10,144 research outputs found
Adaptación de sistemas de verificación de firma manuscrita a dispositivos móviles
En este Trabajo de Fin de Grado se realiza un estudio para la adaptación de sistemas de verificación de firma manuscrita a dispositivos móviles. Para ello, en primer lugar, se hace un estudio de las tecnologías existentes, que han conseguido buenos resultados sobre firmas capturadas mediante tabletas digitalizadoras utilizando como útil de escritura un lápiz o stylus. Tras esto, se han desarrollado experimentos similares a los existentes, pero específicamente adaptados a las características especiales que tienen las firmas con el dedo. Con los resultados obtenidos, se ha realizado un estudio cuyo objetivo es identificar las diferencias existentes entre firmas capturadas mediante stylus y dedo, de forma que sea posible desarrollar un sistema robusto que pueda trabajar en ambos casos. Dado que las diferencias entre ambos tipos de firmas son bastante notables, la solución propuesta es mantener un sistema híbrido que identifique la situación particular de cada firma y utilice los parámetros que ofrezcan mejor resultado para cada caso concreto. En segundo lugar, en este proyecto también se ha llevado a cabo un perfeccionamiento de los protocolos experimentales existentes, evitando situaciones de sobreentrenamiento. Estudios anteriores a este trabajo se han realizado sin tener cuidado de evitar estas situaciones, que habitualmenteconllevanunadegradacióndelrendimientodelmismoydificultadparageneralizar el sistema propuesto a un tamaño de datos mayor. Paralosexperimentosllevadosacaboenesteproyectosehanutilizadolasprincipalesbasesde datos existentes de firmas con el dedo, concluyendo que el factor más limitante para el desarrollo de esta tecnología es la reducida cantidad de datos disponibles, lo que impide el aprovechamiento completo del rendimiento ofrecido por algoritmos como SFFS, que ofrecen mejores resultados cuantos más datos de entrenamiento estén disponibles. Por último, una vez extraídas las conclusiones al respecto, se ha propuesto una serie de temas para trabajos futuros
The effect of nature on designers' creativity, according to their personality profile
The aim of this work is to demonstrate whether natural environments, either real or simulated, tend to enhance designers' creativity, and whether the effects differ depending on their personality profile. Numerous studies have been conducted on the variables that shape the work environment and affect the designer's creativity, but few take into account the interaction between the work environment and the designer's personality profile. The aim of this study is to carry out a practical experiment in which a certain number of individuals solve conceptual design problems in different work environments, followed by an assessment of the creativity of the results. The results show higher values of creativity for both types of natural setting than in a neutral scenario. The personality of the designers determines whether the highest values are achieved in real or in artificial nature
Recursive linear estimation for discrete time systems in the presence of different multiplicative observation noises
This paper describes a design for a least mean square error estimator in discrete time systems where the components of the state vector, in measurement equation, are corrupted by different multiplicative noises in addition to observation noise. We show how known results can be considered a particular case of the algorithm stated in this paperState estimation, multiplicative noise, uncertain observations
Use of the supercritical fluid technology for the preparation of nanostructured hybrid materials and design of the interface
Premi extraordinari doctorat curs 2009-2010, àmbit d’Enginyeria IndustrialLos materiales compuestos nanoestructurados son considerados una opción prometedora
para la concepción de materiales multifuncionales. Sin embargo, la falta habitual de interacción
entre los componentes orgánicos e inorgánicos en los materiales híbridos nanoestructurados
comporta unas propiedades macroscópicas anisotrópicas que limitan su uso. Por ello, se hace
necesario el diseño de la interfase formada entre los componentes mencionados a fin de mejorar
sus prestaciones. En esta Tesis Doctoral se ha optado por el uso de dióxido de carbono supercrítico
(scCO2) para la modificación superficial de nanopartículas inorgánicas y para la preparación de
materiales híbridos nanoestructurados. Estos procesos supercríticos, diseñados como sostenibles,
se proponen como sustitutos de técnicas convencionales que empleen disolventes orgánicos.
El tratamiento superficial de nanopartículas de dióxido de titanio (TiO2) con
octiltrietoxisilano se ha empleado como sistema de estudio para evaluar el uso de recubrimientos
de alcoxisilanos bifuncionales como promotores de adhesión de partículas inorgánicas
nanométricas. El scCO2 se emplea como disolvente del alcoxisilano para la silanización del TiO2.
También se han llevado a cabo estudios fundamentales de solubilidad de octiltrietoxisilano en
CO2 y de la cinética del proceso de silanización del TiO2. La modulación de las propiedades
fisicoquímicas del scCO2 con la presión y la temperatura permite el control de las características
del recubrimiento con silano. El proceso de silanización supercrítico se ha extendido a diferentes
sistemas alcoxisilano-nanopartículas inorgánicas.
