Response of Soybean Grown on a Claypan Soil in Southeastern Kansas to the Residual of Different Plant Nutrient Sources and Tillage

The residual from previous high rate turkey litter applications, which were based on N requirements of the previous grain sorghum crop, increased soybean yield above that obtained from the residual of P-based turkey litter applications (low rate), commercial fertilizer, or the control. Even though early soybean growth was not significantly affected by residual treatments, the greatest dry matter production at the R6 growth stage was where the N-based litter had been applied and incorporated

Surface Runoff Characteristics from Claypan Soil in Southeastern Kansas Receiving Different Plant Nutrient Sources and Tillage

Preliminary results show that two-year average total nitrogen (N) runoff losses and ortho-phosphorus (P) and total P runoff losses in the second year were greater with N-based turkey litter/no-till applications than P-based turkey litter or fertilizer-only applications. Incorporation of turkey litter applied based on N requirements resulted in N and P losses that did not differ from losses from P-based or fertilizer-only treatments. Chemical and statistical analyses of third-year samples will allow for final results and interpretation

Response of Soybean Grown on a Claypan Soil in Southeastern Kansas to the Residual of Different Plant Nutrient Sources and Tillage

The residual from previous high rate turkey litter applications, which were based on N requirements of the previous grain sorghum crop, increased soybean yield above that obtained from the residual of P-based turkey litter applications (low rate), commercial fertilizer, or the control. Even though early soybean growth was not significantly affected by residual treatments, the greatest dry matter production at the R6 growth stage was where the N-based litter had been applied and incorporated

Response of Soybean Grown on a Claypan Soil in Southeastern Kansas to the Residual of Different Plant Nutrient Sources and Tillage

Soybean yields measured from 2014 through 2016 were more than 50% greater from the residual from N-based turkey litter applications during 2011 through 2013 than in the control where no nitrogen (N) or phosphorus (P) was applied. However, residual from P-based turkey litter applications or fertilizer-only did not result in soybean yield different from the no N-P control. This residual effect on yield was largely due to increased pods per plant

Formation and Stability of Substituted Pyromorphite: A Molecular Modeling Study

Soils contaminated with lead pose significant risk to human as well as terrestrial and aquatic ecosystems. Theoretical phase relationships and field observations suggest that the interaction of lead and phosphorus to form pyromorphites Pb5(PO4 )3 X (X= OH-, Br-, Cl-, or F-) is an important buffer mechanism controlling the migration and fixation of lead in the environment. We report a molecular modeling approach to investigate the formation and stability of the substituted pyromorphites, which involved evaluating the lattice energy of the minerals using ab initio quantum mechanics. The lattice energy values are used in a Born-Haber thermodynamic cycle to calculate the heat of formation of the minerals. The Gibbs free energy of the substituted pyromorphites is then calculated from the change in entropy and heat of formation. The systems investigated in this study include partial and total substitution of Pb2+ by Cd2+ and Zn2+ cations in chloropyromorphite (Pb5(PO4 )3Cl ). Results indicate the unstable nature of the substituted Pb pyromorphite. The stability of the substituted minerals is found in the order Pb-pyromorphite \u3e Cd-pyromorphite \u3e Zn-pyromorphite

Response of Soybean Grown on a Claypan Soil in Southeastern Kansas to the Residual of Different Plant Nutrient Sources and Tillage

Increased fertilizer prices in recent years, especially noticeable when the cost of phosphorus spiked in 2008, have led U.S. producers to consider other alternatives, including manure sources. The use of poultry litter as an alternative to fertilizer is of particular interest in southeastern Kansas because large amounts of poultry litter are imported from nearby confined animal feeding operations in Arkansas, Oklahoma, and Missouri. Annual application of turkey litter can affect the current crop, but information is lacking concerning any residual effects from several continuous years of poultry litter applications on a following crop. This is especially true for tilled soil compared with no-till because production of most annual cereal crops on the claypan soils of the region is often negatively affected by no-till planting. The objective of this study was to determine if the residual from fertilizer and poultry litter applications under tilled or no-till systems affects soybean yield and growth

Micro-X-Ray Fluorescence, Micro-X-Ray Absorption Spectroscopy, and Micro-X-Ray Diffraction Investigation of Lead Speciation after the Addition of Different Phosphorus Amendments to a Smelter-Contaminated Soil

