperature anisotropy maps when all other cosmological parameters except for the tensor amplitude are known and the combination with CMB-galaxy correlation allows this limit to be reached easily by accounting for degeneracies in certain cosmological parameters.Comment: 5 Pages, 1 Figure, revised discussion on cosmic variance limits on the tensor-to-scalar ratio from CMB, matches PRD accepted versio

Effects of standard and modified gravity on interplanetary ranges

We numerically investigate the impact on the two-body range by several Newtonian and non-Newtonian dynamical effects for some Earth-planet (Mercury, Venus, Mars, Jupiter, Saturn) pairs in view of the expected cm-level accuracy in some future planned or proposed interplanetary ranging operations (abridged).Comment: LaTex, World Scientific style, 46 pages, 55 figures, 1 table, 57 references. Version in press in International Journal of Modern Physics D (IJMPD

Chaplygin gas in light of recent Integrated Sachs--Wolfe effect data

We investigate the possibility of constraining Chaplygin dark energy models with current Integrated Sachs Wolfe effect data. In the case of a flat universe we found that generalized Chaplygin gas models must have an energy density such that $\Omega_c >0.55$ and an equation of state $w <-0.6$ at 95% c.l.. We also investigate the recently proposed Silent Chaplygin models, constraining $\Omega_c >0.55$ and $w <-0.65$ at 95% c.l.. Better measurements of the CMB-LSS correlation will be possible with the next generation of deep redshift surveys. This will provide independent and complementary constraints on unified dark energy models such as the Chaplygin gas.Comment: 5 pages, 4 figure

Cosmological and Solar-System Tests of f(R) Modified Gravity

We investigate the cosmological and the local tests of the f(R) theory of modified gravity via the observations of (1) the cosmic expansion and (2) the cosmic structures and via (3) the solar-system experiments. To fit the possible cosmic expansion histories under consideration, for each of them we reconstruct f(R), known as "designer f(R)". We then test the designer f(R) via the cosmic-structure constraints on the metric perturbation ratio Psi/Phi and the effective gravitational coupling G_eff and via the solar-system constraints on the Brans-Dicke theory with the chameleon mechanism. We find that among the designer f(R) models specified by the CPL effective equation of state w_eff, only the model closely mimicking general relativity with a cosmological constant (LambdaCDM) can survive all the tests. Accordingly, these tests rule out the frequently studied "w_eff = -1" designer f(R) models which are distinct in cosmic structures from LambdaCDM. When considering only the cosmological tests, we find that the surviving designer f(R) models, although exist for a variety of w_eff, entail fine-tuning.Comment: 22 pages, 9 figures, LaTe

Structure formation from non-Gaussian initial conditions: multivariate biasing, statistics, and comparison with N-body simulations

We study structure formation in the presence of primordial non-Gaussianity of the local type with parameters f_NL and g_NL. We show that the distribution of dark-matter halos is naturally described by a multivariate bias scheme where the halo overdensity depends not only on the underlying matter density fluctuation delta, but also on the Gaussian part of the primordial gravitational potential phi. This corresponds to a non-local bias scheme in terms of delta only. We derive the coefficients of the bias expansion as a function of the halo mass by applying the peak-background split to common parametrizations for the halo mass function in the non-Gaussian scenario. We then compute the halo power spectrum and halo-matter cross spectrum in the framework of Eulerian perturbation theory up to third order. Comparing our results against N-body simulations, we find that our model accurately describes the numerical data for wavenumbers k < 0.1-0.3 h/Mpc depending on redshift and halo mass. In our multivariate approach, perturbations in the halo counts trace phi on large scales and this explains why the halo and matter power spectra show different asymptotic trends for k -> 0. This strongly scale-dependent bias originates from terms at leading order in our expansion. This is different from what happens using the standard univariate local bias where the scale-dependent terms come from badly behaved higher-order corrections. On the other hand, our biasing scheme reduces to the usual local bias on smaller scales where |phi| is typically much smaller than the density perturbations. We finally discuss the halo bispectrum in the context of multivariate biasing and show that, due to its strong scale and shape dependence, it is a powerful tool for the detection of primordial non-Gaussianity from future galaxy surveys.Comment: 26 pages, 16 figures. Minor modifications, version accepted by Phys. Rev.