Asimismo, se ha evaluado la tecnología de scCO2 para la preparación de materiales
híbridos nanoestructurados que contengan nanopartículas inorgánicas silanizadas. El tratamiento
superficial de las nanopartículas favorece la distribución homogénea de éstas en el material
híbrido y mejora la interacción relleno-matriz orgánica. Se han procesado matrices
biopoliméricas de interés en ingeniería tisular, compuestas de ácido poliláctico o la mezcla
iv
polimetilmetacrilato/policaprolactona, con adiciones de nanopartículas de TiO2 o hidroxiapatita,
respectivamente. Para su procesado, se ha empleado scCO2 como no-disolvente utilizando la
técnica Particles from a Compressed Anti-Solvent (PCA). Además, se han preparado partículas
híbridas formadas por una mezcla lipídica de aceite de ricino hidrogenado y glicerilmonoestearato
con adiciones de TiO2 y cafeína, con posibles aplicaciones en cremas para uso tópico. Estas
partículas sólidas lipídicas se han obtenido usando la técnica Particles from Gas Saturated
Solutions (PGSS) que emplea scCO2 como soluto.
Por último, el proceso de silanización supercrítico se ha ensayado para materiales híbridos
complejos multiescalados. Se han procesado materiales de base cemento empleando un proceso
supercrítico de carbonatación-silanización en dos etapas. Primero, el cemento se carbonata de
manera acelerada usando scCO2 como agente de carbonatación. Este cemento, ya carbonatado, se
somete, finalmente, a un tratamiento hidrofóbico mediante silanización supercrítica, para su
posible aplicación en confinamiento de residuos peligrosos en ambientes húmedos o como
material de construcción duradero.Nowadays, society is asking for a global changing in the way of manufacturing goods in a
more sustainable manner. Indeed, the weight of the classical factors (cost, quality, appearance)
influencing the acceptance of a certain good in the market have currently changed.
Manufacturing requirements and regulations concerning environment protection (e.g., resource
consumption, sustainability, toxicity, CO2 footprint, recycling potential) and quality features (e.g.,
product guarantees, durability against aggressive environments, corporate vision) are aspects of
increasing concern. The competitive position of a company is influenced by seizing the
opportunities and challenges and by managing the risks that the changeable market has. As a
consequence, the industry is continuously looking for smart and innovative solutions for the
design and manufacturing of materials with novel properties and increased added value, and for
the production of materials already existing in the market in a more efficient manner.
Nanostructured hybrid composites have emerged as a promising class of innovative
materials for many industrial sectors (e.g., energy, optoelectronics, biomedicine, cosmetics). The
multicomponent composition of these materials provides them with unique properties arising
from the synergistic combination of the characteristics of their individual components structured
at the nanolevel. Nevertheless, in numerous hybrid materials, the lack of coupling or bonding
between the components often leads to anisotropic macroscopic properties, limiting their use.
Hence, the interaction at the interphase between hybrid components must be properly
engineered to enhance materials properties. In this PhD Thesis, the quest for sustainable and
environmentally friendly processes led to the use of supercritical carbon dioxide (scCO2) for both
the surface modification of nanometric inorganic particles and the preparation of nanostructured
hybrid materials. These processes are designed for the replacement of conventional methods
using organic solvents.
vi
Bifunctional alkoxysilane molecules, acting as adhesion promoters, are, herein,
investigated for the surface modification of nanometric inorganic particles. The surface treatment
of titanium dioxide (TiO2) nanoparticles with octyltriethoxysilane is taken as the model system
for study. In terms of processing, scCO2 is used as the solvent of choice for alkoxysilanes for the
surface modification of TiO2. Fundamental studies on the solubility of the used silane in CO2 in
the pressure range 8-18 MPa at two different temperatures (318 and 348 K) and on the kinetics of
the TiO2 silanization process are performed. For the scCO2-aided silanization process, studies are
conducted to ascertain the effects and interactions of the operating variables on the properties of
the final material. Results show that the tunable physicochemical properties of scCO2 with
pressure and temperature (e.g., density, solvation power) allows the engineering control of the
characteristics of the silane coating. Examples of the extension of the application of the
supercritical silanization process to other sets of alkoxysilanes and inorganic nanoparticles are
also presented.
