Characterization of a calcium phospho-silicated apatite with iron oxide inclusions

An iron oxide containing calcium phosphate–silicate hydroxyapatite was synthesized by calcination at 900 °C of a sample obtained by precipitation in basic aqueous solution of Ca, P, Si, Fe and Mg containing acidic solution made from dissolution of natural minerals. XRD and FTIR were used for crystallographic characterization of the main apatitic phase. Its composition was determined using ICP-AES. EDX coupled with SEM and TEM evidenced the heterogeneity of this compound and the existence of iron–magnesium oxide. Magnetic analyses highlighted that this phase was non-stoichiometric magnesioferrite (Mg1.2Fe1.8O3.9) spherical nanoparticles. Those analyses also put into evidence the role of calcination in synthesis. Carbonates detected by FTIR and estimated by SEM-EDX in non-calcinated sample were removed from apatitic structure, and crystallization of apatite was enhanced during heating. Moreover, there was phase segregation that led to magnesioferrite formation

Impact demagnetization of the Martian crust: Current knowledge and future directions

The paleomagnetism of the Martian crust has important implications for the history of the dynamo, the intensity of the ancient magnetic field, and the composition of the crust. Modification of crustal magnetization by impact cratering is evident from the observed lack of a measurable crustal field (at spacecraft altitude) within the youngest large impact basins (e.g., Hellas, Argyre and Isidis). It is hoped that comparisons of the magnetic intensity over impact structures, forward modeling of subsurface magnetization, and experimental results of pressure-induced demagnetization of rocks and minerals will provide constraints on the primary magnetic mineralogy in the Martian crust. Such an effort requires: (i) accurate knowledge of the spatial distribution of the shock pressures around impact basins, (ii) crustal magnetic intensity maps of adequate resolution over impact structures, and (iii) determination of demagnetization properties for individual rocks and minerals under compression. In this work, we evaluate the current understanding of these three conditions and compile the available experimental pressure demagnetization data on samples bearing (titano-) magnetite, (titano-) hematite, and pyrrhotite. We find that all samples demagnetize substantially at pressures of a few GPa and that the available data support significant modification of the crustal magnetic field from both large and small impact events. However, the amount of demagnetization with applied pressure does not vary significantly among the possible carrier phases. Therefore, the presence of individual mineral phases on Mars cannot be determined from azimuthally averaged demagnetization profiles over impact basins at present. The identification of magnetic mineralogy on Mars will require more data on pressure demagnetization of thermoremanent magnetization and forward modeling of the crustal field subject to a range of plausible initial field and demagnetization patterns.United States. National Aeronautics and Space Administration (NNG04GD17G)United States. National Aeronautics and Space Administration (NNX07AQ69G)United States. National Aeronautics and Space Administration (NNX06AD14G

Magnetic field microscopy of rock samples using a giant magnetoresistance–based scanning magnetometer

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95412/1/ggge1634.pd

Constraining the Evolutionary History of the Moon and the Inner Solar System: A Case for New Returned Lunar Samples

The Moon is the only planetary body other than the Earth for which samples have been collected in situ by humans and robotic missions and returned to Earth. Scientific investigations of the first lunar samples returned by the Apollo 11 astronauts 50 years ago transformed the way we think most planetary bodies form and evolve. Identification of anorthositic clasts in Apollo 11 samples led to the formulation of the magma ocean concept, and by extension the idea that the Moon experienced large-scale melting and differentiation. This concept of magma oceans would soon be applied to other terrestrial planets and large asteroidal bodies. Dating of basaltic fragments returned from the Moon also showed that a relatively small planetary body could sustain volcanic activity for more than a billion years after its formation. Finally, studies of the lunar regolith showed that in addition to containing a treasure trove of the Moon’s history, it also provided us with a rich archive of the past 4.5 billion years of evolution of the inner Solar System. Further investigations of samples returned from the Moon over the past five decades led to many additional discoveries, but also raised new and fundamental questions that are difficult to address with currently available samples, such as those related to the age of the Moon, duration of lunar volcanism, the lunar paleomagnetic field and its intensity, and the record on the Moon of the bombardment history during the first billion years of evolution of the Solar System. In this contribution, we review the information we currently have on some of the key science questions related to the Moon and discuss how future sample-return missions could help address important knowledge gaps

The identification of airbursts in the past: insights from the BIT-58 layer

Airbursts are estimated to be the most frequent type of destructive impact events. Yet, confirmation of these events is elusive, resulting in a major gap in the impact record of Earth. The recent discovery of igneous chondritic spherules produced during a new type of touchdown airburst 430 thousand years (kyr) ago over Antarctica, in which a projectile vapor jet interacts with the Antarctic ice sheet, provided the first trace of such an impact in the geological record. In terms of petrology and geochemistry, particles constituting the BIT-58 dust horizon, which was found in surface ice at near Allan Hills in Antarctica, are almost identical to those produced 430 kyr ago. We demonstrate here that BIT-58 particles were indeed formed during a touchdown event between 2.3 and 2.7 million years (Myr) ago. This represents the oldest record of an airburst on Earth identified to date. Slight geochemical differences with 430 kyr old airburst spherules provide additional constraints on spherule condensation in large airburst plumes. Finding confirmation of airbursts in the paleorecord can provide insight into the frequency of the most hazardous impacts and, thus, has implications for planetary defence