91 research outputs found
Electronic properties of the pseudogap system (TaSe4)2I
The room temperature ``metallic'' properties of the quasi-one-dimensional
charge density wave system (TaSe4)2I differ markedly from those expected of
either a Fermi or a Luttinger Liquid. We discuss evidence for the simplest
possible explanation of the observed behavior of (TaSe4)2I in its conducting
phase - namely the existence of large quasi-static fluctuations of structural
order, which however remain of finite extent above the charge density wave
transition temperature. These fluctuations produce a pseudogap in the density
of states. We compute the temperature dependence of the optical and DC
conductivities of (TaSe4)2I in its conducting phase, the nature of its core
hole spectra, and the NMR relaxation rate. Predictions for these quantities are
made on the basis of a Lee, Rice and Anderson model. This model represents the
simplest theory of a pseudogap, and gives satisfactory agreement with
experiment in the cases where comparisons can be made. In contrast, the
predictions of a strongly correlated (Luttinger Liquid) model appear to to
contradict the data. The chief remaining discrepancy is that the gap appearing
in transport quantities is less than that observed in photoemission. We discuss
some possibilities for resolving this issue.Comment: 41 pages latex, 11 ps figures, uses IOP macro
Spin-Waves in the Mid-Infrared Spectrum of Antiferromagnetic YBaCuO
The mid-infrared spin-wave spectrum of antiferromagnetic
YBaCuO\ was determined by infrared transmission and reflection
measurements (\bbox{k} \!\! \parallel c) at ~K.\@ Excitation of
single magnons of the optical branch was observed at
~meV.\@ Two further peaks at ~meV
() and ~meV
() both belong to the two-magnon spectrum. Linear
spin wave theory is in good agreement with the measured two-magnon spectrum,
and allows to determine the exchange constant to be about ~meV,
whereas the intrabilayer coupling is approximately .Comment: 3 figures in uuencoded for
Optical investigation of the charge-density-wave phase transitions in
We have measured the optical reflectivity of the quasi
one-dimensional conductor from the far infrared up to the
ultraviolet between 10 and 300 using light polarized along and normal to
the chain axis. We find a depletion of the optical conductivity with decreasing
temperature for both polarizations in the mid to far-infrared region. This
leads to a redistribution of spectral weight from low to high energies due to
partial gapping of the Fermi surface below the charge-density-wave transitions
at 145 K and 59 K. We deduce the bulk magnitudes of the CDW gaps and discuss
the scattering of ungapped free charge carriers and the role of fluctuations
effects
Optical conductivity of a quasi-one-dimensional system with fluctuating order
We describe a formally exact method to calculate the optical conductivity of
a one-dimensional system with fluctuating order. For classical phase
fluctuations we explicitly determine the optical conductivity by solving two
coupled Fokker-Planck equations numerically. Our results differ considerably
from perturbation theory and in contrast to Gaussian order parameter
fluctuations show a strong dependence on the correlation length.Comment: 7 pages, 2 figure
Anisotropic optical properties of single-crystal GdBa2Cu3O7-delta
The optical spectrum of reduced-T(c) GdBa2Cu3O7-delta has been measured for polarizations parallel and perpendicular to the ab plane. The sample was an oxygen-deficient single crystal with a large face containing the c axis. The polarized reflectance from this face was measured from 20-300 K in the spectral region from 30-3000 cm-1, with 300 K data to 30 000 cm-1. Kramers-Kronig analysis was used to determine the spectral dependence of the ab and the c components of the dielectric tensor. The optical properties are strongly anisotropic. The ab-plane response resembles that of other reduced-T(c) materials whereas the c axis, in contrast, shows only the presence of several phonons. There is a complete absence of charge carrier response along c above and below T(c). This observation allows us to set an upper limit to the free-carrier spectral weight for transport perpendicular to the CuO2 planes
Metabolic analysis of vitreous/lens and retina in wild type and retinal degeneration mice
