Politics ex cathedra: Religious authority and the Pope in modern international relations

Political scientists are increasingly interested in the impact of religious authority on modern politics. However, little attention has been paid to the conditions under which religious leaders are more likely to speak politically. Tackling this question, this article argues that religious authorities should issue political statements at the outbreak of international crises, when secular institutions are unwilling or incapable of taking clear political positions. I test this argument focusing on the Roman Vatican through a quantitative text analysis of the papal encyclicals from 1958 until today. Latent topic models indicate that political themes systematically emerge in the papal documents and that the timing of the more political encyclicals correlate with years in which international crises break out. The findings have implications for the understanding of the modern relations between state and church and the political mobilization of religion today

Quantum correlation dynamics in photosynthetic processes assisted by molecular vibrations

During the long course of evolution, nature has learnt how to exploit quantum effects. In fact, recent experiments reveal the existence of quantum processes whose coherence extends over unexpectedly long time and space ranges. In particular, photosynthetic processes in light-harvesting complexes display a typical oscillatory dynamics ascribed to quantum coherence. Here, we consider the simple model where a dimer made of two chromophores is strongly coupled with a quasi-resonant vibrational mode. We observe the occurrence of wide oscillations of genuine quantum correlations, between electronic excitations and the environment, represented by vibrational bosonic modes. Such a quantum dynamics has been unveiled through the calculation of the negativity of entanglement and the discord, indicators widely used in quantum information for quantifying the resources needed to realize quantum technologies. We also discuss the possibility of approximating additional weakly-coupled off-resonant vibrational modes, simulating the disturbances induced by the rest of the environment, by a single vibrational mode. Within this approximation, one can show that the off-resonant bath behaves like a classical source of noise

Fragment Approach to Constrained Density Functional Theory Calculations using Daubechies Wavelets

In a recent paper we presented a linear scaling Kohn-Sham density functional theory (DFT) code based on Daubechies wavelets, where a minimal set of localized support functions is optimized in situ and therefore adapted to the chemical properties of the molecular system. Thanks to the systematically controllable accuracy of the underlying basis set, this approach is able to provide an optimal contracted basis for a given system: accuracies for ground state energies and atomic forces are of the same quality as an uncontracted, cubic scaling approach. This basis set offers, by construction, a natural subset where the density matrix of the system can be projected. In this paper we demonstrate the flexibility of this minimal basis formalism in providing a basis set that can be reused as-is, i.e. without reoptimization, for charge-constrained DFT calculations within a fragment approach. Support functions, represented in the underlying wavelet grid, of the template fragments are roto-translated with high numerical precision to the required positions and used as projectors for the charge weight function. We demonstrate the interest of this approach to express highly precise and efficient calculations for preparing diabatic states and for the computational setup of systems in complex environments

Pollution responsibility allocation in supply networks: A game-theoretic approach and a case study

This study introduces a cooperative game theory approach aimed at addressing the problem of allocating pollution responsibility across partners collaborating in supply networks. The proposed framework includes three different allocation rules through which companies can share pollution responsibility across complex supply networks. A case study in the context of a supply network for the manufacturing of construction materials is illustrated for demonstrating the real-world applicability of the approach

Towards explainable face aging with Generative Adversarial Networks

Generative Adversarial Networks (GAN) are being increasingly used to perform face aging due to their capabilities of automatically generating highly-realistic synthetic images by using an adversarial model often based on Convolutional Neural Networks (CNN). However, GANs currently represent black box models since it is not known how the CNNs store and process the information learned from data. In this paper, we propose the \ufb01rst method that deals with explaining GANs, by introducing a novel qualitative and quantitative analysis of the inner structure of the model. Similarly to analyzing the common genes in two DNA sequences, we analyze the common \ufb01lters in two CNNs. We show that the GANs for face aging partially share their parameters with GANs trained for heterogeneous applications and that the aging transformation can be learned using general purpose image databases and a \ufb01ne-tuning step. Results on public databases con\ufb01rm the validity of our approach, also enabling future studies on similar models

New quantumness domains through generalized squeezed states

Current definitions of both squeezing operator and squeezed vacuum state are critically examined on the grounds of consistency with the underlying su(1,1) algebraic structure. Accordingly, the generalized coherent states for su(1,1) in its Schwinger two-photon realization are proposed as squeezed states. The physical implication of this assumption is that two additional degrees of freedom become available for the control of quantum optical systems. The resulting physical predictions are evaluated in terms of quadrature squeezing and photon statistics, while the application to a Mach–Zehnder interferometer is discussed to show the emergence of nonclassical regions, characterized by negative values of Mandel’s parameter, which cannot be anticipated by the current formulation, and then outline future possible use in quantum technologies

Experiment Investigating the Connection between Weak Values and Contextuality

Weak value measurements have recently given rise to a large interest for both the possibility of measurement amplification and the chance of further quantum mechanics foundations investigation. In particular, a question emerged about weak values being proof of the incompatibility between Quantum Mechanics and Non-Contextual Hidden Variables Theories (NCHVT). A test to provide a conclusive answer to this question was given in [M. Pusey, Phys. Rev. Lett. 113, 200401 (2014)], where a theorem was derived showing the NCHVT incompatibility with the observation of anomalous weak values under specific conditions. In this paper we realize this proposal, clearly pointing out the strict connection between weak values and the contextual nature of Quantum Mechanics.Comment: 5 pages, 4 figure

Measuring the photon distribution by ON/OFF photodectors

Reconstruction of photon statistics of optical states provide fundamental information on the nature of any optical field and find various relevant applications. Nevertheless, no detector that can reliably discriminate the number of incident photons is available. On the other hand the alternative of reconstructing density matrix by quantum tomography leads to various technical difficulties that are particular severe in the pulsed regime (where mode matching between signal an local oscillator is very challenging). Even if on/off detectors, as usual avalanche PhotoDiodes operating in Geiger mode, seem useless as photocounters, recently it was shown how reconstruction of photon statistics is possible by considering a variable quantum efficiency. Here we present experimental reconstructions of photon number distributions of both continuous-wave and pulsed light beams in a scheme based on on/off avalanche photodetection assisted by maximum-likelihood estimation. Reconstructions of the distribution for both semiclassical and quantum states of light (as single photon, coherent, pseudothermal and multithermal states) are reported for single-mode as well as for multimode beams. The stability and good accuracy obtained in the reconstruction of these states clearly demonstrate the interesting potentialities of this simple technique.Comment: 6 pages, 7 figures, to appear on Laser Physic

Direct experimental observation of nonclassicality in ensembles of single photon emitters

In this work we experimentally demonstrate for the first time a recently proposed criterion adressed to detect nonclassical behavior in the fluorescence emission of ensembles of single-photon emitters. In particular, we apply the method to study clusters of NV centres in diamond observed via single-photon-sensitive confocal microscopy. Theoretical considerations on the behavior of the parameter at any arbitrary order in presence of poissonian noise are presented and, finally, the opportunity of detecting manifold coincidences is discussed