Aurophilic interactions in polynuclear Au(I) complexes with phosphine ligands containing imidazole rings

Aurophilic interactions in polynuclear Au(I) complexes with phosphine ligands containing imidazole rings Fiorella Bachechiaa*, Alfredo Burinib, Rossana Galassib aIstituto di Strutturistica Chimica, C.N.R., Area della Ricerca di Roma, C.P. 10, 00016 Monterotondo St. (Roma), Italy., bDipartimento di Scienze Chimiche, Università di Camerino, 62032 Camerino, Italy. E-mail: [email protected] Keywords: gold complexes, aurophilicity, crystal structures The tertiary phosphines of the type (Bzim)3-nPhnP, where Bzim is 1-benzyl-2-imidazolylphosphine and n varies from 0 to 2, were synthesised as part of a program aimed to the study of the coordination chemistry of phosphines containing imidazole rings. The softer character of imidazole, with respect to other heterocycles, turned out to be useful in the stabilization of complexes with soft metals as those of Group 11 in low oxidation states. These ligands can behave as monodentate or as P, N bidentate forming dinuclear cationic complexes. With Au(I) they were found to be able to favour the formation of intraand intermolecular aurophilic interactions. TheAu(I) complexes assume considerable interest when aurophilic bonds occur between gold atoms, since their chemical and physical properties change to particular characteristics with potential applications in electronic, optical or sensor devices. In particular short Au•••Au interactions are considered related to optoelectronic properties as observed in a number of polynuclear gold compounds. Here the structures of two Au(I) complexes are reported. The binuclear complex [μ-(Bzim)Ph2PAu2(C6F5)2] adopts a folded conformation with parallel, eclipsed C6F5 rings and a corresponding short AucccAu contact of 3.033(2)Å. The tetranuclear cluster complex {[μ-N,N’-(Bzim)3PAuCl]2 Au2}2+c AuCl2 - c AuCl4 - consists in a 12-membered macrocycle with two gold atoms coordinated to two (Bzim)3P molecules, in bridging mode, through the nitrogen atoms of the imidazole rings and two gold atoms coordinated to the phosphorus atoms of the (Bzim)3P ligands. Two chloride atoms complete the Au bicoordination. Three strong aurophilic interactions, Au(1)cccAu(4) [2.989(2)Å], Au(2)cccAu(3) [3.014(2)Å] andAu(1)cccAu(2) [3.257(3)Å], occur.Aweak gold-gold contact, Au(3)cccAu(4) [3.766(2)Å], is also present. Understanding molecular interactions 23r

Gamma-ray Bursts, Classified Physically

From Galactic binary sources, to extragalactic magnetized neutron stars, to long-duration GRBs without associated supernovae, the types of sources we now believe capable of producing bursts of gamma-rays continues to grow apace. With this emergent diversity comes the recognition that the traditional (and newly formulated) high-energy observables used for identifying sub-classes does not provide an adequate one-to-one mapping to progenitors. The popular classification of some > 100 sec duration GRBs as ``short bursts'' is not only an unpalatable retronym and syntactically oxymoronic but highlights the difficultly of using what was once a purely phenomenological classification to encode our understanding of the physics that gives rise to the events. Here we propose a physically based classification scheme designed to coexist with the phenomenological system already in place and argue for its utility and necessity.Comment: 6 pages, 3 figures. Slightly expanded version of solicited paper to be published in the Proceedings of ''Gamma Ray Bursts 2007,'' Santa Fe, New Mexico, November 5-9. Edited by E. E. Fenimore, M. Galassi, D. Palme

The hidden X-ray breaks in afterglow light curves

Gamma-Ray Burst (GRB) afterglow observations in the Swift era have a perceived lack of achromatic jet breaks compared to the BeppoSAX, or pre-Swift era. Specifically, relatively few breaks, consistent with jet breaks, are observed in the X-ray light curves of these bursts. If these breaks are truly missing, it has serious consequences for the interpretation of GRB jet collimation and energy requirements, and the use of GRBs as standard candles. Here we address the issue of X-ray breaks which are possibly 'hidden' and hence the light curves are misinterpreted as being single power-laws. We show how a number of precedents, including GRB 990510 & GRB 060206, exist for such hidden breaks and how, even with the well sampled light curves of the Swift era, these breaks may be left misidentified. We do so by synthesising X-ray light curves and finding general trends via Monte Carlo analysis. Furthermore, in light of these simulations, we discuss how to best identify achromatic breaks in afterglow light curves via multi-wavelength analysis.Comment: 4 pages, contributed talk, submitted to the proceedings of Gamma Ray Bursts 2007, Santa Fe, New Mexico, November 5-9 200

