34 research outputs found

    Effect of 1.5 MeV electron irradiation on the transmission of optical materials

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    Comparison of 1.5 MeV electron irradiation induced optical absorption of fused commercial silicas and optical transmission of Al2O3, MgF2, BaF2, LiF, and Be

    Experimental investigation of thermal annealing of nuclear-reactor-induced coloration in fused silica

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    Spectral transmission characteristics of fused silica over range of temperature prior to nuclear irradiation and during thermal annealing of reactor-induced coloratio

    Optical absorption in transparent materials following high-temperature reactor irradiation

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    Reactor irradiation effects on optical absorption levels in fused silic

    Optical absorption in fused silica during TRIGA reactor pulse irradiation

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    Spectral transmission characteristics of fused silica before, during, and after exposure to reactor irradiation pulse

    Photochemistry of Imine-Group VI Carbene Complexes with Alkenes: Synthetic Scope and Photochemical Aspects

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    The irradiation of imine-group VI carbene complexes with alkenes leads to the formation of 1-pyrrolines through a mechanism involving an initial cyclopropanation followed by a light-induced [1,3]-sigmatropic rearrangement. The reaction has no limitations on the structural nature of the imine-carbene complexes and is general for terminal and acyclic or cyclic 1,2-disubstituted electron-poor olefins. From the studies on photochemical aspects such as excited-state quenching, quantum yield, excited-state sensitizers and Stern-Volmer plots, it is concluded that both excited states, singlet and triplet, undergo the photoreaction. As far as we know, this is the first photochemical study on these kinds of compounds
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