The preparation of hybrid materials including silanized inorganic nanoparticles and
organic matrices is further tested using scCO2 technology. Surface treated nanoparticles are used
to facilitate the homogeneous distribution of the nanoparticles within the matix and to improve
the inorganic filler-organic matrix interaction. Biopolymeric matrices of either poly(L-lactic acid)
(L-PLA) or the blend poly(methylmethacrylate)/poly(ε-caprolactone) (PMMA/PCL) loaded with
nanometric titanium dioxide or hydroxyapatite, respectively, are prepared. To obtain these
hybrid materials, scCO2 is employed as an anti-solvent, using the Particles from a Compressed
Anti-Solvent (PCA) technique. Studies are performed to pursue the effect of the processing
conditions on the morphology of the precipitated hybrid materials. The resulting material,
obtained in the form of fibers, has suitable properties for its potential application in tissue
engineering. In a different system, hybrid particles composed of a lipidic matrix (hydrogenated
castor oil/glyceryl monostearate) loaded with silanized titanium dioxide and caffeine are
prepared. The Particles from Gas Saturated Solutions (PGSS) technique, assisted by the use of
scCO2 as a solute, is employed for the production of these solid lipid particles. The obtained
hybrid material is evaluated concerning the drug carrier and release ability and the UV-shielding
capacity. The UV-light protection and photoaging prevention capacity of the lipid-based hybrid
material provide excellent properties for the use of these particles in the formulation of
sunscreens and pharmaceutical dermal products.
vii
Finally, the possibility of extending the supercritical silane treatment to multiscale
complex hybrid materials is assessed. The technology based on the use of scCO2 is presented for
the two-step carbonation-silanization process of cement-based materials. In the first step, the
carbonation of cement is accelerated using scCO2 as the carbonation agent. The effects of the
cement formulation and process operation conditions on the microstructure and physicochemical
properties of carbonated samples are evaluated. The carbonation process is followed by the
hydrophobic treatment of the carbonated samples using a supercritical silanization method. The
surface modification of carbonated cement with octyltriethoxysilane confers water repellence to
the material. The carbonation-silanization process is scheduled and integrated to mitigate the
consumption of raw materials and the use of facilities.Award-winningPostprint (published version
Efectos de un entrenamiento de fuerza de corta duración sobre la capacidad de salto vertical en jugadores de voleibol de elite durante la temporada
The aim of this study was to describe the effects of 6 weeks of combined strength and jump training which incorporated modera
te loads and
high intensity contractions on the vertical jump ability (VJ), loaded jumps and velocity of execution in full squat in a group
of professional male
volleyball players during the competition season. It was hypothesized that the VJ improved by cross combined strength and jump
training both
characterized by high velocity of execution (>1m/s). The participants in this study were twelve players who competed in the fir
st national division of
the Spanish National League during the 2011-2012 season. The neuromuscular performance was estimated by unloaded (CMJ) and load
ed
countermovement jumps (CMJ
loaded
) height (cm); and by velocity of displacement in the concentric phase of full squat (FS) (m/s). There was a
significant increase in CMJ and CMJ
loaded
after 6-week of training (5%, p<0.01; and 5.7%, p<0.05; respectively). These changes were accompanied by
a small and moderate value of Effect Size (0.47, and 0.67; respectively). No significant differences were observed for velocity
of displacement in FS.
The linear correlation analysis showed a single moderate correlation statistically significant between the changes in CMJ-CMJ
loaded
and CMJ-FS (r=0.62
and r=0.59, p<0.05; respectively). Albeit speculative, our results suggest that the use of moderate loads could be enough to im
prove the vertical jump
performance, since in our study a load equivalent to 60% 1RM in the FS was not exceeded and jumping exercises were performed wi
th light loads.El objetivo de este estudio fue describir los efectos de 6 semanas de entrenamiento combinado de fuerza y salto, el cual incorpora cargas
moderadas e intensidades de contracción altas, sobre la capacidad de salto vertical, saltos con cargas y la velocidad de ejecución en el ejercicio de sentadilla
en un grupo de jugadores profesionales de voleibol durante la temporada de competición. Se estableció la hipótesis de que el sa
lto vertical mejoro por el
uso combinado de entrenamiento de fuerza y salto, ambos caracterizados por una alta velocidad de ejecución (>1m/s). El rendimie
nto neuromuscular fue
estimado por la altura (cm) del salto sin cargas (CMJ), salto con cargas (CMJ
loaded
), y por la velocidad (m/s) de desplazamiento en la fase concéntrica en
la sentadilla completa (FS). Tuvo lugar un incremento significativo en CMJ y CMJ
loaded
después de 6 semanas de entrenamientos (5%, p<0.01; y 5.7%,
p<0.05; respectivamente). Estos cambios fueron acompañados por un valor de Tamaño del Efecto pequeño y moderado (0.47, and 0.67