GRBs and the thermalization process of electron-positron plasmas

We discuss the temporal evolution of the pair plasma created in Gamma-Ray Burst sources. A particular attention is paid to the relaxation of the plasma into thermal equilibrium. We also discuss the connection between the dynamics of expansion and the spatial geometry of the plasma. The role of the baryonic loading parameter is emphasized.Comment: 4 pages, 3 figures, in the Proceedings of the "Gamma Ray Bursts 2007" meeting, November 5-9, 2007, Santa Fe, New Mexico, US

Dispersion analysis of the nucleon form factors including meson continua

Dispersion relations provide a powerful tool to analyse the electromagnetic form factors of the nucleon for all momentum transfers. Constraints from meson-nucleon scattering data, unitarity, and perturbative QCD can be included in a straightforward way. In particular, we include the 2pi, rho-pi, and KKbar continua as independent input in our analysis and provide an error band for our results. Moreover, we discuss two different methods to include the asymptotic constraints from perturbative QCD. We simultaneously analyze the world data for all four form factors in both the space-like and time-like regions and generally find good agreement with the data. We also extract the nucleon radii and the omega-NN coupling constants. For the radii, we generally find good agreement with other determinations with the exception of the electric charge radius of the proton which comes out smaller. The omega-NN vector coupling constant is determined relatively well by the fits, but for the tensor coupling constant even the sign can not be determined.Comment: 24 pages, 9 figure

GRB 070714B - Discovery of the Highest Spectroscopically Confirmed Short Burst Redshift

Gemini Nod & Shuffle spectroscopy on the host of the short GRB 070714B shows a single emission line at 7167 angstroms which, based on a grizJHK photometric redshift, we conclude is the 3727 angstrom [O II] line. This places the host at a redshift of z=.923 exceeding the previous record for the highest spectroscopically confirmed short burst redshift of z=.546 held by GRB 051221. This dramatically moves back the time at which we know short bursts were being formed, and suggests that the present evidence for an old progenitor population may be observationally biased.Comment: Conference procedings for Gamma Ray Bursts 2007 November 5-9, 2007 Santa Fe, New Mexico (4 pages, 2 figures

Optomechanical sideband cooling of a thin membrane within a cavity

We present an experimental study of dynamical back-action cooling of the fundamental vibrational mode of a thin semitransparent membrane placed within a high-finesse optical cavity. We study how the radiation pressure interaction modifies the mechanical response of the vibrational mode, and the experimental results are in agreement with a Langevin equation description of the coupled dynamics. The experiments are carried out in the resolved sideband regime, and we have observed cooling by a factor 350 We have also observed the mechanical frequency shift associated with the quadratic term in the expansion of the cavity mode frequency versus the effective membrane position, which is typically negligible in other cavity optomechanical devices.Comment: 15 pages, 7 figure

The Construction of Sorkin Triangulations

Some time ago, Sorkin (1975) reported investigations of the time evolution and initial value problems in Regge calculus, for one triangulation each of the manifolds $R*S^3$ and $R^4$. Here we display the simple, local characteristic of those triangulations which underlies the structure found by Sorkin, and emphasise its general applicability, and therefore the general validity of Sorkin's conclusions. We also make some elementary observations on the resulting structure of the time evolution and initial value problems in Regge calculus, and add some comments and speculations.Comment: 5 pages (plus one figure not included, available from author on request), Plain Tex, no local preprint number (Only change: omitted "\magnification" command now replaced

Influence of static electric fields on an optical ion trap

We recently reported on a proof-of-principle experiment demonstrating optical trapping of an ion in a single-beam dipole trap superimposed by a static electric potential [Nat. Photonics 4, 772--775 (2010)]. Here, we first discuss the experimental procedures focussing on the influence and consequences of the static electric potential. These potentials can easily prevent successful optical trapping, if their configuration is not chosen carefully. Afterwards, we analyse the dipole trap experiments with different analytic models, in which different approximations are applied. According to these models the experimental results agree with recoil heating as the relevant heating effect. In addition, a Monte-Carlo simulation has been developed to refine the analysis. It reveals a large impact of the static electric potential on the dipole trap experiments in general. While it supports the results of the analytic models for the parameters used in the experiments, the analytic models cease their validity for significantly different parameters. Finally, we propose technical improvements for future realizations of experiments with optically trapped ions.Comment: 16 pages, 16 figure