Solar-driven broad spectrum fungicides based on monodispersed Cu₇S₄ nanorods with strong near-infrared photothermal efficiency

The development of low-cost and biocompatible inorganic photothermal nanoagents with broadband sunlight absorption and high photothermal conversion efficiency as broad spectrum fungicides is highly desirable for the large scale antibacterial treatment especially in the wild, because of their highly efficient anti-bacteria ability via solar irradiation. Here, we present a facile strategy for the synthesis of Cu7S4 nanorods (NRs) with broadband light absorption (300-3300 nm) and high photothermal conversion efficiency (57.8%, 808 nm), and the use of these NRs as broad spectrum fungicides for efficient disinfection using natural sunlight as light source. In the presence of Cu7S4 NRs, with natural sunlight irradiation (70 mW cm-2), both Gram-positive (S. aureus) and Gram-negative (E. coli) bacterium strains (2 mL, 106 mL-1) were completely killed in 10 min. These results suggest that our Cu7S4 NRs are effective and broad spectrum photothermal anti-bacterial agents regardless of drug resistance, that are particularly suitable for anti-bacteria activity in the wild using solar irradiation where artificial light sources are not available. Due to their strong near infrared (NIR) absorption, these biocompatible and low-cost Cu7S4 NRs may also serve as promising agents for photothermal therapy of tumors, disinfection in clinics, food sterilization and environmental treatment.</p

Synthesis and fungicidal activity of pyrazole derivatives containing 1,2,3,4-tetrahydroquinoline

Additional file 3. Structural information (CIF) for Compound 10g

Validation of Sentinel-2, MODIS, CGLS, SAF, GLASS and C3S leaf area index products in maize crops

Altres ajuts: this research was funded by the Copernicus Global Land Service (CGLOPS-1, 199494-JRC).We proposed a direct approach to validate hectometric and kilometric resolution leaf area index (LAI) products that involved the scaling up of field-measured LAI via the validation and recalibration of the decametric Sentinel-2 LAI product. We applied it over a test study area of maize crops in northern China using continuous field measurements of LAINet along the year 2019. Sentinel-2 LAI showed an overall accuracy of 0.67 in terms of Root Mean Square Error (RMSE) and it was used, after recalibration, as a benchmark to validate six coarse resolution LAI products: MODIS, Copernicus Global Land Service 1 km Version 2 (called GEOV2) and 300 m (GEOV3), Satellite Application Facility EUMETSAT Polar System (SAF EPS) 1.1 km, Global LAnd Surface Satellite (GLASS) 500 m and Copernicus Climate Change Service (C3S) 1 km V2. GEOV2, GEOV3 and MODIS showed a good agreement with reference LAI in terms of magnitude (RMSE ≤ 0.29) and phenology. SAF EPS (RMSE = 0.68) and C3S V2 (RMSE = 0.41), on the opposite, systematically underestimated high LAI values and showed systematic differences for phenological metrics: a delay of 6 days (d), 20 d and 24 d for the start, peak and the end of growing season, respectively, for SAF EPS and an advance of −4 d, −6 d and −6 d for C3S

Solar-driven broad spectrum fungicides based on monodispersed Cu₇S₄ nanorods with strong near-infrared photothermal efficiency

Cu7S4 nanorods were used for the first time as broad spectrum fungicides for efficient bacterial disinfection via natural sunlight irradiation.</p

Ultrasmall Organic Nanoparticles with Aggregation-Induced Emission and Enhanced Quantum Yield for Fluorescence Cell Imaging

The use of fluorescence probes for biomedical imaging has attracted significant attention over recent years owing to their high resolution at cellular level. The probes are available in many formats including small particle size based imaging agents which are considered to be promising candidates, due to their excellent stabilities. Yet, concerns over the potential cytotoxicity effects of inorganic luminescent particles have led to questions about their suitability for imaging applications. Exploration of alternatives inspired us to use organic fluorophores with aggregation-induced emission (AIE), prepared by functionalizing the amine group on tetraphenylethene with 3,5-bis­(trifluoromethyl)­phenyl isocyanate. The as-synthesized novel AIE fluorophore (TPE-F) display enhanced quantum yield and longer lifetime as compared with its counterparts (4,4′,4″,4‴-(ethene-1,1,2,2-tetrayl)­tetraaniline, TPE-AM). Furthermore, the TPE-F was encapsulated into small-size organic nanoparticles (NPs; dynamic light scattering size, ∼10 nm) with polysuccinimide (PSI). The biocompatibility, excellent stability, bright fluorescence, and selective cell targeting of these NPs enable the as-prepared TPE-F NPs to be suitable for specific fluorescence cell imaging

