1,913 research outputs found

    Ultrathin epitaxial Fe films in vicinal GaAs(001): A study by spin-resolved photoelectron spectroscopy

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    Thin epitaxial Fe films have been grown on vicinal GaAs(001) substrates and their remanent magnetic properties and the degree of substrate atom diffusion investigated using synchrotron-based photoelectron spectroscopy. The vicinal Fe films, though exhibiting greater As diffusion than their singular homologues, displayed better film quality both from the structural and the magnetic points of view. The spin-resolved valence spectra of the vicinal films resemble those for crystalline bulk Fe at lower film thicknesses than for singular films

    Exposure and Exposure Modeling

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    Exposure to contaminants in the environment is quantified through the ecological risk assessment (ERA) process which provides a framework for the development and implementation of environmental management decisions. The ERA uses available toxicological and ecological information to estimate the probability of occurrence for a specified undesired ecological event or endpoint. The level for these endpoints depends on the objectives and the constraints imposed upon the risk assessment process; therefore, multiple endpoints at different scales may be necessary. ERAs Ecotoxicology | Exposure and Exposure Assessment 1527Author\u27s personal copy often rely on the link between these undesired endpoints to a threshold of exposure to specific toxicants and toxicant mixtures. Oral reference doses (RfD), inhalation reference concentrations (RfC), and carcinogenicity assessments are the usual way these links are expressed in the ERA, and unfortunately most of these thresholds have been developed for human health assessments and not ecosystem integrity. However, since these studies often use animal models, in many cases the original empirical data can be used when trying to apply these findings to ecological consequences or to establish ecological screening values (ESVs). The ecological exposure assessment often begins by comparing constituent concentrations in media (surface water, sediment, soil) to ESVs. The ESVs are derived from ecologically relevant criteria and standards. For example, in the United States the United States Environmental Protection Agency (USEPA) Screening Values and National Ambient Water Quality Criteria (NAWQC) are often used based on ‘no observed adverse effect levels’ (NOAELs) or ‘lowest observed adverse effect levels’ (LOAELs) derived from literature to assess exposure. Radionuclide comparisons for ecological screening are typically dose-based for population level effects. In addition to the ecological threshold comparison, constituents that may bioaccumulate/bioconcentrate are identified during initial screening processes. This is done to account for toxicants that may not be present at levels exceeding ESVs, but must be considered due to trophic transfer of toxicants that may concentrate in higher-trophic-level organisms. Constituents that exceed ESV comparisons (present with means, maximums, or 95% upper confidence levels (UCLs)) are evaluated using a lines-of-evidence approach based on (1) a background evaluation, (2) a bioaccumulation/ bioconcentration potential and ecotoxicity evaluation, (3) a frequency and pattern-of-exceedances evaluation based on review of exceedances to the ESVs, and (4) an evaluation of existing biological data. From this information, ecosystems can be prioritized in terms of risk and focused for proper exposure assessments. This article presents a scientific overview and review of how toxicant exposure is estimated and applied to assess ecosystem integrity

    Space shuttle high pressure auxiliary propulsion subsystem definition study Subtask B report

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    Space shuttle high pressure, hydrogen oxygen auxiliary propulsion subsystem preliminary desig

    Evaluation available encapsulation materials for low-cost long-life silicon photovoltaic arrays

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    Experimental evaluation of selected encapsulation designs and materials based on an earlier study which have potential for use in low cost, long-life photovoltaic arrays are reported. The performance of candidate materials and encapsulated cells were evaluated principally for three types of encapsulation designs based on their potentially low materials and processing costs: (1) polymeric coatings, transparent conformal coatings over the cell with a structural-support substrate; (2) polymeric film lamination, cells laminated between two films or sheets of polymeric materials; and (3) glass-covered systems, cells adhesively bonded to a glass cover (superstrate) with a polymeric pottant and a glass or other substrate material. Several other design types, including those utilizing polymer sheet and pottant materials, were also included in the investigation

    Measurement techniques and instruments suitable for life-prediction testing of photovoltaic arrays

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    Array failure modes, relevant materials property changes, and primary degradation mechanisms are discussed as a prerequisite to identifying suitable measurement techniques and instruments. Candidate techniques and instruments are identified on the basis of extensive reviews of published and unpublished information. These methods are organized in six measurement categories - chemical, electrical, optical, thermal, mechanical, and other physicals. Using specified evaluation criteria, the most promising techniques and instruments for use in life prediction tests of arrays were selected

    Molecular mechanisms of adaptive evolution revealed by global selection for glyphosate resistance

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    The human‐directed, global selection for glyphosate resistance in weeds has revealed a fascinating diversity of evolved resistance mechanisms, including herbicide sequestration in the vacuole, a rapid cell death response, nucleotide polymorphisms in the herbicide target (5‐enolpyruvylshikimate‐3‐phosphate synthase, EPSPS) and increased gene copy number of EPSPS. For this latter mechanism, two distinct molecular genetic mechanisms have been observed, a tandem duplication mechanism and a large extrachromosomal circular DNA (eccDNA) that is tethered to the chromosomes and passed to gametes at meiosis. These divergent mechanisms have a range of consequences for the spread, fitness, and inheritance of resistance traits, and, particularly in the case of the eccDNA, demonstrate how evolved herbicide resistance can generate new insights into plant adaptation to contemporary environmental stress

    Description of Synthetic Model Building and Image Compositing Processes

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