Non-linear response of single-molecule magnets: field-tuned quantum-to-classical crossovers

Quantum nanomagnets can show a field dependence of the relaxation time very different from their classical counterparts, due to resonant tunneling via excited states (near the anisotropy barrier top). The relaxation time then shows minima at the resonant fields H_{n}=n D at which the levels at both sides of the barrier become degenerate (D is the anisotropy constant). We showed that in Mn12, near zero field, this yields a contribution to the nonlinear susceptibility that makes it qualitatively different from the classical curves [Phys. Rev. B 72, 224433 (2005)]. Here we extend the experimental study to finite dc fields showing how the bias can trigger the system to display those quantum nonlinear responses, near the resonant fields, while recovering an classical-like behaviour for fields between them. The analysis of the experiments is done with heuristic expressions derived from simple balance equations and calculations with a Pauli-type quantum master equation.Comment: 4 pages, 3 figures. Submitted to Phys. Rev. B, brief report

Temperature dependent magnetization dynamics of magnetic nanoparticles

Recent experimental and theoretical studies show that the switching behavior of magnetic nanoparticles can be well controlled by external time-dependent magnetic fields. In this work, we inspect theoretically the influence of the temperature and the magnetic anisotropy on the spin-dynamics and the switching properties of single domain magnetic nanoparticles (Stoner-particles). Our theoretical tools are the Landau-Lifshitz-Gilbert equation extended as to deal with finite temperatures within a Langevine framework. Physical quantities of interest are the minimum field amplitudes required for switching and the corresponding reversal times of the nanoparticle's magnetic moment. In particular, we contrast the cases of static and time-dependent external fields and analyze the influence of damping for a uniaxial and a cubic anisotropy.Comment: accepted by Journal of Physics: Condensed Matte

Partition Functions of Classical Heisenberg Spin Chains with Arbitrary and Different Exchange

The classical Heisenberg model has been effective in modelling exchange interactions in molecular magnets. In this model, the partition function is important as it allows the calculation of the magnetization and susceptibility. For an ensemble of N-spin sites, this typically involves integrals in 2N dimensions. Here, for two-, three- and four-spin nearest neighbour open linear Heisenberg chains these integrals are reduced to sums of known functions, using a result due to Gegenbauer. For the case of the three- and four-spin chains, the sums are equivalent in form to the results of Joyce. The general result for an N-spin chain is also obtained

Wireless-based identification and model updating of a skewed highway bridge for structural health monitoring

Vibration-based monitoring was performed on a short-span skewed highway bridge on the basis of wireless measurements. By means of operational modal analysis, highly accurate modal results (frequencies and mode shapes) were extracted by using a self-developed wireless acquisition system, for which the performance was verified in the field. In order to reproduce the experimental modal characteristics, a refined finite element model was manually tuned to reduce the idealization errors and then updated with the sensitivity method to reduce the parametric errors. It was found that to build a reliable Finite element (FE) model for application in structural health monitoring, the effects of superelevation and boundary conditions of a skewed bridge should be taken into account carefully

Low-field susceptibility of classical Heisenberg chains with arbitrary and different nearest-neighbour exchange

Interest in molecular magnets continues to grow, o®ering a link between the atomic and nanoscale properties. The classical Heisenberg model has been effective in modelling exchange interactions in such systems. In this, the magnetization and susceptibility are calculated through the partition function, where the Hamiltonian contains both Zeeman and exchange energy. For an ensemble of N spins, this requires integrals in 2N dimensions. For two, three and four spin nearest neighbour chains these integrals reduce to sums of known functions. For the case of the three and four spin chains, the sums are equivalent to results of Joyce. Expanding these sums, the effect of the exchange on the linear susceptibility appears as Langevin functions with exchange term arguments. These expressions are generalised here to describe an N spin nearest neighbour chain, where the exchange between each pair of nearest neighbours is different and arbitrary. For a common exchange constant, this reduces to the result of Fisher. The high temperature expansion of the Langevin functions for the different exchange constants, leads to agreement with the appropriate high temperature quantum formula of Schmidt et al., when the spin number is large. Simulations are presented for open linear chains of three, four and five spins with up to four different exchange constants, illustrating how the exchange constants can be retrieved successfully

Observation of a Griffiths-like phase in the paramagnetic regime of ErCo_2

A systematic x-ray magnetic circular dichroism study of the paramagnetic phase of ErCo2 has recently allowed to identify the inversion of the net magnetization of the Co net moment with respect to the applied field well above the ferrimagnetic ordering temperature, Tc. The study of small angle neutron scattering measurements has also shown the presence of short range order correlations in the same temperature region. This phenomenon, which we have denoted parimagnetism, may be related with the onset of a Griffiths-like phase in paramagnetic ErCo2. We have measured ac susceptibility on ErCo2 as a function of temperature, applied field, and excitation frequency. Several characteristics shared by systems showing a Griffiths phase are present in ErCo2, namely the formation of ferromagnetic clusters in the disordered phase, the loss of analyticity of the magnetic susceptibility and its extreme sensitivity to an applied magnetic field. The paramagnetic susceptibility allows to establish that the magnetic clusters are only formed by Co moments as well as the intrinsic nature of those Co moments

The Importance of Mineralogical Knowledge in the Sustainability of Artisanal Gold Mining: A Mid-South Peru Case

Mineralogy and gold processing techniques from several mining areas of the Nazca-Ocoña gold belt, Mid-South Peru, were investigated to assess the efficiency of gold extraction methods in relation to their mineralogy. The deposits from this belt are intrusion gold related to mineralization in quartz veins. Native gold occurs as micrometric grains encapsulated in pyrite and in minor amounts in other sulfides and quartz. Electrum is found mainly in fractures of pyrite and attains up to 35 wt. % Ag. In addition to these occurrences, gold tellurides also occur and they are abundant in San Luis. Gold processing is carried out by amalgamation with mercury and/or cyanidation. The comparison of the gold grade in the mineralizations and in the residual tailings indicates that a significant amount of gold is not recovered using the mercury amalgamation process and also, in the case of the gold recovery by cyanidation, except when cement was added to the cyanide solution. This was due to an increase in the pH that favours the dissolution of the gold matrix. In the cyanidation process carried out in tailings previously treated with mercury, part of the mercury retained in them is released to the atmosphere or to the cyanidation fluid