480 research outputs found

    PAMP SA: Production Artistiques Métaux Précieux SA: Corrosion of Precious Metals

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    Immobilization of catalase via adsorption into natural and modified active carbon obtained from walnut in various methods

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    In the present work, the immobilization of catalase into natural active carbon and active carbon modified by hydrochloric acid was carried out. In the experimental section, the effects of pH, ionic strength andreaction temperature were chosen as parameters, with experiments performed in batch system. For the optimization of immobilization procedure, values of kinetic parameters were evaluated. It was observedthat storage and operational stabilities of the enzyme increased with immobilization. The results obtained from experiments showed that active carbon is a valuable support for the adsorption of enzymes

    Chemical pre-processing of cluster galaxies over the past 10 billion years in the IllustrisTNG simulations

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    We use the IllustrisTNG simulations to investigate the evolution of the mass-metallicity relation (MZR) for star-forming cluster galaxies as a function of the formation history of their cluster host. The simulations predict an enhancement in the gas-phase metallicities of star-forming cluster galaxies (10^9< M_star<10^10 M_sun) at z<1.0 in comparisons to field galaxies. This is qualitatively consistent with observations. We find that the metallicity enhancement of cluster galaxies appears prior to their infall into the central cluster potential, indicating for the first time a systematic "chemical pre-processing" signature for {\it infalling} cluster galaxies. Namely, galaxies which will fall into a cluster by z=0 show a ~0.05 dex enhancement in the MZR compared to field galaxies at z<0.5. Based on the inflow rate of gas into cluster galaxies and its metallicity, we identify that the accretion of pre-enriched gas is the key driver of the chemical evolution of such galaxies, particularly in the stellar mass range (10^9< M_star<10^10 M_sun). We see signatures of an environmental dependence of the ambient/inflowing gas metallicity which extends well outside the nominal virial radius of clusters. Our results motivate future observations looking for pre-enrichment signatures in dense environments.Comment: 5 pages, 4 figures, accepted for publication in MNRAS Letter

    Free vibrations of spatial frame structures: Analytical modelling and solution

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    This study analytically handles the three-dimensional free vibrations of spatial frames using the initial values method, considering the axial and shear deformations alongside rotary inertias, namely, torsional, in-plane bending and out-of-plane bending. To handle the spatial geometry, the direction cosine matrices are used. Validation is performed with three cases in total, one case available in the literature alongside two numerical examples that are solved analytically and compared to the finite element models. Excellent agreements are found between the analytical results and the results in the literature, as well as those obtained from the finite element models

    Damped lyman α absorbers as a probe of stellar feedback

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    We examine the abundance, clustering and metallicity of Damped Lyman-alpha Absorbers (DLAs) in a suite of hydrodynamic cosmological simulations using the moving mesh code AREPO. We incorporate models of supernova and AGN feedback, as well as molecular hydrogen formation. We compare our simulations to the column density distribution function at z=3z=3, the total DLA abundance at z=2−4z=2-4, the measured DLA bias at z=2.3z=2.3 and the DLA metallicity distribution at z=2−4z=2-4. Our preferred models produce populations of DLAs in good agreement with most of these observations. The exception is the DLA abundance at z<3z < 3, which we show requires stronger feedback in 1011−12 h−1M⊙10^{11-12} \, h^{-1} M_\odot mass halos. While the DLA population probes a wide range of halo masses, we find the cross-section is dominated by halos of mass 1010−1011 h−1M⊙10^{10} - 10^{11} \, h^{-1} M_\odot and virial velocities 50−100  km/s50 - 100 \;\mathrm{km/s}. The simulated DLA population has a linear theory bias of 1.71.7, whereas the observations require 2.17±0.22.17 \pm 0.2. We show that non-linear growth increases the bias in our simulations to 2.32.3 at k=1  Mpc/hk=1\; \mathrm{Mpc/}h, the smallest scale observed. The scale-dependence of the bias is, however, very different in the simulations compared against the observations. We show that, of the observations we consider, the DLA abundance and column density function provide the strongest constraints on the feedback model

    Mergers and Mass Accretion Rates in Galaxy Assembly: The Millennium Simulation Compared to Observations of z~2 Galaxies