; respectivamente). No se observaron diferencias significativas en la velocidad de desplazamiento en FS. El análisis de correlación lineal
mostró una correlación
moderada estadísticamente significativa entre los cambios en CMJ-CMJ
loaded
y CMJ-FS (r=0.62; y r=0.59, p<0.05; respectivamente). Aunque algo
especulativo, nuestros resultados sugieren que el uso de cargas moderadas podría ser suficiente para mejorar el rendimiento del
salto vertical, ya que en
nuestro estudio no se excedió una carga equivalente al 60% de 1RM en FS y los ejercicios de saltos también fueron realizados con cargas ligeras
Relating free will beliefs and attitudes
D.W. was supported by the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie (MSCA) grant agreement no. 665501 and the Flemish Science Foundation (FWO) grant FWO.KAN.2019.0023.01. E.C. was supported by FWO grants FWO18/PDO/049 and 12U0322N. C.G.-G. was supported by MSCA grant no. 835767 and the Spanish Ministry of Science and Innovation grant IJC2019-040208-I. M.B. was supported by the Einstein Foundation Berlin (Einstein Strategic Professorship). ReferencesMost people believe in free will, which is foundational for our
sense of agency and responsibility. Past research demonstrated
that such beliefs are dynamic, and can be manipulated
experimentally. Much less is known about free will attitudes
(FWAs; do you value free will?), whether they are equally
dynamic, and about their relation to free will beliefs (FWBs).
If FWAs were strongly positive, people might be reluctant to
revise their beliefs even in the face of strong evidence to do
so. In this registered report, we developed a novel measure
of FWAs and directly related FWBs and attitudes for the first
time. We found FWBs and attitudes to be positively related,
although to a lesser degree than determinism or dualism
beliefs/attitudes. Nevertheless, an experimental manipulation
technique aimed at reducing FWBs (Crick text) showed
remarkably specific effects on FWBs only, and no effects on
FWAs. Overall, these results provide valuable new insights
into laypeople’s views on free will by including a novel
measure of FWAs. They also provide evidence for the
validity of a common experimental technique that has been
rightfully criticized in the literature lately.European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie (MSCA) 665501FWO FWO.KAN.2019.0023.01
FWO18/PDO/049
12U0322N
MSCA 835767Spanish Government IJC2019-040208-IEinstein Foundation Berlin (Einstein Strategic Professorship
Knowledge generation for enhancing design creativity through co-creative Virtual Learning Communities
With the current technological explosion, the arrival of Web 2.0 and the growth of ICTs, designers’ tools can be understood and used by novice users. With this statement in mind, and considering previous works that claim that team-working enhances creativity, the present paper reports on an experiment conducted to test whether a large group of creative people organised in a Virtual Learning Community are able to produce a Graphic Design with a satisfactory level of creativity starting from an almost complete lack of knowledge on the discipline, where a “satisfactory level of creativity” is understood as being that level which can be achieved by an individual with specific knowledge in the subject working in isolation. The results were assessed by means of an adapted questionnaire based on the CPSS taxonomy, and statistically analysed using ANOVA. The conclusions appear to reinforce the idea that virtual team-working enhances creativity, but the lack of specific competence training can be discerned by an expert eye.The research presented in this paper was funded by the Universitat Jaume I (project ref. P1· 1B2015-30 - El arte y el diseño en la nueva sociedad digital
Estimation of specific cutting energy in an S235 alloy for multi-directional ultrasonic vibration-assisted machining using the Finite Element Method
The objective of this work is to analyze the influence of the vibration-assisted turning process on the machinability of S235 carbon steel. During the experiments using this vibrational machining process, the vibrational amplitude and frequency of the cutting tool were adjusted to drive the tool tip in an elliptical or linear motion in the feed direction. Furthermore, a finite element analysis was deployed to investigate the mechanical response for different vibration-assisted cutting conditions. The results show how the specific cutting energy and the material’s machinability behave when using different operational cutting parameters, such as vibration frequency and tool tip motion in the x-axis, y-axis, and elliptical (x-y plane) motion. Then, the specific cutting energy and material’s machinability are compared with a conventional turning process, which helps to validate the finite element method (FEM) for the vibration-assisted process. As a result of the operating parameters used, the vibration-assisted machining process leads to a machinability improvement of up to 18% in S235 carbon steel. In particular, higher vibration frequencies were shown to increase the material’s machinability due to the specific cutting energy decrease. Therefore, the finite element method can be used to predict the vibration-assisted cutting and the specific cutting energy, based on predefined cutting parameters.Peer ReviewedPostprint (published version
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