Letter. On the activation of [CrCl3{R-SN(H)S-R}] catalysts for selective trimerization of ethene: a freeze-quench Cr K-edge XAFS study

Homogeneous chromium catalysts for the selective conversion of ethene to hex-1-ene are formed from Cr(III) reagents, amino-thioether ligands of the type HN(CH2CH2SR)2, and aluminum reagents. In this study the early activation steps are investigated by EPR, UV-visible and Cr K-edge XAFS spectroscopy; rapid stopped-flow mixing and a freeze-quench allows good quality EXAFS analysis of a species formed in ~ 1 second of reaction. This is shown to involve reduction to Cr(II) and deprotonation of a NH group of the auxiliary ligand. This 4-coordinate metal-center may act as precursor for the coordination of ethene and subsequent selective oligomerization

Insights into the Structure of Dot@Rod and Dot@Octapod CdSe@CdS Heterostructures

CdSe@CdS dot@rods with diameter around 6 nm and length of either 20, 27, or 30 nm and dot@octapods with pod diameters of ?15 nm and lengths of ?50 nm were investigated by X-ray absorption spectroscopy. These heterostructures are prepared by seed-mediated routes, where the structure, composition, and morphology of the CdSe nanocrystals used as a seed play key roles in directing the growth of the second semiconducting domain. The local structural environment of all the elements in the CdSe@CdS heterostructures was investigated at the Cd, S, and Se K-edges by taking advantage of the selectivity of X-ray absorption spectroscopy, and was compared to pure reference compounds. We found that the structural features of dot@rods are independent of the size of the rods. These structures can be described as made of a CdSe dot and a CdS rod, both in the wurtzite phase with a high crystallinity of both the core and the rod. This result supports the effectiveness of high temperature colloidal synthesis in promoting the formation of core@shell nanocrystals with very low defectivity. On the other hand, data on the CdSe@CdS with octapod morphology suggest the occurrence of a core composed of a CdSe cubic sphalerite phase with eight pods made of CdS wurtzite phase. Our findings are compared to current models proposed for the design of functional heterostructures with controlled nanoarchitecture

Frontal brain asymmetries as effective parameters to assess the quality of audiovisual stimuli perception in adult and young cochlear implant users

How is music perceived by cochlear implant (CI) users? This question arises as "the next step" given the impressive performance obtained by these patients in language perception. Furthermore, how can music perception be evaluated beyond self-report rating, in order to obtain measurable data? To address this question, estimation of the frontal electroencephalographic (EEG) alpha activity imbalance, acquired through a 19-channel EEG cap, appears to be a suitable instrument to measure the approach/withdrawal (AW index) reaction to external stimuli. Specifically, a greater value of AW indicates an increased propensity to stimulus approach, and vice versa a lower one a tendency to withdraw from the stimulus. Additionally, due to prelingually and postlingually deafened pathology acquisition, children and adults, respectively, would probably differ in music perception. The aim of the present study was to investigate children and adult CI users, in unilateral (UCI) and bilateral (BCI) implantation conditions, during three experimental situations of music exposure (normal, distorted and mute). Additionally, a study of functional connectivity patterns within cerebral networks was performed to investigate functioning patterns in different experimental populations. As a general result, congruency among patterns between BCI patients and control (CTRL) subjects was seen, characterised by lowest values for the distorted condition (vs. normal and mute conditions) in the AW index and in the connectivity analysis. Additionally, the normal and distorted conditions were significantly different in CI and CTRL adults, and in CTRL children, but not in CI children. These results suggest a higher capacity of discrimination and approach motivation towards normal music in CTRL and BCI subjects, but not for UCI patients. Therefore, for perception of music CTRL and BCI participants appear more similar than UCI subjects, as estimated by measurable and not self-reported parameters