365 research outputs found

    Towards an ecological index for tropical soil quality based on soil macrofauna

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    The objective of this work was to construct a simple index based on the presence/absence of different groups of soil macrofauna to determine the ecological quality of soils. The index was tested with data from 20 sites in South and Central Tabasco, Mexico, and a positive relation between the model and the field observations was detected. The index showed that diverse agroforestry systems had the highest soil quality index (1.00), and monocrops without trees, such as pineapple, showed the lowest soil quality index (0.08). Further research is required to improve this model for natural systems that have very low earthworm biomass

    Systematic XAS study on the reduction and uptake of Tc by magnetite and mackinawite

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    The mechanisms for the reduction and uptake of Tc by magnetite (Fe3O4) and mackinawite (FeS) are investigated using X-ray absorption spectroscopy (XANES and EXAFS), in combination with thermodynamic calculations of the Tc/Fe systems and accurate characterization of the solution properties (pHm, pe, [Tc]). Batch sorption experiments were performed under strictly anoxic conditions using freshly prepared magnetite and mackinawite in 0.1 M NaCl solutions with varying initial Tc(VII) concentrations (2 × 10−5 and 2 × 10−4 M) and Tc loadings (400–900 ppm). XANES confirms the complete reduction of Tc(VII) to Tc(IV) in all investigated systems, as predicted from experimental (pHm + pe) measurements and thermodynamic calculations. Two Tc endmember species are identified by EXAFS in the magnetite system, Tc substituting for Fe in the magnetite structure and Tc–Tc dimers sorbed to the magnetite {111} faces through a triple bond. The sorption endmember is favoured at higher [Tc], whereas incorporation prevails at low [Tc] and less alkaline pH conditions. The key role of pH in the uptake mechanism is interpreted in terms of magnetite solubility, with higher [Fe] and greater recrystallization rates occurring at lower pH values. A TcSx-like phase is predominant in all investigated mackinawite systems, although the contribution of up to 20% of TcO2·xH2O(s) (likely as surface precipitate) is observed for the highest investigated loadings (900 ppm). These results provide key inputs for an accurate mechanistic interpretation of the Tc uptake by magnetite and mackinawite, so far controversially discussed in the literature, and represent a highly relevant contribution to the investigation of Tc retention processes in the context of nuclear waste disposal

    Nonuniform high-gamma (60-500 Hz) power changes dissociate cognitive task and anatomy in human cortex

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    High-gamma-band (\u3e60 Hz) power changes in cortical electrophysiology are a reliable indicator of focal, event-related cortical activity. Despite discoveries of oscillatory subthreshold and synchronous suprathreshold activity at the cellular level, there is an increasingly popular view that high-gamma-band amplitude changes recorded from cellular ensembles are the result of asynchronous firing activity that yields wideband and uniform power increases. Others have demonstrated independence of power changes in the low- and high-gamma bands, but to date, no studies have shown evidence of any such independence above 60 Hz. Based on nonuniformities in time-frequency analyses of electrocorticographic (ECoG) signals, we hypothesized that induced high-gamma-band (60-500 Hz) power changes are more heterogeneous than currently understood. Using single-word repetition tasks in six human subjects, we showed that functional responsiveness of different ECoG high-gamma sub-bands can discriminate cognitive task (e.g., hearing, reading, speaking) and cortical locations. Power changes in these sub-bands of the high-gamma range are consistently present within single trials and have statistically different time courses within the trial structure. Moreover, when consolidated across all subjects within three task-relevant anatomic regions (sensorimotor, Broca\u27s area, and superior temporal gyrus), these behavior- and location-dependent power changes evidenced nonuniform trends across the population. Together, the independence and nonuniformity of power changes across a broad range of frequencies suggest that a new approach to evaluating high-gamma-band cortical activity is necessary. These findings show that in addition to time and location, frequency is another fundamental dimension of high-gamma dynamics

    Sequential heuristic optimisation of a real offshore wind farm site considering turbine placement and cable layout

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    Competition within the energy generation industry provides an incentive for developers to build offshore wind farms with a low levelised cost of energy. Therefore, there is a need for design optimisation to reduce costs and increase energy capture. A sequential approach to optimise turbine placement and cable layout is presented, using a heuristic k-opt algorithm and mixed-integer linear programming respectively. Energy storage is considered as a means to further improve the cable selection process. A case study is carried out on the Lillgrund offshore wind farm and the resulting layout improves energy capture by 6%. Cable costs are increased but the electrical losses are reduced such that there is an overall saving over the project lifetime of 20%. Energy storage as a means to peak shave the power seen by a cable in order to reduce electrical losses or de-rate a cable section was found to be impractically large and not profitable. Future work will consider secondary revenue streams to remedy this

    A vision of uses and gratifications applied to the study of Internet use by adolescents

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    Based on uses and gratifications theory, the aim of this paper is to identify the reasons for using Internet among teenagers and to check different variables in order to predict types of uses. After conducting a representative survey applied to 397 high school students in Community of Madrid (Spain), Internet users’ gratifications and their relationships with variables related to adolescent characteristics, family context and time of online exposure are analyzed. The article concludes that daily use of Internet predicts higher consumption of communication and social relationship
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