Exploring the Potential of Gaofen-1/6 for Crop Monitoring: Generating Daily Decametric-Resolution Leaf Area Index Time Series

High spatiotemporal resolution time series of leaf area index (LAI) are essential for monitoring crop dynamics and validating coarse-resolution LAI products. The optical satellite sensors at decametric resolution have historically suffered from a long revisit cycle and cloud contamination issues that hampered the acquisition of frequent and high-quality observations. The 16-m/four-day resolution of the new-generation Gaofen-1 (GF-1) and Gaofen-6 (GF-6) satellites provide an unprecedented opportunity to address these limitations. Here, we developed an effective strategy to generate daily 16-m LAI maps combining GF-1/6 data and ground LAINet measurements. All high-quality GF-1/6 observations were utilized first to derive smoothed time series of vegetation indices (VIs). Second, a random forest regression (RF-r) model was trained to link the VIs with corresponding field LAI measurements. The trained RF-r was finally employed to generate the LAI maps. Results demonstrated the reliability of the reconstructed daily VIs (relative error (RE) < 1%) and the derived LAI time series, which greatly benefited from GF-1/6 high-frequency observations. The direct comparison with field LAI measurements by LAI-2200/LI-3000 showed the good performance of retrieved LAI maps, with bias, root mean square error (RMSE), and R2 of 0.05, 0.59, and 0.75, respectively. The LAI time series well captured the spatiotemporal variation of crop growth. Furthermore, the continuous GF-1/6 LAI maps outperformed Sentinel-2 LAI estimates both in terms of temporal frequency and accuracy. Our study indicates the potential of GF-1/6 to generate continuous decametric-resolution LAI maps for fine-scale agricultural monitoring

The genomic and bulked segregant analysis of \u3ci\u3eCurcuma alismatifolia\u3c/i\u3e revealed its diverse bract pigmentation

Compared with most flowers where the showy part comprises specialized leaves (petals) directly subtending the reproductive structures, most Zingiberaceae species produce showy ‘‘flowers’’ through modifications of leaves (bracts) subtending the true flowers throughout an inflorescence. Curcuma alismatifolia, belonging to the Zingiberaceae family, a plant species originating from Southeast Asia, has become increasingly popular in the flower market worldwide because of its varied and esthetically pleasing bracts produced in different cultivars. Here, we present the chromosome-scale genome assembly of C. alismatifolia ‘‘Chiang Mai Pink’’ and explore the underlying mechanisms of bract pigmentation. Comparative genomic analysis revealed C. alismatifolia contains a residual signal of wholegenome duplication. Duplicated genes, including pigment-related genes, exhibit functional and structural differentiation resulting in diverse bract colors among C. alismatifolia cultivars. In addition, we identified the key genes that produce different colored bracts in C. alismatifolia, such as F3\u275’H, DFR, ANS and several transcription factors for anthocyanin synthesis, as well as chlH and CAO in the chlorophyll synthesis pathway by conducting transcriptomic analysis, bulked segregant analysis using both DNA and RNA data, and population genomic analysis. This work provides data for understanding the mechanism of bract pigmentation and will accelerate breeding in developing novel cultivars with richly colored bracts in C. alismatifolia and related species. It is also important to understand the variation in the evolution of the Zingiberaceae family

Ultrasmall Organic Nanoparticles with Aggregation-Induced Emission and Enhanced Quantum Yield for Fluorescence Cell Imaging

The use of fluorescence probes for biomedical imaging has attracted significant attention over recent years owing to their high resolution at cellular level. The probes are available in many formats including small particle size based imaging agents which are considered to be promising candidates, due to their excellent stabilities. Yet, concerns over the potential cytotoxicity effects of inorganic luminescent particles have led to questions about their suitability for imaging applications. Exploration of alternatives inspired us to use organic fluorophores with aggregation-induced emission (AIE), prepared by functionalizing the amine group on tetraphenylethene with 3,5-bis(trifluoromethyl)phenyl isocyanate. The as-synthesized novel AIE fluorophore (TPE-F) display enhanced quantum yield and longer lifetime as compared with its counterparts (4,4′,4″,4-(ethene-1,1,2,2-tetrayl)tetraaniline, TPE-AM). Furthermore, the TPE-F was encapsulated into small-size organic nanoparticles (NPs; dynamic light scattering size, ∼10 nm) with polysuccinimide (PSI). The biocompatibility, excellent stability, bright fluorescence, and selective cell targeting of these NPs enable the as-prepared TPE-F NPs to be suitable for specific fluorescence cell imaging.</p