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    Recent observations of UV-/optically selected, massive star forming galaxies at z~2 indicate that the baryonic mass assembly and star formation history is dominated by continuous rapid accretion of gas and internal secular evolution, rather than by major mergers. We use the Millennium Simulation to build new halo merger trees, and extract halo merger fractions and mass accretion rates. We find that even for halos not undergoing major mergers the mass accretion rates are plausibly sufficient to account for the high star formation rates observed in z~2 disks. On the other hand, the fraction of major mergers in the Millennium Simulation is sufficient to account for the number counts of submillimeter galaxies (SMGs), in support of observational evidence that these are major mergers. When following the fate of these two populations in the Millennium Simulation to z=0, we find that subsequent mergers are not frequent enough to convert all z~2 turbulent disks into elliptical galaxies at z=0. Similarly, mergers cannot transform the compact SMGs/red sequence galaxies at z~2 into observed massive cluster ellipticals at z=0. We argue therefore, that secular and internal evolution must play an important role in the evolution of a significant fraction of z~2 UV-/optically and submillimeter selected galaxy populations.Comment: 5 pages, 4 figures, Accepted for publication in Ap

    Constraint on the Assembly and Dynamics of Galaxies. II. Properties of Kiloparsec-Scale Clumps in Rest-Frame Optical Emission of z ~ 2 Star-Forming Galaxies

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    We study the properties of luminous stellar "clumps" identified in deep, high-resolution Hubble Space Telescope NIC2/F160W imaging at 1.6 μm of six z ~ 2 star-forming galaxies with existing near-infrared integral field spectroscopy from SINFONI at the Very Large Telescope. Individual clumps contribute ~0.5%-15% of the galaxy-integrated rest-frame ≈5000 Å emission, with median of ≈2%; the total contribution of clump light ranges from 10% to 25%. The median intrinsic clump size and stellar mass are ~1 kpc and ~10^9 M_☉, in the ranges for clumps identified in rest-UV or line emission in other studies. The clump sizes and masses in the subset of disks are broadly consistent with expectations for clump formation through gravitational instabilities in gas-rich, turbulent disks given the host galaxies' global properties. By combining the NIC2 data with Advanced Camera for Surveys (ACS)/F814W imaging available for one source, and adaptive-optics-assisted SINFONI Hα data for another, we infer modest color, M/L, and stellar age variations within each galaxy. In these two objects, sets of clumps identified at different wavelengths do not fully overlap; NIC2-identified clumps tend to be redder/older than ACS- or Hα-identified clumps without rest-frame optical counterparts. There is evidence for a systematic trend of older ages at smaller galactocentric radii among the clumps, consistent with scenarios where inward migration of clumps transports material toward the central regions. From constraints on a bulge-like component at radii ≾1-3 kpc, none of the five disks in our sample appears to contain a compact massive stellar core, and we do not discern a trend of bulge stellar mass fraction with stellar age of the galaxy. Further observations are necessary to probe the buildup of stellar bulges and the role of clumps in this process

    Hydrogen reionization in the illustris universe

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    Hydrodynamical simulations of galaxy formation such as the Illustris simulations have progressed to a state where they approximately reproduce the observed stellar mass function from high to low redshift. This in principle allows self-consistent models of reionization that exploit the accurate representation of the diffuse gas distribution together with the realistic growth of galaxies provided by these simulations, within a representative cosmological volume. In this work, we apply and compare two radiative transfer algorithms implemented in a GPU-accelerated code to the 106.5 Mpc106.5\,{\rm Mpc} wide volume of Illustris in postprocessing in order to investigate the reionization transition predicted by this model. We find that the first generation of galaxies formed by Illustris is just about able to reionize the universe by redshift z∼7z\sim 7, provided quite optimistic assumptions about the escape fraction and the resolution limitations are made. Our most optimistic model finds an optical depth of τ≃0.065\tau\simeq 0.065, which is in very good agreement with recent Planck 2015 determinations. Furthermore, we show that moment-based approaches for radiative transfer with the M1 closure give broadly consistent results with our angular-resolved radiative transfer scheme. In our favoured fiducial model, 20\% of the hydrogen is reionized by redshift z=9.20z=9.20, and this rapidly climbs to 80\% by redshift z=6.92z=6.92. It then takes until z=6.24z=6.24 before 99\% of the hydrogen is ionized. On average, reionization proceeds `inside-out' in our models, with a size distribution of reionized bubbles that progressively features regions of ever larger size while the abundance of small bubbles stays fairly constant
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