Agenda Control in the Bundestag, 1980-2002

We find strong evidence of monopoly legislative agenda control by government parties in the Bundestag. First, the government parties have near-zero roll rates, while the opposition parties are often rolled over half the time. Second, only opposition parties’ (and not government parties’) roll rates increase with the distances of each party from the floor median. Third, almost all policy moves are towards the government coalition (the only exceptions occur during periods of divided government). Fourth, roll rates for government parties sky- rocket when they fall into the opposition and roll rates for opposition parties plummet when they enter government, while policy movements go from being nearly 100 per cent rightward when there is a rightist government to 100 per cent leftward under a leftist government

Ultrasound-induced emulsification of subcritical carbon dioxide/water with and without surfactant as a strategy for enhanced mass transport

Pulsed ultrasound was used to disperse a biphasic mixture of CO2/H2O in a 1 dm3 high-pressure reactor at 30 °C/80 bar. A view cell positioned in-line with the sonic vessel allowed observation of a turbid emulsion which lasted approximately 30 min after ceasing sonication. Within the ultrasound reactor, simultaneous CO2-continuous and H2O-continuous environments were identified. The hydrolysis of benzoyl chloride was employed to show that at similar power intensities, comparable initial rates (1.6 ± 0.3 × 10–3 s–1 at 95 W cm–2) were obtained with those reported for a 87 cm3 reactor (1.8 ± 0.2 × 10–3 s–1 at 105 W cm–2), demonstrating the conservation of the physical effects of ultrasound in high-pressure systems (emulsification induced by the action of acoustic forces near an interface). A comparison of benzoyl chloride hydrolysis rates and benzaldehyde mass transport relative to the non-sonicated, ‘silent’ cases confirmed that the application of ultrasound achieved reaction rates which were over 200 times faster, by reducing the mass transport resistance between CO2 and H2O. The versatility of the system was further demonstrated by ultrasound-induced hydrolysis in the presence of the polysorbate surfactant, Tween, which formed a more uniform CO2/H2O emulsion that significantly increased benzoyl chloride hydrolysis rates. Finally, pulse rate was employed as a means of slowing down the rate of hydrolysis, further illustrating how ultrasound can be used as a valuable tool for controlling reactions in CO2/H2O solvent mixtures

Body composition of elite Olympic combat sport athletes

Physique traits of a range of elite athletes have been identified; however, few detailed investigations of Olympic combat sports (judo, wrestling, taekwondo and boxing) exist. This is surprising given the importance of body composition in weight category sports. We sought to develop a descriptive database of Olympic combat sport athletes, compare variables relative to weight division and examine differences within and between sports. Additionally, we investigated the appropriateness of athletes’ self-selected weight classes compared to an internationally recognised classification system (the NCAA minimum wrestling weight scheme used to identify minimum ‘safe’ weight). Olympic combat sport athletes (56♂, 38♀) had body mass (BM), stretch stature and dual-energy X-ray absorptiometry derived body composition assessed within 7–21 days of competition. Most athletes were heavier than their weight division. Sport had an effect (p  0.6) with; fat free mass, fat mass and body fat percentage, however, was not predictive of total mass/weight division. The Olympic combat sports differ in competitive format and physiological requirements, which is partly reflected in athletes’ physique traits. We provide reference ranges for lean and fat mass across a range of BM. Lighter athletes likely must utilise acute weight loss in order to make weight, whereas heavier athletes can potentially reduce fat mass