Citation: Baker, Lucas R., Gary M. Pierzynski, Ganga M. Hettiarachchi, Kirk G. Scheckel, and Matthew Newville. “Micro-X-Ray Fluorescence, Micro-X-Ray Absorption Spectroscopy, and Micro-X-Ray Diffraction Investigation of Lead Speciation after the Addition of Different Phosphorus Amendments to a Smelter-Contaminated Soil.” Journal of Environmental Quality 43, no. 2 (2014): 488–97. https://doi.org/10.2134/jeq2013.07.0281.The stabilization of Pb on additions of P to contaminated soils and mine spoil materials has been well documented. It is clear from the literature that different P sources result in different efficacies of Pb stabilization in the same contaminated material. We hypothesized that the differences in the efficacy of Pb stabilization in contaminated soils on fluid or granular P amendment addition is due to different P reaction processes in and around fertilizer granules and fluid droplets. We used a combination of several synchrotron-based techniques (i.e., spatially resolved micro-X-ray fluorescence, micro-X-ray absorption near-edge structure spectroscopy, and micro-X-ray diffraction) to speciate Pb at two incubation times in a smelter-contaminated soil on addition of several fluid and granular P amendments. The results indicated that the Pb phosphate mineral plumbogummite was an intermediate phase of pyromorphite formation. Additionally, all fluid and granular P sources were able to induce Pb phosphate formation, but fluid phosphoric acid (PA) was the most effective with time and distance from the treatment. Granular phosphate rock and triple super phosphate (TSP) amendments reacted to generate Pb phosphate minerals, with TSP being more effective at greater distances from the point of application. As a result, PA and TSP were the most effective P amendments at inducing Pb phosphate formation, but caution needs to be exercised when adding large amounts of soluble P to the environment

Nano-oxides immobilize cadmium, lead, and zinc in mine spoils and contaminated soils facilitating plant growth

Nanoparticles with high reactivity can be applied as amendments to remediate soil metal contaminations by immobilizing toxic elements. Nano-oxides of Fe have been studied but Al and Ti nano-oxides have not been tested for their remediation capacity of toxic metals. The potential of synthesized iron (Fe-O), aluminum (Al-O), and titanium (Ti-O) nano-oxides for stabilizing Cd, Pb, and Zn in mine spoil (Chat) and contaminated soil was compared using adsorption studies and a greenhouse experiment. Chat and soil were amended with nanooxides at two rates (25 and 50 g·kg−1) and a pot experiment was conducted with sorghum (Sorghum bicolor L. Moench). Leachates were collected twice per week from plant emergence to harvest at maturity and metals were compared against an unamended control. Chat was contaminated with Cd, Pb, and Zn at 84, 1583, and 6154 mg·kg−1, and soil at 15, 1260, and 3082 mg·kg−1, respectively. Adsorption conformed to the Langmuir linear isotherm and adsorption maxima of metals were in the order of Al-O > Ti-O ≥ Fe-O. Nano-oxides reduced Cd concentration by 28% (Fe-O) to 87% (Ti-O) and Zn concentration by 14% (Fe-O) to 85% (Al-O) in plant tissues compared with unamended Chat. Nano-oxides significantly reduced Cd, Pb, and Zn in leachates and available Cd and Zn in Chat/soil relative to the respective unamended controls. Nano-oxides can be used to remediate heavy metal contaminated Chat and soil and facilitate plant growth under proper nutrient supplements. Nano-oxides of Al-O and Ti-O remediated metals more effectively than Fe-O."We thank the Department of Agronomy at Kansas State University for providing the facilities and materials to conduct this research. Contribution No. 21-074-J from Kansas Agricultural Experiment Station. The first author received the Fulbright Visiting Scholar Fellowship and wishes to acknowledge the CIES, USA Fulbright Program for funding the visit to KSU."https://cdnsciencepub.com/doi/10.1139/cjss-2020-012

Calibration of the APEX Model to Simulate Management Practice Effects on Runoff, Sediment, and Phosphorus Loss

Process-based computer models have been proposed as a tool to generate data for Phosphorus (P) Index assessment and development. Although models are commonly used to simulate P loss from agriculture using managements that are different from the calibration data, this use of models has not been fully tested. The objective of this study is to determine if the Agricultural Policy Environmental eXtender (APEX) model can accurately simulate runoff, sediment, total P, and dissolved P loss from 0.4 to 1.5 ha of agricultural fields with managements that are different from the calibration data. The APEX model was calibrated with field-scale data from eight different managements at two locations (management-specific models). The calibrated models were then validated, either with the same management used for calibration or with different managements. Location models were also developed by calibrating APEX with data from all managements. The management-specific models resulted in satisfactory performance when used to simulate runoff, total P, and dissolved P within their respective systems, with r2 \u3e 0.50, Nash– Sutcliffe efficiency \u3e 0.30, and percent bias within ±35% for runoff and ±70% for total and dissolved P. When applied outside the calibration management, the management-specific models only met the minimum performance criteria in one-third of the tests. The location models had better model performance when applied across all managements compared with management-specific models. Our results suggest that models only be applied within the managements used for calibration and that data be included from multiple management systems for calibration when using models to assess management effects on P loss or evaluate P Indices

Agricultural Phosphorus Management and Water Quality Protection in the Midwest

For nutrient management planners -- to understand the risk of phosphorus in surface waters and to manage this risk. Targeted for Iowa, Kansas, Missouri, and Nebraska.https://lib.dr.iastate.edu/extension_ag_pubs/1151/thumbnail.jp