Decolorization of the dye reactive black 5 using Fenton oxidation

Study on the effect of Fenton process on decolorization and mineralization of RB-5 in aqueous solution is presented in this work. Batch experiments were carried out to find the optimal operational conditions including pH, temperature, H2O2 dosage, FeSO4 dosage and RB-5 concentration at low cost. Degradation of RB-5 dye as an organic pollutant was monitored based on decolorization and mineralization extents of the model solution determined by UV-vis spectrophotometric and chemical oxygen demand (COD) analysis respectively. Optimum pH and temperature for 250 mg/L RB-5 were observed at 3.0 and 40°C respectively and using 50 mg/L of FeSO4 and 300 mg/L of H2O2 resulted in generation of 58.9% COD and 97% color removal after 10 min reaction by Fenton. It is concluded that Fenton process can provide better result for decolorization compared to COD removal in the treatment of textile effluent.Keywords: Decolorization, black 5, Fenton oxidation, dyeAfrican Journal of Biotechnology Vol. 12(26), pp. 4115-412

Defluoridation of water via Light Weight Expanded Clay Aggregate (LECA): Adsorbent characterization, competing ions, chemical regeneration, equilibrium and kinetic modeling

International audienceNatural, H2O2 and MgCl2 - modified Light Weight Expanded Clay Aggregate (LECA) were used as fluoride adsorbents. Characterization of LECA and its modified forms was done by infra-red, X-ray diffraction, scanning electron microscope and X-ray fluorescence studies. The specific surface area of HML and MGML was 3.34 and 3.97 times greater than that of NL (11.72 m2/g). Improved chemical composition of Magnesium (as oxide) to 15.6% by 2 M MgCl2 solution was ascertained through XRF results. The fluoride levels were reduced (within the safe limit of WHO: 0.5-1.5 mg/L−1) to 0.39 mg/L, 1.0 mg/L and 0.075 mg/L respectively using natural (NL), H2O2 (HML) and MgCl2 - modified LECA (MGML) at a pH of 6.0 and initial fluoride concentration of 10 g/L for an equilibrium time of 120 min. The sorption capacities of 8.53 mg/g, 17.83 mg/g and 23.86 mg/g were determined for NL, HML and MGML respectively. Validation of kinetic and isotherm models was checked for the present fluoride sorption dynamics. The thermodynamic data revealed that the present fluoride sorption was spontaneous, exothermic and ends up with decrease in randomness. Prediction of fluoride sorption mechanism for onto natural and modified LECA forms was also elucidated. Chloride and sulfate were the highly competing species against fluoride sorption. Regeneration efficiency of the spent LECA materials prompted the ability of MGML even after five cycles of adsorption-regeneration processes

Data on physicochemical quality of drinking water in the rural area in Divandarreh county, Kurdistan, Iran

Good quality of drinking water is very important in the maintenance of human health. The gathered data from the present work was used to evaluate the quality of drinking water resources in the rural villages of Divandarreh, Iran. Physicochemical quality of water was determined by a collection of 35 random samples during dry and rainy seasons in 2015. The APHA approach was used to determine the physicochemical parameters of the samples. The results showed that the average concentration of Ca, Mg, Na, K, Cl, SO4, TDS and TH during dry season was 85.64 mg/l, 13.41 mg/l, 34.11 mg/l, 2.8 mg/l, 9.9 mg/l, 45.7 mg/l, 326.06 mg/l and 269.61 mg/l, respectively. Also, the average concentration of the parameters during rainy season was 77.3 mg/l, 18.27 mg/l, 30.3 mg/l, 1.9 mg/l, 12.54 mg/l, 39 mg/l, 269.1 mg/l and 316.17 mg/l, respectively. Keywords: Divandarreh, Physicochemical quality, Drinking water, Rural are