Temperature Fluctuations and Abundances in HII Galaxies

There is evidence for temperature fluctuations in Planetary Nebulae and in Galactic HII regions. If such fluctuations occur in the low-metallicity, extragalactic HII regions used to probe the primordial helium abundance, the derived 4He mass fraction, Y_P, could be systematically different from the true primordial value. For cooler, mainly high-metallicity HII regions the derived helium abundance may be nearly unchanged but the oxygen abundance could have been seriously underestimated. For hotter, mainly low-metallicity HII regions the oxygen abundance is likely accurate but the helium abundance could be underestimated. The net effect is to tilt the Y vs. Z relation, making it flatter and resulting in a higher inferred Y_P. Although this effect could be large, there are no data which allow us to estimate the size of the temperature fluctuations for the extragalactic HII regions. Therefore, we have explored this effect via Monte Carlos in which the abundances derived from a fiducial data set are modified by \Delta-T chosen from a distribution with 0 < \Delta-T < \Delta-T_max where \Delta-T_max is varied from 500K to 4000K. It is interesting that although this effect shifts the locations of the HII regions in Y vs. O/H plane, it does not introduce any significant additional dispersion.Comment: 11 pages, 9 postscript figures; submitted to the Ap

Quantifying site-level usage and certainty of absence for an invasive species through occupancy analysis of camera-trap data

Copyright Springer International Publishing This document is a U.S. government work and is not subject to copyright in the United States. https://doi.org/10.1007/s10530-017-1579-

Reply to Simon and Reed: Independent and Converging Results Rule Out Historic Disturbance and Confirm Age Constraints for Barrier Canyon Rock Art

We welcome this further discussion of our results on the age of the Great Gallery rock art in the Canyonlands of Utah. The comment by Simon and Reed (1) focuses on just one of the three components of our study (2), which is presented in greater technical detail in ref. 3 and is surely our best-constrained and least-surprising result: the dating of a rock-fall that removed some of the art and thus provides a minimum age. Simon and Reed (1) point out that the Great Gallery panel is not pristine and relate the sordid human history of visitation and possible disturbance to the site. Indeed, being aware of this during our research, one of our initial hypotheses was that the rock fall may be historic. Despite the possibility of recent disturbance to some of the talus boulders, our results document that the rock fall occurred ∼900 y ago, and for the boulder we sampled a scenario of historic disturbance and exposure such as postulated by Simon and Reed (1) can be ruled out

Age of Barrier Canyon-style rock art constrained by cross-cutting relations and luminescence dating techniques

Rock art compels interest from both researchers and a broader public, inspiring many hypotheses about its cultural origin and meaning, but it is notoriously difficult to date numerically. Barrier Canyon-style (BCS) pictographs of the Colorado Plateau are among the most debated examples; hypotheses about its age span the entire Holocene epoch and previous attempts at direct radiocarbon dating have failed. We provide multiple age constraints through the use of cross-cutting relations and new and broadly applicable approaches in optically stimulated luminescence dating at the Great Gallery panel, the type section of BCS art in Canyonlands National Park, southeastern Utah. Alluvial chronostratigraphy constrains the burial and exhumation of the alcove containing the panel, and limits are also set by our related research dating both a rockfall that removed some figures and the rock’s exposure duration before that time. Results provide a maximum possible age, a minimum age, and an exposure time window for the creation of the Great Gallery panel, respectively. The only prior hypothesis not disproven is a late Archaic origin for BCS rock art, although our age result of A.D. ∼1–1100 coincides better with the transition to and rise of the subsequent Fremont culture. This chronology is for the type locality only, and variability in the age of other sites is likely. Nevertheless, results suggest that BCS rock art represents an artistic tradition that spanned cultures and the transition from foraging to farming in the region. Archaeology is focused upon material records, contextualized in time. Rock art is a record with the potential to provide unique insight into the dynamics and evolution of culture, but it generally lacks stratigraphic or chronologic context. Interpretation of the origin and meaning of rock art is indirect at best, or simply speculative. In the case of some pictographs, pigments may include or have enough accessory carbon for accelerator mass spectrometry (AMS) radiocarbon dating (1⇓⇓–4). In other special situations, such as caves, minimum age constraints have been obtained by various techniques of dating material that overlies or entombs rock art (5⇓–7). However, most rock art remains undatable and researchers rely upon stylistic comparison and indirect associations with artifacts at nearby sites (8, 9). The case in point for this study is arguably the most compelling and debated rock art in the United States—the Barrier Canyon style (BCS) of the Colorado Plateau. Previous attempts to derive an absolute chronology have failed and its age remains unknown, with widely ranging hypotheses that have remained untested until now. The continued development of dating techniques offers new possibilities for hypothesis testing. The optically stimulated luminescence (OSL) signals from mineral grains make it possible to date the deposition of most sediment that is exposed to a few seconds of full sunlight before burial, and its use in the earth and cultural sciences has greatly increased (10, 11). Among the latest applications of OSL are techniques dating the outer surfaces of rock clasts that have become shielded from light, including those with archaeological context (12⇓⇓–15). Recent work has furthermore used the “bleaching” profile of decreasing luminescence signal toward the surface of rock to estimate exposure time to sunlight (16, 17). Using these dating tools, we can constrain the age of rock art and gain new insight into past cultures and landscapes. Here, we synthesize results from three approaches to dating the type section of BCS art, the Great Gallery in Canyonlands National Park of southeastern Utah. Through dating the full alluvial stratigraphy and a rockfall event that both have incontrovertible cross-cutting relations with the rock art, and then by determining the exposure duration of a painted rock surface, we greatly narrow the window of time when the rock art was created. These approaches do not require direct sampling of rock art and have strong potential for application to other archaeological and surface processes research. Although our results are only for the type section of BCS art, and chronological variability should be expected for the style across the region, they suggest that BCS art coincides with the transition to agriculture in the northern Colorado Plateau and may not have been limited to a specific archaeological culture