Photoreceptors are the light-sensing cells of the retina and the major cell type affected in most inherited retinal degenerations. Different metabolic pathways sustain their high energetic demand in physiological conditions, particularly aerobic glycolysis. The principal metabolome of the mature retina has been studied, but only limited information is available on metabolic adaptations in response to key developmental events, such as eye opening. Moreover, dynamic metabolic changes due to retinal degeneration are not well understood. Here, we aimed to explore and map the ocular metabolic dynamics induced by eye opening in healthy (wild type) or Pde6b-mutant (retinal degeneration 1, Rd1) mice, in which photoreceptors degenerate shortly after eye opening. To unravel metabolic differences emerging before and after eye opening under physiological and pathophysiological conditions, we performed nuclear magnetic resonance (NMR) spectrosco-py-based metabolome analysis of wild type and Rd1 retina and vitreous/lens. We show that eye opening is accompanied by changes in the concentration of selected metabolites in the retina and by alterations in the vitreous/lens composition only in the retinal degeneration context. As such, we identify N-Acetylaspartate as a potential novel vitreous/lens marker reflecting progressive retinal degeneration. Thus, our data can help elucidating mechanisms underlying key events in retinal physiology and reveal changes occurring in pathology, while highlighting the importance of the vitreous/lens in the characterization of retinal diseases.Proteomic
Highly conducting perylene radical salts
Temperature dependent dc and microwave conductivity data together with EPR and optical reflectance measurements on the "mixed" system (pe)2(ASF6)0,75(PF6)0,35 times 0,85 CH2Cl2 are described. The data prove metallic behaviour of this organic solid down to 200 K
Optical study of orbital excitations in transition-metal oxides
The orbital excitations of a series of transition-metal compounds are studied
by means of optical spectroscopy. Our aim was to identify signatures of
collective orbital excitations by comparison with experimental and theoretical
results for predominantly local crystal-field excitations. To this end, we have
studied TiOCl, RTiO3 (R=La, Sm, Y), LaMnO3, Y2BaNiO5, CaCu2O3, and K4Cu4OCl10,
ranging from early to late transition-metal ions, from t_2g to e_g systems, and
including systems in which the exchange coupling is predominantly
three-dimensional, one-dimensional or zero-dimensional. With the exception of
LaMnO3, we find orbital excitations in all compounds. We discuss the
competition between orbital fluctuations (for dominant exchange coupling) and
crystal-field splitting (for dominant coupling to the lattice). Comparison of
our experimental results with configuration-interaction cluster calculations in
general yield good agreement, demonstrating that the coupling to the lattice is
important for a quantitative description of the orbital excitations in these
compounds. However, detailed theoretical predictions for the contribution of
collective orbital modes to the optical conductivity (e.g., the line shape or
the polarization dependence) are required to decide on a possible contribution
of orbital fluctuations at low energies, in particular in case of the orbital
excitations at about 0.25 eV in RTiO3. Further calculations are called for
which take into account the exchange interactions between the orbitals and the
coupling to the lattice on an equal footing.Comment: published version, discussion of TiOCl extended to low T, improved
calculation of orbital excitation energies in TiOCl, figure 16 improved,
references updated, 33 pages, 20 figure
Redirected nuclear glutamate dehydrogenase supplies Tet3 with alpha-ketoglutarate in neurons
Tet3 is the main alpha -ketoglutarate (alpha KG)-dependent dioxygenase in neurons that converts 5-methyl-dC into 5-hydroxymethyl-dC and further on to 5-formyl- and 5-carboxy-dC. Neurons possess high levels of 5-hydroxymethyl-dC that further increase during neural activity to establish transcriptional plasticity required for learning and memory functions. How alpha KG, which is mainly generated in mitochondria as an intermediate of the tricarboxylic acid cycle, is made available in the nucleus has remained an unresolved question in the connection between metabolism and epigenetics. We show that in neurons the mitochondrial enzyme glutamate dehydrogenase, which converts glutamate into alpha KG in an NAD(+)-dependent manner, is redirected to the nucleus by the alpha KG-consumer protein Tet3, suggesting on-site production of alpha KG. Further, glutamate dehydrogenase has a stimulatory effect on Tet3 demethylation activity in neurons, and neuronal activation increases the levels of alpha KG. Overall, the glutamate dehydrogenase-Tet3 interaction might have a role in epigenetic changes during neural plasticity. alpha -ketoglutarate (alpha KG) is an intermediate in the tricarboxylic acid cycle that is required in the nucleus for genomic DNA demethylation by Tet3. Here, the authors show that the enzyme glutamate dehydrogenase, which converts glutamate to alpha KG, is redirected from the mitochondria to the nucleus.Proteomic
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