Ultrasound-induced CO₂ /H₂O emulsions as a medium for clean product formation and separation : the Barbier reaction as a synthetic example

: Subcritical CO2/H2O (30 °C/80 bar) was employed as a renewable solvent mixture in a 1 dm3 ultrasound reactor. As a representative synthetic transformation, the metal-mediated Barbier allylation was used to demonstrate the facility of formation and separation of the homoallylic alcohol product. The chemoselectivity over the competing aldehyde reduction could be improved by deploying the biocompatible nonionic surfactant Tween 80, a saturated salt aqueous phase, or by carrying out the reaction at 60 °C/120 bar. All of these modifications led to an apparent rate increase in the desired allylation. A range of substituted benzaldehydes afforded the corresponding homoallylic alcohols in moderate to high yields. The presence of water constituted a necessary condition for efficient product formation, while CO2 provided an appropriate phase for clean product separation by exploiting a favorable homoallylic alcohol enrichment. In this way, 0.025 mol of homoallylic alcohol product could be isolated from the CO2 phase in 1 h, avoiding further extraction stages that would typically require organic solvents

First Reported Case of Cryptococcus gattii in the Southeastern USA: Implications for Travel-Associated Acquisition of an Emerging Pathogen

In 2007, the first confirmed case of Cryptococcus gattii was reported in the state of North Carolina, USA. An otherwise healthy HIV negative male patient presented with a large upper thigh cryptococcoma in February, which was surgically removed and the patient was started on long-term high-dose fluconazole treatment. In May of 2007, the patient presented to the Duke University hospital emergency room with seizures. Magnetic resonance imaging revealed two large CNS lesions found to be cryptococcomas based on brain biopsy. Prior chest CT imaging had revealed small lung nodules indicating that C. gattii spores or desiccated yeast were likely inhaled into the lungs and dissemination occurred to both the leg and CNS. The patient's travel history included a visit throughout the San Francisco, CA region in September through October of 2006, consistent with acquisition during this time period. Cultures from both the leg and brain biopsies were subjected to analysis. Based on phenotypic and molecular methods, both isolates were C. gattii, VGI molecular type, and distinct from the Vancouver Island outbreak isolates. Based on multilocus sequence typing of coding and noncoding regions and virulence in a heterologous host model, the leg and brain isolates are identical, but the two differed in mating fertility. Two clinical isolates, one from a transplant recipient in San Francisco and the other from Australia, were identical to the North Carolina clinical isolate at all markers tested. Closely related isolates that differ at only one or a few noncoding markers are present in the Australian environment. Taken together, these findings support a model in which C. gattii VGI was transferred from Australia to California, possibly though an association with its common host plant E. camaldulensis, and the patient was exposed in San Francisco and returned to present with disease in North Carolina